Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2

Miner, Elise M.; Fukushima, Tomohiro; Sheberla, Dennis; Sun, Lei; Surendranath, Yogesh; Dinca, Mircea

doi:10.1038/ncomms10942

Electrochemical oxygen reduction catalysed by Ni₃(hexaiminotriphenylene)₂

Journal Article · Mon Mar 07 23:00:00 EST 2016 · Nature Communications

DOI:https://doi.org/10.1038/ncomms10942· OSTI ID:1252901

Miner, Elise M. ^[1]; Fukushima, Tomohiro ^[2]; ^[2]; ^[2]; Surendranath, Yogesh ^[2]; Dinca, Mircea ^[2]

Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Massachusetts Institute of Technology
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni₃(HITP)₂ (HITP=2, 3, 6, 7, 10, 11-hexaiminotriphenylene) as an intrinsically conductive metal-organic framework which functions as a well-defined, tunable oxygen reduction electrocatalyst in alkaline solution. Ni₃(HITP)₂ exhibits oxygen reduction activity competitive with the most active non-platinum group metal electrocatalysts and stability during extended polarization. The square planar Ni-N₄ sites are structurally reminiscent of the highly active and widely studied non-platinum group metal electrocatalysts containing M-N₄ units. Ni₃(HITP)₂ and analogues thereof combine the high crystallinity of metal-organic frameworks, the physical durability and electrical conductivity of graphitic materials, and the diverse yet well-controlled synthetic accessibility of molecular species. As a result, such properties may enable the targeted synthesis and systematic optimization of oxygen reduction electrocatalysts as components of fuel cells and electrolysers for renewable energy applications.

View Accepted Manuscript (DOE)

Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0006937

OSTI ID:: 1252901

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 7; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (54)

Heterometal-Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts Lin, Qipu; Bu, Xianhui; Kong, Aiguo Advanced Materials, Vol. 27, Issue 22 https://doi.org/10.1002/adma.201500727	journal	April 2015
On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction Masa, Justus; Xia, Wei; Muhler, Martin Angewandte Chemie International Edition, Vol. 54, Issue 35 https://doi.org/10.1002/anie.201500569	journal	July 2015
Platinum and Non-Platinum Nanomaterials for the Molecular Oxygen Reduction Reaction Alonso-Vante, Nicolas ChemPhysChem, Vol. 11, Issue 13 https://doi.org/10.1002/cphc.200900817	journal	April 2010
Metal-Organic Framework-Derived Bamboo-like Nitrogen-Doped Graphene Tubes as an Active Matrix for Hybrid Oxygen-Reduction Electrocatalysts Li, Qing; Pan, Hengyu; Higgins, Drew Small, Vol. 11, Issue 12 https://doi.org/10.1002/smll.201402069	journal	November 2014
Oxygen electroreduction on Ag(111): The pH effect Blizanac, B. B.; Ross, P. N.; Markovic, N. M. Electrochimica Acta, Vol. 52, Issue 6 https://doi.org/10.1016/j.electacta.2006.06.047	journal	January 2007
Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction Jahan, Maryam; Bao, Qiaoliang; Loh, Kian Ping Journal of the American Chemical Society, Vol. 134, Issue 15 https://doi.org/10.1021/ja211433h	journal	April 2012
Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja5116937	journal	December 2014
Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction Zhao, Shenlong; Yin, Huajie; Du, Lei ACS Nano, Vol. 8, Issue 12 https://doi.org/10.1021/nn505582e	journal	November 2014
Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination Strickland, Kara; Miner, Elise; Jia, Qingying Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8343	journal	June 2015
From cage-in-cage MOF to N-doped and Co-nanoparticle-embedded carbon for oxygen reduction reaction Kong, Aiguo; Mao, Chengyu; Lin, Qipu Dalton Transactions, Vol. 44, Issue 15 https://doi.org/10.1039/c4dt03726j	journal	January 2015
Carbonization of self-assembled nanoporous hemin with a significantly enhanced activity for the oxygen reduction reaction Xie, Yan; Tang, Chizhou; Hao, Zhiqiang Faraday Discuss., Vol. 176 https://doi.org/10.1039/c4fd00121d	journal	January 2014
