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Title: Electrochemical oxygen reduction catalysed by Ni 3(hexaiminotriphenylene) 2

Abstract

Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni 3(HITP) 2 (HITP=2, 3, 6, 7, 10, 11-hexaiminotriphenylene) as an intrinsically conductive metal-organic framework which functions as a well-defined, tunable oxygen reduction electrocatalyst in alkaline solution. Ni 3(HITP) 2 exhibits oxygen reduction activity competitive with the most active non-platinum group metal electrocatalysts and stability during extended polarization. The square planar Ni-N 4 sites are structurally reminiscent of the highly active and widely studied non-platinum group metal electrocatalysts containing M-N 4 units. Ni 3(HITP) 2 and analogues thereof combine the high crystallinity of metal-organic frameworks, the physical durability and electrical conductivity of graphitic materials, and the diverse yet well-controlled synthetic accessibility of molecular species. As a result, such properties may enable the targeted synthesis and systematic optimization of oxygen reduction electrocatalysts as components of fuel cells and electrolysers for renewable energy applications.

Authors:
 [1];  [1]; ORCiD logo [1]; ORCiD logo [1];  [1];  [1]
  1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Publication Date:
Research Org.:
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1252901
Grant/Contract Number:  
SC0006937
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; chemical sciences; catalysis; inorganic chemistry; materials science

Citation Formats

Miner, Elise M., Fukushima, Tomohiro, Sheberla, Dennis, Sun, Lei, Surendranath, Yogesh, and Dinca, Mircea. Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2. United States: N. p., 2016. Web. doi:10.1038/ncomms10942.
Miner, Elise M., Fukushima, Tomohiro, Sheberla, Dennis, Sun, Lei, Surendranath, Yogesh, & Dinca, Mircea. Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2. United States. doi:10.1038/ncomms10942.
Miner, Elise M., Fukushima, Tomohiro, Sheberla, Dennis, Sun, Lei, Surendranath, Yogesh, and Dinca, Mircea. Tue . "Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2". United States. doi:10.1038/ncomms10942. https://www.osti.gov/servlets/purl/1252901.
@article{osti_1252901,
title = {Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2},
author = {Miner, Elise M. and Fukushima, Tomohiro and Sheberla, Dennis and Sun, Lei and Surendranath, Yogesh and Dinca, Mircea},
abstractNote = {Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni3(HITP)2 (HITP=2, 3, 6, 7, 10, 11-hexaiminotriphenylene) as an intrinsically conductive metal-organic framework which functions as a well-defined, tunable oxygen reduction electrocatalyst in alkaline solution. Ni3(HITP)2 exhibits oxygen reduction activity competitive with the most active non-platinum group metal electrocatalysts and stability during extended polarization. The square planar Ni-N4 sites are structurally reminiscent of the highly active and widely studied non-platinum group metal electrocatalysts containing M-N4 units. Ni3(HITP)2 and analogues thereof combine the high crystallinity of metal-organic frameworks, the physical durability and electrical conductivity of graphitic materials, and the diverse yet well-controlled synthetic accessibility of molecular species. As a result, such properties may enable the targeted synthesis and systematic optimization of oxygen reduction electrocatalysts as components of fuel cells and electrolysers for renewable energy applications.},
doi = {10.1038/ncomms10942},
journal = {Nature Communications},
issn = {2041-1723},
number = ,
volume = 7,
place = {United States},
year = {2016},
month = {3}
}

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Works referenced in this record:

Cobalt Phthalocyanine as a Fuel Cell Cathode
journal, January 1965

  • Jasinski, Raymond
  • Journal of The Electrochemical Society, Vol. 112, Issue 5
  • DOI: 10.1149/1.2423590

Molecular Architecture of Cobalt Porphyrin Multilayers on Reduced Graphene Oxide Sheets for High-Performance Oxygen Reduction Reaction
journal, April 2013

  • Tang, Hongjie; Yin, Huajie; Wang, Jiangyan
  • Angewandte Chemie International Edition, Vol. 52, Issue 21
  • DOI: 10.1002/anie.201300711

On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction
journal, July 2015

  • Masa, Justus; Xia, Wei; Muhler, Martin
  • Angewandte Chemie International Edition, Vol. 54, Issue 35
  • DOI: 10.1002/anie.201500569

A review on non-precious metal electrocatalysts for PEM fuel cells
journal, January 2011

