Composite membranes, methods of making same, and applications of same

Pintauro, Peter N.; Park, Andrew; Ballengee, Jason

Title: Composite membranes, methods of making same, and applications of same

Patent · Tue May 24 00:00:00 EDT 2016

OSTI ID:1254129

Pintauro, Peter N.; Park, Andrew; Ballengee, Jason

In one aspect of the present invention, a method of fabricating a composite membrane includes: forming a first polymer solution from a first polymer and a second polymer solution from a second polymer, respectively, where the first polymer includes a charged polymer and the second polymer includes an uncharged polymer; electrospinning, separately and simultaneously, the first and second polymer solutions to form a dual fiber mat with first polymer fibers and second polymer fibers; and processing the dual fiber mat by softening and flowing one of the first or second polymer fibers to fill in the void space between the other of the first and second polymer fibers so as to form the composite membrane. In some embodiments, the composite membrane may be a proton exchange membrane (PEM) or an anion exchange membrane (AEM).

View Patent

Cite

Export

Save

Research Organization:: Vanderbilt Univ., Nashville, TN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG36-06GO16030

Assignee:: VANDERBILT UNIVERSITY (Nashville, TN)

Patent Number(s):: 9,350,036

Application Number:: 13/567,857

OSTI ID:: 1254129

Resource Relation:: Patent File Date: 2012 Aug 06

Country of Publication:: United States

Language:: English

References (52)