Highly graphitized nitrogen-doped porous carbon nanopolyhedra derived from ZIF-8 nanocrystals as efficient electrocatalysts for oxygen reduction reactions Zhang, Linjie; Su, Zixue; Jiang, Feilong Nanoscale, Vol. 6, Issue 12 https://doi.org/10.1039/c4nr00348a	journal	January 2014
Non-precious electrocatalysts synthesized from metal–organic frameworks Afsahi, Foroughazam; Kaliaguine, Serge Journal of Materials Chemistry A, Vol. 2, Issue 31 https://doi.org/10.1039/c4ta02010c	journal	January 2014
Cobalt Phthalocyanine as a Fuel Cell Cathode Jasinski, Raymond Journal of The Electrochemical Society, Vol. 112, Issue 5 https://doi.org/10.1149/1.2423590	journal	January 1965
Electrochemical Reduction of Carbon Dioxide Using a Copper Rubeanate Metal Organic Framework Hinogami, R.; Yotsuhashi, S.; Deguchi, M. ECS Electrochemistry Letters, Vol. 1, Issue 4 https://doi.org/10.1149/2.001204eel	journal	January 2012
Highly Active Non-PGM Catalysts Prepared from Metal Organic Frameworks Barkholtz, Heather; Chong, Lina; Kaiser, Zachary Catalysts, Vol. 5, Issue 2 https://doi.org/10.3390/catal5020955	journal	June 2015
A Graphene Oxide and Copper-Centered Metal Organic Framework Composite as a Tri-Functional Catalyst for HER, OER, and ORR Jahan, Maryam; Liu, Zhaolin; Loh, Kian Ping Advanced Functional Materials, Vol. 23, Issue 43 https://doi.org/10.1002/adfm.201300510	journal	May 2013
Graphene/Graphene-Tube Nanocomposites Templated from Cage-Containing Metal-Organic Frameworks for Oxygen Reduction in Li-O ₂ Batteries Li, Qing; Xu, Ping; Gao, Wei Advanced Materials, Vol. 26, Issue 9 https://doi.org/10.1002/adma.201304218	journal	November 2013
Highly Efficient Non-Precious Metal Electrocatalysts Prepared from One-Pot Synthesized Zeolitic Imidazolate Frameworks Zhao, Dan; Shui, Jiang-Lan; Grabstanowicz, Lauren R. Advanced Materials, Vol. 26, Issue 7 https://doi.org/10.1002/adma.201304238	journal	December 2013
Molecular Architecture of Cobalt Porphyrin Multilayers on Reduced Graphene Oxide Sheets for High-Performance Oxygen Reduction Reaction Tang, Hongjie; Yin, Huajie; Wang, Jiangyan Angewandte Chemie, Vol. 125, Issue 21 https://doi.org/10.1002/ange.201300711	journal	April 2013
Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei Angewandte Chemie, Vol. 127, Issue 41 https://doi.org/10.1002/ange.201506048	journal	August 2015
Molecular Architecture of Cobalt Porphyrin Multilayers on Reduced Graphene Oxide Sheets for High-Performance Oxygen Reduction Reaction Tang, Hongjie; Yin, Huajie; Wang, Jiangyan Angewandte Chemie International Edition, Vol. 52, Issue 21 https://doi.org/10.1002/anie.201300711	journal	April 2013
Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei Angewandte Chemie International Edition, Vol. 54, Issue 41 https://doi.org/10.1002/anie.201506048	journal	August 2015
Zeolitic Imidazolate Framework (ZIF)-Derived, Hollow-Core, Nitrogen-Doped Carbon Nanostructures for Oxygen-Reduction Reactions in PEFCs Palaniselvam, Thangavelu; Biswal, Bishnu P.; Banerjee, Rahul Chemistry - A European Journal, Vol. 19, Issue 28 https://doi.org/10.1002/chem.201300145	journal	May 2013
X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M. Surface and Interface Analysis, Vol. 41, Issue 4 https://doi.org/10.1002/sia.3026	journal	April 2009
Physical and Chemical Applications of Dyestuffs Schäfer, F. P.; Gerischer, H.; Willig, F. Topics in Current Chemistry https://doi.org/10.1007/BFb0046055	book	January 1976
Nitrogen-doped porous carbons from bipyridine-based metal-organic frameworks: Electrocatalysis for oxygen reduction reaction and Pt-catalyst support for methanol electrooxidation Zhu, Dandan; Li, Liangjun; Cai, Jinjun Carbon, Vol. 79 https://doi.org/10.1016/j.carbon.2014.08.013	journal	November 2014
High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction Ge, Lei; Yang, Ying; Wang, Li Carbon, Vol. 82 https://doi.org/10.1016/j.carbon.2014.10.085	journal	February 2015
Electrocatalytic four-electron reduction of oxygen with Copper (II)-based metal-organic frameworks Mao, Junjie; Yang, Lifen; Yu, Ping Electrochemistry Communications, Vol. 19 https://doi.org/10.1016/j.elecom.2012.02.025	journal	June 2012
Iron(II) phthalocyanine covalently functionalized graphene as a highly efficient non-precious-metal catalyst for the oxygen reduction reaction in alkaline media Liu, Ying; Wu, Yan-Ying; Lv, Guo-Jun Electrochimica Acta, Vol. 112 https://doi.org/10.1016/j.electacta.2013.08.174	journal	December 2013