  • Chen, Zhongwei; Higgins, Drew; Yu, Aiping
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c0ee00558d

Electrocatalytic four-electron reduction of oxygen with Copper (II)-based metal-organic frameworks
journal, June 2012


Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction
journal, April 2012

  • Jahan, Maryam; Bao, Qiaoliang; Loh, Kian Ping
  • Journal of the American Chemical Society, Vol. 134, Issue 15
  • DOI: 10.1021/ja211433h

A Graphene Oxide and Copper-Centered Metal Organic Framework Composite as a Tri-Functional Catalyst for HER, OER, and ORR
journal, May 2013

  • Jahan, Maryam; Liu, Zhaolin; Loh, Kian Ping
  • Advanced Functional Materials, Vol. 23, Issue 43
  • DOI: 10.1002/adfm.201300510

Oxygen reduction in the nanocage of metal–organic frameworks with an electron transfer mediator
journal, January 2014

  • Jiang, Min; Li, Liangjun; Zhu, Dandan
  • J. Mater. Chem. A, Vol. 2, Issue 15
  • DOI: 10.1039/C3TA15319C

Synthesis of an ε-MnO 2 /metal–organic-framework composite and its electrocatalysis towards oxygen reduction reaction in an alkaline electrolyte
journal, January 2015

  • Wang, Hao; Yin, Fengxiang; Chen, Biaohua
  • Journal of Materials Chemistry A, Vol. 3, Issue 31
  • DOI: 10.1039/C5TA02244D

Highly Active Non-PGM Catalysts Prepared from Metal Organic Frameworks
journal, June 2015

  • Barkholtz, Heather; Chong, Lina; Kaiser, Zachary
  • Catalysts, Vol. 5, Issue 2
  • DOI: 10.3390/catal5020955

Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water
journal, December 2014

  • Clough, Andrew J.; Yoo, Joseph W.; Mecklenburg, Matthew H.
  • Journal of the American Chemical Society, Vol. 137, Issue 1
  • DOI: 10.1021/ja5116937

Electrochemical Reduction of Carbon Dioxide Using a Copper Rubeanate Metal Organic Framework
journal, January 2012

  • Hinogami, R.; Yotsuhashi, S.; Deguchi, M.
  • ECS Electrochemistry Letters, Vol. 1, Issue 4
  • DOI: 10.1149/2.001204eel

Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water
journal, August 2015


Large-Area, Free-Standing, Two-Dimensional Supramolecular Polymer Single-Layer Sheets for Highly Efficient Electrocatalytic Hydrogen Evolution
journal, August 2015

  • Dong, Renhao; Pfeffermann, Martin; Liang, Haiwei
  • Angewandte Chemie International Edition, Vol. 54, Issue 41
  • DOI: 10.1002/anie.201506048

Two-Dimensional π-Conjugated Metal Bis(dithiolene) Complex Nanosheets as Selective Catalysts for Oxygen Reduction Reaction
journal, December 2015

  • Zhang, Peng; Hou, Xiuli; Liu, Lei
  • The Journal of Physical Chemistry C, Vol. 119, Issue 50
  • DOI: 10.1021/acs.jpcc.5b09148

High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Non-precious electrocatalysts synthesized from metal–organic frameworks
journal, January 2014

  • Afsahi, Foroughazam; Kaliaguine, Serge
  • Journal of Materials Chemistry A, Vol. 2, Issue 31
  • DOI: 10.1039/C4TA02010C

From Metal–Organic Framework to Nitrogen-Decorated Nanoporous Carbons: High CO 2 Uptake and Efficient Catalytic Oxygen Reduction
journal, May 2014

  • Aijaz, Arshad; Fujiwara, Naoko; Xu, Qiang
  • Journal of the American Chemical Society, Vol. 136, Issue 19
  • DOI: 10.1021/ja5003907

From cage-in-cage MOF to N-doped and Co-nanoparticle-embedded carbon for oxygen reduction reaction
journal, January 2015

  • Kong, Aiguo; Mao, Chengyu; Lin, Qipu
  • Dalton Transactions, Vol. 44, Issue 15
  • DOI: 10.1039/C4DT03726J

Zeolitic Imidazolate Framework (ZIF)-Derived, Hollow-Core, Nitrogen-Doped Carbon Nanostructures for Oxygen-Reduction Reactions in PEFCs
journal, May 2013

