Three-dimensional periodic supramolecular organic framework ion sponge in water and microcrystals

Tian, Jia; Zhou, Tian-You; Zhang, Shao-Chen; Aloni, Shaul; Altoe, Maria Virginia; Xie, Song-Hai; Wang, Hui; Zhang, Dan-Wei; Zhao, Xin; Liu, Yi; Li, Zhan-Ting

doi:10.1038/ncomms6574

Title: Three-dimensional periodic supramolecular organic framework ion sponge in water and microcrystals

Journal Article · Tue Dec 02 00:00:00 EST 2014 · Nature Communications

DOI:https://doi.org/10.1038/ncomms6574· OSTI ID:1255553

Tian, Jia ^[1]; Zhou, Tian-You ^[2]; Zhang, Shao-Chen ^[1]; Aloni, Shaul ^[3]; Altoe, Maria Virginia ^[3]; Xie, Song-Hai ^[1]; Wang, Hui ^[1]; Zhang, Dan-Wei ^[1]; Zhao, Xin ^[2]; Liu, Yi ^[3]; Li, Zhan-Ting ^[1]

Fudan Univ., Shanghai (China)
Chinese Academy of Sciences (CAS), Shanghai (China). Shanghai Institute of Organic Chemistry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Self-assembly has emerged as a powerful approach to generating complex supramolecular architectures. Despite there being many crystalline frameworks reported in the solid state, the construction of highly soluble periodic supramolecular networks in a three-dimensional space is still a challenge. In this paper we demonstrate that the encapsulation motif, which involves the dimerization of two aromatic units within cucurbit[8]uril, can be used to direct the co-assembly of a tetratopic molecular block and cucurbit[8]uril into a periodic three-dimensional supramolecular organic framework in water. The periodicity of the supramolecular organic framework is supported by solution-phase small-angle X-ray-scattering and diffraction experiments. Upon evaporating the solvent, the periodicity of the framework is maintained in porous microcrystals. Lastly, as a supramolecular 'ion sponge', the framework can absorb different kinds of anionic guests, including drugs, in both water and microcrystals, and drugs absorbed in microcrystals can be released to water with selectivity.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1255553

Journal Information:: Nature Communications, Vol. 5; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 176 works

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