Nano-structured non-platinum catalysts for automotive fuel cell application Serov, Alexey; Artyushkova, Kateryna; Niangar, Ellazar Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.07.002	journal	September 2015
New interpretations of XPS spectra of nickel metal and oxides Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C. Surface Science, Vol. 600, Issue 9 https://doi.org/10.1016/j.susc.2006.01.041	journal	May 2006
Two-Dimensional π-Conjugated Metal Bis(dithiolene) Complex Nanosheets as Selective Catalysts for Oxygen Reduction Reaction Zhang, Peng; Hou, Xiuli; Liu, Lei The Journal of Physical Chemistry C, Vol. 119, Issue 50 https://doi.org/10.1021/acs.jpcc.5b09148	journal	December 2015
Efficient Oxygen Electroreduction: Hierarchical Porous Fe–N-doped Hollow Carbon Nanoshells Wang, Yuan; Kong, Aiguo; Chen, Xitong ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00530	journal	May 2015
Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E. Chemistry of Materials, Vol. 25, Issue 24 https://doi.org/10.1021/cm403726v	journal	December 2013
From Metal–Organic Framework to Nitrogen-Decorated Nanoporous Carbons: High CO ₂ Uptake and Efficient Catalytic Oxygen Reduction Aijaz, Arshad; Fujiwara, Naoko; Xu, Qiang Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja5003907	journal	May 2014
High Electrical Conductivity in Ni ₃ (2,3,6,7,10,11-hexaiminotriphenylene) ₂ , a Semiconducting Metal–Organic Graphene Analogue Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A. Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja502765n	journal	April 2014
Post modification of MOF derived carbon via g-C ₃ N ₄ entrapment for an efficient metal-free oxygen reduction reaction Pandiaraj, Sekar; Aiyappa, Harshitha Barike; Banerjee, Rahul Chem. Commun., Vol. 50, Issue 25 https://doi.org/10.1039/C3CC47620K	journal	January 2014
Oxygen reduction in the nanocage of metal–organic frameworks with an electron transfer mediator Jiang, Min; Li, Liangjun; Zhu, Dandan J. Mater. Chem. A, Vol. 2, Issue 15 https://doi.org/10.1039/C3TA15319C	journal	January 2014
Metal–organic framework templated nitrogen and sulfur co-doped porous carbons as highly efficient metal-free electrocatalysts for oxygen reduction reactions Li, Jisen; Chen, Yuyun; Tang, Yujia J. Mater. Chem. A, Vol. 2, Issue 18 https://doi.org/10.1039/C3TA15335E	journal	January 2014
From cage-in-cage MOF to N-doped and Co-nanoparticle-embedded carbon for oxygen reduction reaction Kong, Aiguo; Mao, Chengyu; Lin, Qipu Dalton Transactions, Vol. 44, Issue 15 https://doi.org/10.1039/C4DT03726J	journal	January 2015
Carbonization of self-assembled nanoporous hemin with a significantly enhanced activity for the oxygen reduction reaction Xie, Yan; Tang, Chizhou; Hao, Zhiqiang Faraday Discuss., Vol. 176 https://doi.org/10.1039/C4FD00121D	journal	January 2014
Highly graphitized nitrogen-doped porous carbon nanopolyhedra derived from ZIF-8 nanocrystals as efficient electrocatalysts for oxygen reduction reactions Zhang, Linjie; Su, Zixue; Jiang, Feilong Nanoscale, Vol. 6, Issue 12 https://doi.org/10.1039/C4NR00348A	journal	January 2014
One-step synthesis of nitrogen-doped microporous carbon materials as metal-free electrocatalysts for oxygen reduction reaction Zhao, Xiaojun; Zhao, Huanyu; Zhang, Tingting J. Mater. Chem. A, Vol. 2, Issue 30 https://doi.org/10.1039/C4TA00846D	journal	January 2014
MOF derived catalysts for electrochemical oxygen reduction Wang, Xiaojuan; Zhou, Junwen; Fu, He J. Mater. Chem. A, Vol. 2, Issue 34 https://doi.org/10.1039/C4TA01506A	journal	January 2014
Well-defined carbon polyhedrons prepared from nano metal–organic frameworks for oxygen reduction Xia, Wei; Zhu, Jinghan; Guo, Wenhan J. Mater. Chem. A, Vol. 2, Issue 30 https://doi.org/10.1039/C4TA01656D	journal	January 2014
Non-precious electrocatalysts synthesized from metal–organic frameworks Afsahi, Foroughazam; Kaliaguine, Serge Journal of Materials Chemistry A, Vol. 2, Issue 31 https://doi.org/10.1039/C4TA02010C	journal	January 2014
Recent advances of doped carbon as non-precious catalysts for oxygen reduction reaction Shi, Hao; Shen, Yanfei; He, Fei J. Mater. Chem. A, Vol. 2, Issue 38 https://doi.org/10.1039/C4TA02790F	journal	January 2014