  • Palaniselvam, Thangavelu; Biswal, Bishnu P.; Banerjee, Rahul
  • Chemistry - A European Journal, Vol. 19, Issue 28
  • DOI: 10.1002/chem.201300145

Post modification of MOF derived carbon via g-C 3 N 4 entrapment for an efficient metal-free oxygen reduction reaction
journal, January 2014

  • Pandiaraj, Sekar; Aiyappa, Harshitha Barike; Banerjee, Rahul
  • Chem. Commun., Vol. 50, Issue 25
  • DOI: 10.1039/C3CC47620K

Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination
journal, June 2015

  • Strickland, Kara; Miner, Elise; Jia, Qingying
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8343

Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism
journal, December 2013

  • Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E.
  • Chemistry of Materials, Vol. 25, Issue 24
  • DOI: 10.1021/cm403726v

Well-defined carbon polyhedrons prepared from nano metal–organic frameworks for oxygen reduction
journal, January 2014

  • Xia, Wei; Zhu, Jinghan; Guo, Wenhan
  • J. Mater. Chem. A, Vol. 2, Issue 30
  • DOI: 10.1039/C4TA01656D

MOF derived catalysts for electrochemical oxygen reduction
journal, January 2014

  • Wang, Xiaojuan; Zhou, Junwen; Fu, He
  • J. Mater. Chem. A, Vol. 2, Issue 34
  • DOI: 10.1039/C4TA01506A

One-step conversion from metal–organic frameworks to Co3O4@N-doped carbon nanocomposites towards highly efficient oxygen reduction catalysts
journal, January 2014

  • Zhang, Guangju; Li, Chuanxi; Liu, Juan
  • Journal of Materials Chemistry A, Vol. 2, Issue 22
  • DOI: 10.1039/c4ta00677a

Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
journal, January 2012

  • Zhao, Dan; Shui, Jiang-Lan; Chen, Chen
  • Chemical Science, Vol. 3, Issue 11
  • DOI: 10.1039/c2sc20657a

Highly Efficient Non-Precious Metal Electrocatalysts Prepared from One-Pot Synthesized Zeolitic Imidazolate Frameworks
journal, December 2013

  • Zhao, Dan; Shui, Jiang-Lan; Grabstanowicz, Lauren R.
  • Advanced Materials, Vol. 26, Issue 7
  • DOI: 10.1002/adma.201304238

Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction
journal, November 2014

  • Zhao, Shenlong; Yin, Huajie; Du, Lei
  • ACS Nano, Vol. 8, Issue 12
  • DOI: 10.1021/nn505582e

One-step synthesis of nitrogen-doped microporous carbon materials as metal-free electrocatalysts for oxygen reduction reaction
journal, January 2014

  • Zhao, Xiaojun; Zhao, Huanyu; Zhang, Tingting
  • J. Mater. Chem. A, Vol. 2, Issue 30
  • DOI: 10.1039/C4TA00846D

Recent advances of doped carbon as non-precious catalysts for oxygen reduction reaction
journal, January 2014

  • Shi, Hao; Shen, Yanfei; He, Fei
  • J. Mater. Chem. A, Vol. 2, Issue 38
  • DOI: 10.1039/C4TA02790F

Nano-structured non-platinum catalysts for automotive fuel cell application
journal, September 2015


Carbonization of self-assembled nanoporous hemin with a significantly enhanced activity for the oxygen reduction reaction
journal, January 2014

  • Xie, Yan; Tang, Chizhou; Hao, Zhiqiang
  • Faraday Discuss., Vol. 176
  • DOI: 10.1039/C4FD00121D

Efficient Oxygen Electroreduction: Hierarchical Porous Fe–N-doped Hollow Carbon Nanoshells
journal, May 2015


Oxygen electroreduction on Ag(111): The pH effect
journal, January 2007


Three dimensional N-doped graphene/PtRu nanoparticle hybrids as high performance anode for direct methanol fuel cells
journal, January 2014

  • Zhao, Shenlong; Yin, Huajie; Du, Lei
  • Journal of Materials Chemistry A, Vol. 2, Issue 11
  • DOI: 10.1039/c3ta14809b

Platinum and Non-Platinum Nanomaterials for the Molecular Oxygen Reduction Reaction
journal, April 2010


New interpretations of XPS spectra of nickel metal and oxides
journal, May 2006

  • Grosvenor, Andrew P.; Biesinger, Mark C.; Smart, Roger St. C.
  • Surface Science, Vol. 600, Issue 9
  • DOI: 10.1016/j.susc.2006.01.041