Nafion Nanofiber Membranes Lee, Kyung Min; Choi, Jonghyun; Wycisk, Ryszard ECS Transactions, Vol. 25, Issue 1, p. 1451-1458 https://doi.org/10.1149/1.3210701	journal	January 2009
Composite Fuel Cell Membranes from Dual-Nanofiber Electrospun Mats Ballengee, Jason B.; Pintauro, Peter N. Macromolecules, Vol. 44, Issue 18, p. 7307-7314 https://doi.org/10.1021/ma201684j	journal	September 2011
On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells Kreuer, K. D. Journal of Membrane Science, Vol. 185, Issue 1, p. 29-39 https://doi.org/10.1016/S0376-7388(00)00632-3	journal	April 2001
Poly(p-phenylene sulfone)s with high ion exchange capacity: ionomers with unique microstructural and transport features de Araujo, C. C.; Kreuer, K. D.; Schuster, M. Physical Chemistry Chemical Physics, Vol. 11, Issue 17 https://doi.org/10.1039/B822069G	journal	January 2009
Highly Sulfonated Poly(phenylene sulfone): Preparation and Stability Issues Schuster, Michael; de Araujo, Carla C.; Atanasov, Vladimir Macromolecules, Vol. 42, Issue 8 https://doi.org/10.1021/ma900333n	journal	April 2009
Mechanical endurance of polymer electrolyte membrane and PEM fuel cell durability Huang, Xinyu; Solasi, Roham; Zou, Yue Journal of Polymer Science Part B: Polymer Physics, Vol. 44, Issue 16 https://doi.org/10.1002/polb.20863	journal	January 2006
A degradation study of Nafion proton exchange membrane of PEM fuel cells Tang, Haolin; Peikang, Shen; Jiang, San Ping Journal of Power Sources, Vol. 170, Issue 1, p. 85-92 https://doi.org/10.1016/j.jpowsour.2007.03.061	journal	June 2007
Small-Angle Scattering Study of Perfluorosulfonated Ionomer Solutions Loppinet, Benoit; Gebel, Gérard; Williams, Claudine E. The Journal of Physical Chemistry B, Vol. 101, Issue 10 https://doi.org/10.1021/jp9623047	journal	March 1997
Morphological Control of Electrospun Nafion Nanofiber Mats Ballengee, J. B.; Pintauro, P. N. Journal of The Electrochemical Society, Vol. 158, Issue 5 https://doi.org/10.1149/1.3561645	journal	January 2011
Electrospinning and Solution Properties of Nafion and Poly(acrylic acid) Chen, Hong; Snyder, Joshua D.; Elabd, Yossef A. Macromolecules, Vol. 41, Issue 1, p. 128-135 https://doi.org/10.1021/ma070893g	journal	January 2008
SAXS Analysis of the Thermal Relaxation of Anisotropic Morphologies in Oriented Nafion Membranes Page, Kirt A.; Landis, Forrest A.; Phillips, Alan K. Macromolecules, Vol. 39, Issue 11 https://doi.org/10.1021/ma052359j	journal	May 2006
Mechanical behavior of fuel cell membranes under humidity cycles and effect of swelling anisotropy on the fatigue stresses Kusoglu, Ahmet; Karlsson, Anette M.; Santare, Michael H. Journal of Power Sources, Vol. 170, Issue 2, p. 345-358 https://doi.org/10.1016/j.jpowsour.2007.03.063	journal	July 2007
Performance of alkaline fuel cells: A possible future energy system? Lin, Betty Y. S.; Kirk, Donald W.; Thorpe, Steven J. Journal of Power Sources, Vol. 161, Issue 1, p. 474-483 https://doi.org/10.1016/j.jpowsour.2006.03.052	journal	October 2006
Prospects for Alkaline Anion-Exchange Membranes in Low Temperature Fuel Cells Varcoe, J.; Slade, R. Fuel Cells, Vol. 5, Issue 2, p. 187-200 https://doi.org/10.1002/fuce.200400045	journal	October 2004
Synthesis and alkaline stability of novel cardo poly(aryl ether sulfone)s with pendent quaternary ammonium aliphatic side chains for anion exchange membranes Zhang, Qiang; Zhang, Qifeng; Wang, Junhua Polymer, Vol. 51, Issue 23, p. 5407-5416 https://doi.org/10.1016/j.polymer.2010.09.049	journal	October 2010
Synthesis and properties of anion-exchange membranes for fuel cells Shevchenko, V. V.; Gumennaya, M. A. Theoretical and Experimental Chemistry, Vol. 46, Issue 3 https://doi.org/10.1007/s11237-010-9131-4	journal	August 2010
Transport Properties of Hydroxide and Proton Conducting Membranes Hibbs, Michael R.; Hickner, Michael A.; Alam, Todd M. Chemistry of Materials, Vol. 20, Issue 7 https://doi.org/10.1021/cm703263n	journal	April 2008
Alkaline polymer electrolyte fuel cells: Principle, challenges, and recent progress Tang, DaoPing; Pan, Jing; Lu, ShanFu Science China Chemistry, Vol. 53, Issue 2 https://doi.org/10.1007/s11426-010-0080-5	journal	February 2010
A Soluble and Highly Conductive Ionomer for High-Performance Hydroxide Exchange Membrane Fuel Cells Gu, Shuang; Cai, Rui; Luo, Ting Angewandte Chemie International Edition, Vol. 48, Issue 35, p. 6499-6502 https://doi.org/10.1002/anie.200806299	journal	August 2009