Synthesis of an ε-MnO ₂ /metal–organic-framework composite and its electrocatalysis towards oxygen reduction reaction in an alkaline electrolyte Wang, Hao; Yin, Fengxiang; Chen, Biaohua Journal of Materials Chemistry A, Vol. 3, Issue 31 https://doi.org/10.1039/C5TA02244D	journal	January 2015
A review on non-precious metal electrocatalysts for PEM fuel cells Chen, Zhongwei; Higgins, Drew; Yu, Aiping Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c0ee00558d	journal	January 2011
Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells Zhao, Dan; Shui, Jiang-Lan; Chen, Chen Chemical Science, Vol. 3, Issue 11 https://doi.org/10.1039/c2sc20657a	journal	January 2012
Three dimensional N-doped graphene/PtRu nanoparticle hybrids as high performance anode for direct methanol fuel cells Zhao, Shenlong; Yin, Huajie; Du, Lei Journal of Materials Chemistry A, Vol. 2, Issue 11 https://doi.org/10.1039/c3ta14809b	journal	January 2014
One-step conversion from metal–organic frameworks to Co3O4@N-doped carbon nanocomposites towards highly efficient oxygen reduction catalysts Zhang, Guangju; Li, Chuanxi; Liu, Juan Journal of Materials Chemistry A, Vol. 2, Issue 22 https://doi.org/10.1039/c4ta00677a	journal	January 2014
Covalent organic frameworks comprising cobalt porphyrins for catalytic CO ₂ reduction in water Lin, Song; Diercks, Christian S.; Zhang, Yue-Biao Science, Vol. 349, Issue 6253 https://doi.org/10.1126/science.aac8343	journal	August 2015

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Two‐Dimensional Metal‐Organic Layers for Electrochemical Acceptorless Dehydrogenation of N‐Heterocycles Yang, Ling; Ma, Fa‐Xue; Xu, Fan Chemistry – An Asian Journal, Vol. 14, Issue 20 https://doi.org/10.1002/asia.201900391	journal	May 2019
Recent Approaches to Design Electrocatalysts Based on Metal–Organic Frameworks and Their Derivatives Liu, Juan; Hou, Shujin; Li, Weijin Chemistry – An Asian Journal, Vol. 14, Issue 20 https://doi.org/10.1002/asia.201900748	journal	September 2019
Pristine Transition‐Metal‐Based Metal‐Organic Frameworks for Electrocatalysis Sun, Fancheng; Li, Qing; Xue, Huaiguo ChemElectroChem, Vol. 6, Issue 5 https://doi.org/10.1002/celc.201801520	journal	January 2019
Electrocatalyst Derived from Abundant Biomass and its Excellent Activity for In Situ H ₂ O ₂ Production Liao, Min‐Ji; Wang, Yun‐Lu; Li, Shi‐Song ChemElectroChem, Vol. 6, Issue 18 https://doi.org/10.1002/celc.201901321	journal	September 2019
Immobilizing Molecular Metal Dithiolene-Diamine Complexes on 2D Metal-Organic Frameworks for Electrocatalytic H ₂ Production Dong, Renhao; Zheng, Zhikun; Tranca, Diana C. Chemistry - A European Journal, Vol. 23, Issue 10 https://doi.org/10.1002/chem.201605337	journal	December 2016
Solar‐Driven Production of Hydrogen Peroxide from Water and Dioxygen Fukuzumi, Shunichi; Lee, Yong‐Min; Nam, Wonwoo Chemistry – A European Journal, Vol. 24, Issue 20 https://doi.org/10.1002/chem.201704512	journal	February 2018
A Polycarboxyl-Decorated Fe ^III -Based Xerogel-Derived Multifunctional Composite (Fe ₃ O ₄ /Fe/C) as an Efficient Electrode Material towards Oxygen Reduction Reaction and Supercapacitor Application Devi, Bandhana; Venkateswarulu, Mangili; Kushwaha, Himmat Singh Chemistry - A European Journal, Vol. 24, Issue 25 https://doi.org/10.1002/chem.201705232	journal	April 2018
Competitive Metal Coordination of Hexaaminotriphenylene on Cu(111) by Intrinsic Copper Versus Extrinsic Nickel Adatoms Lischka, Matthias; Dong, Renhao; Wang, Mingchao Chemistry – A European Journal, Vol. 25, Issue 8 https://doi.org/10.1002/chem.201803908	journal	January 2019
A Dynamically Stabilized Single‐Nickel Electrocatalyst for Selective Reduction of Oxygen to Hydrogen Peroxide Wang, Tingting; Zeng, Zhongming; Cao, Lingyun Chemistry – A European Journal, Vol. 24, Issue 64 https://doi.org/10.1002/chem.201804312	journal	July 2018
Cobalt‐Based Metal–Organic Framework Nanoarrays as Bifunctional Oxygen Electrocatalysts for Rechargeable Zn‐Air Batteries Chen, Guangbo; Zhang, Jian; Wang, Faxing Chemistry – A European Journal, Vol. 24, Issue 69 https://doi.org/10.1002/chem.201804339	journal	June 2018