X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems
journal, April 2009

  • Biesinger, Mark C.; Payne, Brad P.; Lau, Leo W. M.
  • Surface and Interface Analysis, Vol. 41, Issue 4
  • DOI: 10.1002/sia.3026

    Works referencing / citing this record:

    Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal-Organic Framework System
    journal, May 2018

    • Wang, Xiao-Li; Dong, Long-Zhang; Qiao, Man
    • Angewandte Chemie International Edition, Vol. 57, Issue 31
    • DOI: 10.1002/anie.201803587

    A Phthalocyanine-Based Layered Two-Dimensional Conjugated Metal-Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction
    journal, July 2019

    • Zhong, Haixia; Ly, Khoa Hoang; Wang, Mingchao
    • Angewandte Chemie International Edition, Vol. 58, Issue 31
    • DOI: 10.1002/anie.201907002

    Scalable Synthesis of Tetrapodal Octaamine: Scalable Synthesis of Tetrapodal Octaamine
    journal, December 2018

    • Ahmad, Ishfaq; Mahmood, Javeed; Baek, Jong-Beom
    • European Journal of Organic Chemistry, Vol. 2019, Issue 13
    • DOI: 10.1002/ejoc.201801410

    Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
    journal, November 2016


    A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior
    journal, July 2018


    Oxygen reduction catalyzed by a water-soluble binuclear copper( ii ) complex from a neutral aqueous solution
    journal, January 2017

    • Liu, Chengyu; Lei, Haitao; Zhang, Zongyao
    • Chemical Communications, Vol. 53, Issue 22
    • DOI: 10.1039/c6cc09206c

    Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework
    journal, January 2017

    • Lions, M.; Tommasino, J. -B.; Chattot, R.
    • Chemical Communications, Vol. 53, Issue 48
    • DOI: 10.1039/c7cc02113e

    A boron imidazolate framework with mechanochromic and electrocatalytic properties
    journal, January 2018

    • Wen, Tian; Zheng, Yao; Xu, Chaochen
    • Materials Horizons, Vol. 5, Issue 6
    • DOI: 10.1039/c8mh00859k

    Redox-active metal–organic frameworks for energy conversion and storage
    journal, January 2019

    • Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
    • Journal of Materials Chemistry A, Vol. 7, Issue 28
    • DOI: 10.1039/c9ta04680a

    Metal–Organic Frameworks Toward Electrocatalytic Applications
    journal, June 2019

    • Li, Jun-Hong; Wang, Yi-Sen; Chen, Yu-Chuan
    • Applied Sciences, Vol. 9, Issue 12
    • DOI: 10.3390/app9122427

    Metal-Organic Frameworks Encapsulating Active Nanoparticles as Emerging Composites for Catalysis: Recent Progress and Perspectives
    journal, September 2018


    Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis
    journal, December 2017

    • Li, Fei-Long; Shao, Qi; Huang, Xiaoqing
    • Angewandte Chemie International Edition, Vol. 57, Issue 7
    • DOI: 10.1002/anie.201711376

    Solar‐Driven Production of Hydrogen Peroxide from Water and Dioxygen
    journal, February 2018

    • Fukuzumi, Shunichi; Lee, Yong‐Min; Nam, Wonwoo
    • Chemistry – A European Journal, Vol. 24, Issue 20
    • DOI: 10.1002/chem.201704512

    Exploring the Influence of Halogen Coordination Effect of Stable Bimetallic MOFs on Oxygen Evolution Reaction
    journal, October 2019

    • Lu, Jia‐Ni; Liu, Jiang; Dong, Long‐Zhang
    • Chemistry – A European Journal, Vol. 25, Issue 69
    • DOI: 10.1002/chem.201903482

    Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
    journal, November 2019

    • Skorupskii, Grigorii; Trump, Benjamin A.; Kasel, Thomas W.
    • Nature Chemistry, Vol. 12, Issue 2
    • DOI: 10.1038/s41557-019-0372-0

    Metal-Organic Frameworks Encapsulating Active Nanoparticles as Emerging Composites for Catalysis: Recent Progress and Perspectives
    journal, September 2018


    Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis
    journal, December 2017


    Exploring the Performance Improvement of the Oxygen Evolution Reaction in a Stable Bimetal-Organic Framework System
    journal, May 2018