Quaternary Phosphonium-Based Polymers as Hydroxide Exchange Membranes Gu, Shuang; Cai, Rui; Luo, Ting ChemSusChem, Vol. 3, Issue 5 https://doi.org/10.1002/cssc.201000074	journal	April 2010
High-Performance Alkaline Polymer Electrolyte for Fuel Cell Applications Pan, Jing; Lu, Shanfu; Li, Yan Advanced Functional Materials, Vol. 20, Issue 2 https://doi.org/10.1002/adfm.200901314	journal	January 2010
Developing a polysulfone-based alkaline anion exchange membrane for improved ionic conductivity Wang, Guigui; Weng, Yiming; Chu, Deryn Journal of Membrane Science, Vol. 332, Issue 1-2, p. 63-68 https://doi.org/10.1016/j.memsci.2009.01.038	journal	April 2009
Anionic polysulfone ionomers and membranes containing fluorenyl groups for anionic fuel cells Zhou, Junfeng; Unlu, Murat; Vega, Jose A. Journal of Power Sources, Vol. 190, Issue 2, p. 285-292 https://doi.org/10.1016/j.jpowsour.2008.12.127	journal	May 2009
Anion Conductive Aromatic Ionomers Containing Fluorenyl Groups Tanaka, Manabu; Koike, Masaki; Miyatake, Kenji Macromolecules, Vol. 43, Issue 6 https://doi.org/10.1021/ma902479d	journal	March 2010
Synthesis of multi-block poly(arylene ether sulfone) copolymer membrane with pendant quaternary ammonium groups for alkaline fuel cell Zhao, Zhuo; Wang, Junhua; Li, Shenghai Journal of Power Sources, Vol. 196, Issue 10, p. 4445-4450 https://doi.org/10.1016/j.jpowsour.2011.01.081	journal	May 2011
Poly(arylene ether sulfone)s ionomers with pendant quaternary ammonium groups for alkaline anion exchange membranes: Preparation and stability issues Wang, Junhua; Wang, Jing; Li, Shenghai Journal of Membrane Science, Vol. 368, Issue 1-2, p. 246-253 https://doi.org/10.1016/j.memsci.2010.11.058	journal	February 2011
Anion Exchange Membranes by Bromination of Benzylmethyl-Containing Poly(sulfone)s Yan, Jingling; Hickner, Michael A. Macromolecules, Vol. 43, Issue 5 https://doi.org/10.1021/ma902430y	journal	March 2010
Synthesis and properties of anion conductive ionomers containing fluorenyl groups for alkaline fuel cell applications Tanaka, Manabu; Koike, Masaki; Miyatake, Kenji Polym. Chem., Vol. 2, Issue 1 https://doi.org/10.1039/C0PY00238K	journal	January 2011
Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells Hibbs, Michael R.; Fujimoto, Cy H.; Cornelius, Christopher J. Macromolecules, Vol. 42, Issue 21, p. 8316-8321 https://doi.org/10.1021/ma901538c	journal	November 2009
Polymers with Pendant Functional Group. III. Polysulfones Containing Viologen Group Avram, Ecaterina; Butuc, Elena; Luca, Cornelia Journal of Macromolecular Science, Part A, Vol. 34, Issue 9 https://doi.org/10.1080/10601329708010036	journal	September 1997
A review of PEM fuel cell durability: Degradation mechanisms and mitigation strategies Wu, Jinfeng; Yuan, Xiao Zi; Martin, Jonathan J. Journal of Power Sources, Vol. 184, Issue 1, p. 104-119 https://doi.org/10.1016/j.jpowsour.2008.06.006	journal	September 2008
Mechanical response of fuel cell membranes subjected to a hygro-thermal cycle Kusoglu, Ahmet; Karlsson, Anette M.; Santare, Michael H. Journal of Power Sources, Vol. 161, Issue 2, p. 987-996 https://doi.org/10.1016/j.jpowsour.2006.05.020	journal	October 2006
Mechanical properties of Nafion™ electrolyte membranes under hydrated conditions Kundu, Sumit; Simon, Leonardo C.; Fowler, Michael Polymer, Vol. 46, Issue 25, p. 11707-11715 https://doi.org/10.1016/j.polymer.2005.09.059	journal	November 2005
Influence of temperature and humidity on the mechanical properties of Nafion® 117 polymer electrolyte membrane: Mechanical Properties of Nafion® 117 Bauer, F.; Denneler, S.; Willert-Porada, M. Journal of Polymer Science Part B: Polymer Physics, Vol. 43, Issue 7 https://doi.org/10.1002/polb.20367	journal	February 2005
Durability of Perfluorosulfonic Acid and Hydrocarbon Membranes: Effect of Humidity and Temperature Sethuraman, Vijay A.; Weidner, John W.; Haug, Andrew T. Journal of The Electrochemical Society, Vol. 155, Issue 2 https://doi.org/10.1149/1.2806798	journal	January 2008
Blended and Cross-Linked Ionomer Membranes for Application in Membrane Fuel Cells Kerres, J. A. Fuel Cells, Vol. 5, Issue 2 https://doi.org/10.1002/fuce.200400079	journal	April 2005