Exploring the Influence of Halogen Coordination Effect of Stable Bimetallic MOFs on Oxygen Evolution Reaction Lu, Jia‐Ni; Liu, Jiang; Dong, Long‐Zhang Chemistry – A European Journal, Vol. 25, Issue 69 https://doi.org/10.1002/chem.201903482	journal	October 2019
Synthetic Strategies for Constructing Two-Dimensional Metal-Organic Layers (MOLs): A Tutorial Review: Synthetic Strategies for Constructing Two-Dimensional Metal-Organic Layers (MOLs): A Tutorial Review Cao, Lingyun; Wang, Tingting; Wang, Cheng Chinese Journal of Chemistry, Vol. 36, Issue 8 https://doi.org/10.1002/cjoc.201800144	journal	June 2018
Electrocatalytic Metal-Organic Frameworks for Energy Applications Downes, Courtney A.; Marinescu, Smaranda C. ChemSusChem, Vol. 10, Issue 22 https://doi.org/10.1002/cssc.201701420	journal	November 2017
Nonpyrolyzed Fe−N Coordination‐Based Iron Triazolate Framework: An Efficient and Stable Electrocatalyst for Oxygen Reduction Reaction Huang, Zheng‐Hong; Xie, Nan‐Hong; Zhang, Min ChemSusChem, Vol. 12, Issue 1 https://doi.org/10.1002/cssc.201801886	journal	November 2018
Two‐Dimensional Organometallic TM ₃ –C ₁₂ S ₁₂ Monolayers for Electrocatalytic Reduction of CO ₂ Liu, Jin‐Hang; Yang, Li‐Ming; Ganz, Eric ENERGY & ENVIRONMENTAL MATERIALS, Vol. 2, Issue 3 https://doi.org/10.1002/eem2.12048	journal	July 2019
Scalable Synthesis of Tetrapodal Octaamine: Scalable Synthesis of Tetrapodal Octaamine Ahmad, Ishfaq; Mahmood, Javeed; Baek, Jong-Beom European Journal of Organic Chemistry, Vol. 2019, Issue 13 https://doi.org/10.1002/ejoc.201801410	journal	December 2018
Microporous Solids En Route to Heterogeneous Electrocatalysis: The Oxygen Reduction Reaction Haikal, Rana R.; Hassan, Mohamed H.; Alkordi, Mohamed H. Energy Technology, Vol. 8, Issue 3 https://doi.org/10.1002/ente.201900964	journal	December 2019
Cobalt‐based coordination polymer as high activity electrocatalyst for oxygen reduction reaction: Catalysis by novel active site CoO ₄ N ₂ Chen, Xin; Ge, Fan; Lai, Nanjun International Journal of Energy Research, Vol. 44, Issue 3 https://doi.org/10.1002/er.5074	journal	December 2019
Recent Development and Application of Conductive MOFs Li, Pengfei; Wang, Bo Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800078	journal	August 2018
Electroactive Metalorganic Frameworks Medina, Dana D.; Mähringer, Andre; Bein, Thomas Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800110	journal	October 2018
2D Nanoporous Fe−N/C Nanosheets as Highly Efficient Non-Platinum Electrocatalysts for Oxygen Reduction Reaction in Zn-Air Battery Yang, Zheng Kun; Lin, Ling; Xu, An-Wu Small, Vol. 12, Issue 41 https://doi.org/10.1002/smll.201601887	journal	August 2016
Layer Structured Materials for Advanced Energy Storage and Conversion Guo, Yanpeng; Wei, Yaqing; Li, Huiqiao Small, Vol. 13, Issue 45 https://doi.org/10.1002/smll.201701649	journal	September 2017
Synthesis of Bimetallic Conductive 2D Metal–Organic Framework (Co _x Ni _y ‐CAT) and Its Mass Production: Enhanced Electrochemical Oxygen Reduction Activity Yoon, Hajin; Lee, Sujeong; Oh, Sojin Small, Vol. 15, Issue 17 https://doi.org/10.1002/smll.201805232	journal	April 2019
Cu,N‐Codoped Carbon Nanodisks with Biomimic Stomata‐Like Interconnected Hierarchical Porous Topology as Efficient Electrocatalyst for Oxygen Reduction Reaction Wang, Tao; Yang, Rui; Shi, Naien Small, Vol. 15, Issue 43 https://doi.org/10.1002/smll.201902410	journal	August 2019
A Highly Conductive MOF of Graphene Analogue Ni ₃ (HITP) ₂ as a Sulfur Host for High‐Performance Lithium–Sulfur Batteries Cai, Dong; Lu, Mengjie; Li, La Small, Vol. 15, Issue 44 https://doi.org/10.1002/smll.201902605	journal	September 2019
Atomic Scale Materials for Emerging Robust Catalysis Sun, Xian; Chen, Yunxu; Liu, Keli Small Methods, Vol. 2, Issue 11 https://doi.org/10.1002/smtd.201800181	journal	August 2018
Metal–Organic Frameworks for Electrocatalysis Usman, Muhammad; Zhu, Qi-Long Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 29-66 https://doi.org/10.1007/978-3-030-27161-9_2	book	January 2020
Metal–Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion Zhang, Xu; Chen, An; Zhong, Ming Electrochemical Energy Reviews, Vol. 2, Issue 1 https://doi.org/10.1007/s41918-018-0024-x	journal	November 2018
