Interfacial binding of divalent cations to calixarene-based Langmuir monolayers

Tulli, Ludovico G.; Wang, Wenjie; Lindemann, William R.; Kuzmenko, Ivan; Meier, Wolfgang; Vaknin, David; Shahgaldian, Patrick

doi:10.1021/acs.langmuir.5b00262

Interfacial binding of divalent cations to calixarene-based Langmuir monolayers

Journal Article · Fri Feb 20 00:00:00 EST 2015 · Langmuir

DOI:https://doi.org/10.1021/acs.langmuir.5b00262· OSTI ID:1253372

Tulli, Ludovico G. ^[1]; Wang, Wenjie ^[2]; Lindemann, William R. ^[2]; Kuzmenko, Ivan ^[3]; Meier, Wolfgang ^[4]; Vaknin, David ^[2]; Shahgaldian, Patrick ^[1]

Univ. of Applied Science and Arts Northwestern Switzerland, Muttenz (Switzerland)
Ames Lab. and Iowa State Univ., Ames, IA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Univ. of Basel, Basel (Switzerland)

The interactions of Langmuir monolayers produced through the self-assembly of an amphiphilic p-carboxycalix[4]arene with a series of divalent, fourth-period transition metals, at the air-water interface, were investigated. Changes in the interfacial behavior of 1 in response to the presence of CuCl₂, CoCl₂, MnCl₂, and NiCl₂ were studied by means of Langmuir compression isotherms and Brewster angle microscopy (BAM). The measurements revealed that the self-assembly properties of 1 are significantly affected by Cu²⁺ ions. The interactions of 1-based monolayers with Co²⁺ and Cu²⁺ ions were further investigated by means of synchrotron radiation-based X-ray reflectivity (XRR), X-ray near-total-reflection fluorescence (XNTRF), and grazing incidence X-ray diffraction (GIXD). XNTRF and XRR analyses revealed that the monolayer of 1 binds more strongly to Cu²⁺ than Co²⁺ ions. In the presence of relatively high concentrations of Cu²⁺ ions in the subphase (1.4 × 10^-3 M), XNTRF exhibited anomalous depth profile behavior and GIXD measurements showed considerably strong diffuse scattering. Furthermore, both measurements suggest the formation of Cu²⁺ clusters contiguous to the monolayer of 1.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1253372

Alternate ID(s):: OSTI ID: 1241124

Report Number(s):: IS-J--9001

Journal Information:: Langmuir, Journal Name: Langmuir Journal Issue: 8 Vol. 31; ISSN 0743-7463

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Langmuir monolayers
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Interfacial binding of divalent cations to calixarene-based Langmuir monolayers

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