Counterion dependent crystallization kinetics in blends of a perfluorosulfonate ionomer with poly(vinylidene fluoride) Taylor, Eric P.; Landis, Forrest A.; Page, Kirt A. Polymer, Vol. 47, Issue 21, p. 7425-7435 https://doi.org/10.1016/j.polymer.2006.08.023	journal	October 2006
Blends of a Perfluorosulfonate Ionomer with Poly(vinylidene fluoride): Effect of Counterion Type on Phase Separation and Crystal Morphology Landis, Forrest A.; Moore, Robert B. Macromolecules, Vol. 33, Issue 16 https://doi.org/10.1021/ma000636a	journal	August 2000
Miscibility studies of perfluorinated nafion ionomer and poly(vinylidene fluoride) blends Kyu, Thein; Yang, Jen Chang Macromolecules, Vol. 23, Issue 1 https://doi.org/10.1021/ma00203a031	journal	January 1990
Kinetics of phase separation of Nafion perfluorinated ionomer and poly(vinylidene fluoride) blends Yang, Jen Chang; Kyu, Thein Macromolecules, Vol. 23, Issue 1 https://doi.org/10.1021/ma00203a032	journal	January 1990
Chemically-modified Nafion^®/poly(vinylidene fluoride) blend ionomers for proton exchange membrane fuel cells Song, Min-Kyu; Kim, Young-Taek; Fenton, James M. Journal of Power Sources, Vol. 117, Issue 1-2, p. 14-21 https://doi.org/10.1016/S0378-7753(03)00166-6	journal	May 2003
Nanofiber Network Ion-Exchange Membranes Choi, Jonghyun; Lee, Kyung Min; Wycisk, Ryszard Macromolecules, Vol. 41, Issue 13, p. 4569-4572 https://doi.org/10.1021/ma800551w	journal	July 2008
High Conductivity Perfluorosulfonic Acid Nanofiber Composite Fuel-Cell Membranes Choi, Jonghyun; Wycisk, Ryszard; Zhang, Wenjing ChemSusChem, Vol. 3, Issue 11 https://doi.org/10.1002/cssc.201000220	journal	October 2010
High Performance Fuel Cell Operation with a Non-fluorinated Polyphosphazene Electrode Binder Muldoon, J.; Lin, J.; Wycisk, R. Fuel Cells, Vol. 9, Issue 5 https://doi.org/10.1002/fuce.200900123	journal	October 2009
Fabrication and Characterization of Ionic Conducting Nanofibers Laforgue, Alexis; Robitaille, Lucie; Mokrini, Asmae Macromolecular Materials and Engineering, Vol. 292, Issue 12 https://doi.org/10.1002/mame.200700200	journal	November 2007
Electrospun Ru(bpy)32+-doped nafion nanofibers for electrochemiluminescence sensing Zhou, Cuisong; Liu, Zhen; Dai, Jianyuan The Analyst, Vol. 135, Issue 5 https://doi.org/10.1039/B923031A	journal	January 2010
Glass Transition Temperature of Perfluorosulfonic Acid Ionomers Osborn, Shawn J.; Hassan, Mohammad K.; Divoux, Gilles M. Macromolecules, Vol. 40, Issue 10 https://doi.org/10.1021/ma062029e	journal	May 2007
Super Proton Conductive High-Purity Nafion Nanofibers Dong, Bin; Gwee, Liang; Salas-de la Cruz, David Nano Letters, Vol. 10, Issue 9 https://doi.org/10.1021/nl102581w	journal	September 2010
Electrical Resistivity of Composites McLachlan, David S.; Blaszkiewicz, Michael; Newnham, Robert E. Journal of the American Ceramic Society, Vol. 73, Issue 8 https://doi.org/10.1111/j.1151-2916.1990.tb07576.x	journal	August 1990
Nafion-Flourinated Ethylene-Propylene Resin Membrane Blends for Direct Methanol Fuel Cells Lin, J.; Lee, J. K.; Kellner, M. Journal of The Electrochemical Society, Vol. 153, Issue 7 https://doi.org/10.1149/1.2196687	journal	January 2006
Review: Durability and Degradation Issues of PEM Fuel Cell Components de Bruijn, F. A.; Dam, V. A. T.; Janssen, G. J. M. Fuel Cells, Vol. 8, Issue 1 https://doi.org/10.1002/fuce.200700053	journal	February 2008
Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same Grot, Walther G.; Rajendran, Govindarajulu https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5919583 US Patent Document 5,919,583	patent	July 1999

Similar Records

Composite membranes, methods of making same, and applications of same

Patent · Tue Nov 27 00:00:00 EST 2018 · OSTI ID:1254129

Pintauro, Peter N.; Park, Andrew; Ballengee, Jason

Nanofiber electrode and method of forming same

Patent · Tue Feb 27 00:00:00 EST 2018 · OSTI ID:1254129

Pintauro, Peter N.; Zhang, Wenjing

Electrospun Nafion^®/Polyphenylsulfone composite membranes for regenerative Hydrogen bromine fuel cells

Journal Article · Mon Feb 29 00:00:00 EST 2016 · Materials · OSTI ID:1254129

Park, Jun; Wycisk, Ryszard; Pintauro, Peter N.; +2 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
36 MATERIALS SCIENCE

Title: Composite membranes, methods of making same, and applications of same

Citation Formats

References (52)

Similar Records

Related Subjects