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution Zhao, Shenlong; Wang, Yun; Dong, Juncai Nature Energy, Vol. 1, Issue 12 https://doi.org/10.1038/nenergy.2016.184	journal	November 2016
Conductive MOF electrodes for stable supercapacitors with high areal capacitance Sheberla, Dennis; Bachman, John C.; Elias, Joseph S. Nature Materials, Vol. 16, Issue 2 https://doi.org/10.1038/nmat4766	journal	October 2016
Porous materials get energized Vlad, Alexandru; Balducci, Andrea Nature Materials, Vol. 16, Issue 2 https://doi.org/10.1038/nmat4851	journal	January 2017
Missing-linker metal-organic frameworks for oxygen evolution reaction Xue, Ziqian; Liu, Kang; Liu, Qinglin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13051-2	journal	November 2019
Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework Oktawiec, Julia; Jiang, Henry Z. H.; Vitillo, Jenny G. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16897-z	journal	June 2020
Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks Skorupskii, Grigorii; Trump, Benjamin A.; Kasel, Thomas W. Nature Chemistry, Vol. 12, Issue 2 https://doi.org/10.1038/s41557-019-0372-0	journal	November 2019
Oxygen reduction catalyzed by a water-soluble binuclear copper( ii ) complex from a neutral aqueous solution Liu, Chengyu; Lei, Haitao; Zhang, Zongyao Chemical Communications, Vol. 53, Issue 22 https://doi.org/10.1039/c6cc09206c	journal	January 2017
Uniform nitrogen and sulphur co-doped hollow carbon nanospheres as efficient metal-free electrocatalysts for oxygen reduction You, Chenghang; Jiang, Xiaowei; Han, Leiyun Journal of Materials Chemistry A, Vol. 5, Issue 4 https://doi.org/10.1039/c6ta08674h	journal	January 2017
Co( ii )-porphyrin-decorated carbon nanotubes as catalysts for oxygen reduction reactions: an approach for fuel cell improvement Sonkar, Piyush Kumar; Prakash, Kamal; Yadav, Mamta Journal of Materials Chemistry A, Vol. 5, Issue 13 https://doi.org/10.1039/c6ta10482g	journal	January 2017
Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework Lions, M.; Tommasino, J. -B.; Chattot, R. Chemical Communications, Vol. 53, Issue 48 https://doi.org/10.1039/c7cc02113e	journal	January 2017
A biomass derived N/C-catalyst for the electrochemical production of hydrogen peroxide Yang, Yiran; He, Fei; Shen, Yanfei Chemical Communications, Vol. 53, Issue 72 https://doi.org/10.1039/c7cc04819j	journal	January 2017
Co–VN encapsulated in bamboo-like N-doped carbon nanotubes for ultrahigh-stability of oxygen reduction reaction Wang, Ying; Wang, Lei; Tong, Miaomiao Nanoscale, Vol. 10, Issue 9 https://doi.org/10.1039/c7nr09538d	journal	January 2018
A nickel-based pectin coordination polymer as an oxygen reduction reaction catalyst for proton-exchange membrane fuel cells Kadirov, M. K.; Minzanova, S. T.; Nizameev, I. R. Inorganic Chemistry Frontiers, Vol. 5, Issue 4 https://doi.org/10.1039/c7qi00770a	journal	January 2018
A bifunctional two dimensional TM ₃ (HHTP) ₂ monolayer and its variations for oxygen electrode reactions Xiao, B. B.; Liu, H. Y.; Jiang, X. B. RSC Advances, Vol. 7, Issue 86 https://doi.org/10.1039/c7ra09974f	journal	January 2017
Is iron unique in promoting electrical conductivity in MOFs? Sun, Lei; Hendon, Christopher H.; Park, Sarah S. Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/c7sc00647k	journal	January 2017
Bis(aminothiolato)nickel nanosheet as a redox switch for conductivity and an electrocatalyst for the hydrogen evolution reaction Sun, Xinsen; Wu, Kuo-Hui; Sakamoto, Ryota Chemical Science, Vol. 8, Issue 12 https://doi.org/10.1039/c7sc02688a	journal	January 2017
Driving electrochemical oxygen reduction and hydrazine oxidation reaction by enzyme-inspired polymeric Cu(3,3′-diaminobenzidine) catalyst He, Fei; Mi, Li; Shen, Yanfei Journal of Materials Chemistry A, Vol. 5, Issue 33 https://doi.org/10.1039/c7ta05183b	journal	January 2017
From covalent triazine-based frameworks to N-doped porous carbon/reduced graphene oxide nanosheets: efficient electrocatalysts for oxygen reduction Jiao, Long; Hu, Yingli; Ju, Huanxin Journal of Materials Chemistry A, Vol. 5, Issue 44 https://doi.org/10.1039/c7ta07387a	journal	January 2017