    • Wang, Xiao-Li; Dong, Long-Zhang; Qiao, Man
    • Angewandte Chemie International Edition, Vol. 57, Issue 31
    • DOI: 10.1002/anie.201803587

    A Phthalocyanine-Based Layered Two-Dimensional Conjugated Metal-Organic Framework as a Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction
    journal, July 2019

    • Zhong, Haixia; Ly, Khoa Hoang; Wang, Mingchao
    • Angewandte Chemie International Edition, Vol. 58, Issue 31
    • DOI: 10.1002/anie.201907002

    Solar‐Driven Production of Hydrogen Peroxide from Water and Dioxygen
    journal, February 2018

    • Fukuzumi, Shunichi; Lee, Yong‐Min; Nam, Wonwoo
    • Chemistry – A European Journal, Vol. 24, Issue 20
    • DOI: 10.1002/chem.201704512

    Exploring the Influence of Halogen Coordination Effect of Stable Bimetallic MOFs on Oxygen Evolution Reaction
    journal, October 2019

    • Lu, Jia‐Ni; Liu, Jiang; Dong, Long‐Zhang
    • Chemistry – A European Journal, Vol. 25, Issue 69
    • DOI: 10.1002/chem.201903482

    Scalable Synthesis of Tetrapodal Octaamine: Scalable Synthesis of Tetrapodal Octaamine
    journal, December 2018

    • Ahmad, Ishfaq; Mahmood, Javeed; Baek, Jong-Beom
    • European Journal of Organic Chemistry, Vol. 2019, Issue 13
    • DOI: 10.1002/ejoc.201801410

    Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
    journal, November 2016


    A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior
    journal, July 2018


    Efficient and tunable one-dimensional charge transport in layered lanthanide metal–organic frameworks
    journal, November 2019

    • Skorupskii, Grigorii; Trump, Benjamin A.; Kasel, Thomas W.
    • Nature Chemistry, Vol. 12, Issue 2
    • DOI: 10.1038/s41557-019-0372-0

    Oxygen reduction catalyzed by a water-soluble binuclear copper( ii ) complex from a neutral aqueous solution
    journal, January 2017

    • Liu, Chengyu; Lei, Haitao; Zhang, Zongyao
    • Chemical Communications, Vol. 53, Issue 22
    • DOI: 10.1039/c6cc09206c

    Insights into the mechanism of electrocatalysis of the oxygen reduction reaction by a porphyrinic metal organic framework
    journal, January 2017

    • Lions, M.; Tommasino, J. -B.; Chattot, R.
    • Chemical Communications, Vol. 53, Issue 48
    • DOI: 10.1039/c7cc02113e

    A bifunctional two dimensional TM 3 (HHTP) 2 monolayer and its variations for oxygen electrode reactions
    journal, January 2017

    • Xiao, B. B.; Liu, H. Y.; Jiang, X. B.
    • RSC Advances, Vol. 7, Issue 86
    • DOI: 10.1039/c7ra09974f

    Bis(aminothiolato)nickel nanosheet as a redox switch for conductivity and an electrocatalyst for the hydrogen evolution reaction
    journal, January 2017

    • Sun, Xinsen; Wu, Kuo-Hui; Sakamoto, Ryota
    • Chemical Science, Vol. 8, Issue 12
    • DOI: 10.1039/c7sc02688a

    A boron imidazolate framework with mechanochromic and electrocatalytic properties
    journal, January 2018

    • Wen, Tian; Zheng, Yao; Xu, Chaochen
    • Materials Horizons, Vol. 5, Issue 6
    • DOI: 10.1039/c8mh00859k

    Redox-active metal–organic frameworks for energy conversion and storage
    journal, January 2019

    • Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
    • Journal of Materials Chemistry A, Vol. 7, Issue 28
    • DOI: 10.1039/c9ta04680a

    Metal–Organic Frameworks Toward Electrocatalytic Applications
    journal, June 2019

    • Li, Jun-Hong; Wang, Yi-Sen; Chen, Yu-Chuan
    • Applied Sciences, Vol. 9, Issue 12
    • DOI: 10.3390/app9122427

    Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
    journal, June 2020


    Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis
    journal, December 2017

    • Li, Fei-Long; Shao, Qi; Huang, Xiaoqing
    • Angewandte Chemie International Edition, Vol. 57, Issue 7
    • DOI: 10.1002/anie.201711376