A novel two-dimensional nickel phthalocyanine-based metal–organic framework for highly efficient water oxidation catalysis Jia, Hongxing; Yao, Yuchuan; Zhao, Jiangtao Journal of Materials Chemistry A, Vol. 6, Issue 3 https://doi.org/10.1039/c7ta07978h	journal	January 2018
Isolated Fe and Co dual active sites on nitrogen-doped carbon for a highly efficient oxygen reduction reaction Zhang, Diyang; Chen, Wenxing; Li, Zhi Chemical Communications, Vol. 54, Issue 34 https://doi.org/10.1039/c8cc00988k	journal	January 2018
Conductive two-dimensional metal–organic frameworks as multifunctional materials Ko, Michael; Mendecki, Lukasz; Mirica, Katherine A. Chemical Communications, Vol. 54, Issue 57 https://doi.org/10.1039/c8cc02871k	journal	January 2018
Graphene-like metal–organic frameworks: morphology control, optimization of thin film electrical conductivity and fast sensing applications Hoppe, Bastian; Hindricks, Karen D. J.; Warwas, Dawid P. CrystEngComm, Vol. 20, Issue 41 https://doi.org/10.1039/c8ce01264d	journal	January 2018
Two-dimensional metal–organic framework nanosheets: synthesis and applications Zhao, Meiting; Huang, Ying; Peng, Yongwu Chemical Society Reviews, Vol. 47, Issue 16 https://doi.org/10.1039/c8cs00268a	journal	January 2018
First-principles design of bifunctional oxygen reduction and evolution catalysts through bimetallic centers in metal–organic frameworks Zhang, Peng; Yang, Xuejing; Gao, Wang Catalysis Science & Technology, Vol. 8, Issue 14 https://doi.org/10.1039/c8cy00675j	journal	January 2018
Carbon dioxide in the cage: manganese metal–organic frameworks for high performance CO ₂ electrodes in Li–CO ₂ batteries Li, Siwu; Dong, Yu; Zhou, Junwen Energy & Environmental Science, Vol. 11, Issue 5 https://doi.org/10.1039/c8ee00415c	journal	January 2018
A boron imidazolate framework with mechanochromic and electrocatalytic properties Wen, Tian; Zheng, Yao; Xu, Chaochen Materials Horizons, Vol. 5, Issue 6 https://doi.org/10.1039/c8mh00859k	journal	January 2018
3-Layer conductive metal–organic nanosheets as electrocatalysts to enable an ultralow detection limit of H ₂ O ₂ Zhang, Mingdao; Wang, Gang; Zheng, Baohui Nanoscale, Vol. 11, Issue 11 https://doi.org/10.1039/c8nr08686a	journal	January 2019
MOF derived carbon based nanocomposite materials as efficient electrocatalysts for oxygen reduction and oxygen and hydrogen evolution reactions Bhattacharyya, Sohini; Das, Chayanika; Maji, Tapas Kumar RSC Advances, Vol. 8, Issue 47 https://doi.org/10.1039/c8ra05102j	journal	January 2018
Redox-active and semi-conducting donor–acceptor conjugated microporous polymers as metal-free ORR catalysts Roy, Syamantak; Bandyopadhyay, Arkamita; Das, Mrinmay Journal of Materials Chemistry A, Vol. 6, Issue 14 https://doi.org/10.1039/c8ta00099a	journal	January 2018
Recent progress in two-dimensional polymers for energy storage and conversion: design, synthesis, and applications Xiao, Peitao; Xu, Yuxi Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta02820f	journal	January 2018
Electrochemical reduction of CO ₂ by single atom catalyst TM–TCNQ monolayers Liu, Jin-Hang; Yang, Li-Ming; Ganz, Eric Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta08677j	journal	January 2019
A metal–organic framework film with a switchable anodic and cathodic behaviour in a photo-electrochemical cell Ifraemov, Raya; Shimoni, Ran; He, Wenhui Journal of Materials Chemistry A, Vol. 7, Issue 7 https://doi.org/10.1039/c8ta10483b	journal	January 2019
Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries Wu, Zhenzhen; Xie, Jian; Xu, Zhichuan J. Journal of Materials Chemistry A, Vol. 7, Issue 9 https://doi.org/10.1039/c8ta11994e	journal	January 2019
Boost-up electrochemical performance of MOFs via confined synthesis within nanoporous carbon matrices for supercapacitor and oxygen reduction reaction applications Kim, Hee Soo; Kang, Min Seok; Yoo, Won Cheol Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta12200h	journal	January 2019
A cobalt metal–organic framework (Co-MOF): a bi-functional electro active material for the oxygen evolution and reduction reaction Tripathy, Rajat K.; Samantara, Aneeya K.; Behera, J. N. Dalton Transactions, Vol. 48, Issue 28 https://doi.org/10.1039/c9dt01730e	journal	January 2019
Two-dimensional metal–organic frameworks and their derivatives for electrochemical energy storage and electrocatalysis Zhao, Kuangmin; Zhu, Weiwei; Liu, Suqin Nanoscale Advances, Vol. 2, Issue 2 https://doi.org/10.1039/c9na00719a	journal	January 2020
One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid Wang, Qijun; Yan, Jiahao; Xiao, Mingchao RSC Advances, Vol. 9, Issue 50 https://doi.org/10.1039/c9ra05806k	journal	January 2019
A dinuclear cobalt cluster as electrocatalyst for oxygen reduction reaction Li, Yun-Wu; Zhang, Wen-Jie; Li, Chun-Xia RSC Advances, Vol. 9, Issue 72 https://doi.org/10.1039/c9ra08068f	journal	January 2019
Two-dimensional magnetic metal–organic frameworks with the Shastry-Sutherland lattice Zhang, Li-Chuan; Zhang, Lizhi; Qin, Guangzhao Chemical Science, Vol. 10, Issue 44 https://doi.org/10.1039/c9sc03816g	journal	January 2019
Spatially confined electrochemical conversion of metal–organic frameworks into metal-sulfides and their in situ electrocatalytic investigation via scanning electrochemical microscopy Liberman, Itamar; He, Wenhui; Shimoni, Ran Chemical Science, Vol. 11, Issue 1 https://doi.org/10.1039/c9sc04141a	journal	January 2020
Redox, transmetalation, and stacking properties of tetrathiafulvalene-2,3,6,7-tetrathiolate bridged tin, nickel, and palladium compounds Xie, Jiaze; Boyn, Jan-Niklas; Filatov, Alexander S. Chemical Science, Vol. 11, Issue 4 https://doi.org/10.1039/c9sc04381k	journal	January 2020
A metal–organic framework converted catalyst that boosts photo-electrochemical water splitting Cardenas-Morcoso, Drialys; Ifraemov, Raya; García-Tecedor, Miguel Journal of Materials Chemistry A, Vol. 7, Issue 18 https://doi.org/10.1039/c9ta01559k	journal	January 2019
Conductive metal–organic framework nanowire arrays for electrocatalytic oxygen evolution Li, Wen-Hua; Lv, Jiangquan; Li, Qiaohong Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta02169h	journal	January 2019
Redox-active metal–organic frameworks for energy conversion and storage Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta04680a	journal	January 2019
2D molecular crystal lattices: advances in their synthesis, characterization, and application Solomos, Marina A.; Claire, F. James; Kempa, Thomas J. Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/c9ta06534b	journal	January 2019
A supersalt-type copper( i )-thiolate cluster with applications for mechano/thermochromism and the oxygen evolution reaction Hu, Lanxia; Zheng, Aiping; Kang, Yao Chemical Communications, Vol. 56, Issue 28 https://doi.org/10.1039/d0cc00619j	journal	January 2020
Electronically conductive metal–organic framework-based materials Kung, Chung-Wei; Han, Po-Chun; Chuang, Cheng-Hsun APL Materials, Vol. 7, Issue 11 https://doi.org/10.1063/1.5125487	journal	November 2019
Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges Wu, Hao Bin; Lou, Xiong Wen (David) Science Advances, Vol. 3, Issue 12 https://doi.org/10.1126/sciadv.aap9252	journal	December 2017
One-Step Synthesis of Rod-Shaped NiFe-MOF as a Highly Efficient Oxygen Evolution Catalyst Zhang, Dandan; Huang, Renxing; Xie, Huaming Nano, Vol. 14, Issue 08 https://doi.org/10.1142/s1793292019501017	journal	August 2019
Metal-Organic Complexes, [Co(bpy) ₃ ](NO ₃ ) ₂ and [Co(bpy) ₂ NO ₃ ]NO ₃ · 5H ₂ O, for Oxygen Reduction Reaction Sheelam, Anjaiah; Ramanujam, Kothandaraman Journal of The Electrochemical Society, Vol. 164, Issue 9 https://doi.org/10.1149/2.0141712jes	journal	January 2017
Graphene-like metal-organic frameworks: Morphology control, optimization of thin film electrical conductivity and fast sensing applications Hoppe, Bastian; Hindricks, Karen D. J.; Warwas, Dawid P. Cambridge : Royal Society of Chemistry https://doi.org/10.15488/4168	other	January 2018
Two-dimensional magnetic metal-organic frameworks with the Shastry-Sutherland lattice Zhang, Li-Chuan; Zhang, Lizhi; Qin, Guangzhao RWTH Aachen University https://doi.org/10.18154/rwth-2019-11577	text	January 2019
Metal–Organic Frameworks Toward Electrocatalytic Applications Li, Jun-Hong; Wang, Yi-Sen; Chen, Yu-Chuan Applied Sciences, Vol. 9, Issue 12 https://doi.org/10.3390/app9122427	journal	June 2019

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