Voltage clustering in redox-active ligand complexes: mitigating electronic communication through choice of metal ion

Zarkesh, Ryan A.; Ichimura, Andrew S.; Monson, Todd C.; Tomson, Neil C.; Anstey, Mitchell R.

doi:10.1039/c6dt00422a

Voltage clustering in redox-active ligand complexes: mitigating electronic communication through choice of metal ion

Journal Article · Mon Feb 01 04:00:00 EST 2016 · Dalton Transactions

DOI:https://doi.org/10.1039/c6dt00422a· OSTI ID:1249077

Zarkesh, Ryan A. ^[1]; Ichimura, Andrew S. ^[2]; Monson, Todd C. ^[3]; Tomson, Neil C. ^[4]; Anstey, Mitchell R. ^[5]

Sandia National Lab. (SNL-CA), Livermore, CA (United States)
San Francisco State Univ., CA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States)
Sandia National Lab. (SNL-CA), Livermore, CA (United States); Davidson College, Davidson, NC (United States)

We used the redox-active bis(imino)acenapthene (BIAN) ligand to synthesize homoleptic aluminum, chromium, and gallium complexes of the general formula (BIAN)₃M. The resulting compounds were characterized using X-ray crystallography, NMR, EPR, magnetic susceptibility and cyclic voltammetry measurements and modeled using both DFT and ab initio wavefunction calculations to compare the orbital contributions of main group elements and transition metals in ligand-based redox events. Ultimately, complexes of this type have the potential to improve the energy density and electrolyte stability of grid-scale energy storage technologies, such as redox flow batteries, through thermodynamically-clustered redox events.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Sandia National Laboratories, Livermore, CA

Sponsoring Organization:: USDOE Office of Electricity Delivery and Energy Reliability (OE), Power Systems Engineering Research and Development (R&D) (OE-10)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1249077

Report Number(s):: SAND2016-0959J; 619086

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: C Vol. 7; ISSN 1477-9226; ISSN ICHBD9

Country of Publication:: United States

Language:: English

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MetILs ³ : A Strategy for High Density Energy Storage Using Redox-Active Ionic Liquids Small, Leo J.; Pratt, Harry D.; Staiger, Chad L. Advanced Sustainable Systems, Vol. 1, Issue 9 https://doi.org/10.1002/adsu.201700066	journal	July 2017
Synthesis and Catalysis of Redox-Active Bis(imino)acenaphthene (BIAN) Iron Complexes Villa, Matteo; Miesel, Dominique; Hildebrandt, Alexander ChemCatChem, Vol. 9, Issue 16 https://doi.org/10.1002/cctc.201700144	journal	July 2017
Tris(1‐methyl‐imidazol‐2‐yl)phosphane Complexes of Pnictogen, Tetrel, and Triel Cations Suter, Riccardo; Gray, Paul A.; Burford, Neil Chemistry – A European Journal, Vol. 24, Issue 18 https://doi.org/10.1002/chem.201706107	journal	February 2018
Features of Magnetic Behavior in the Row of Pentacoordinated Bis- o -Iminobenzosemiquinonato Metal (Al, Ga, In) Complexes : Features of Magnetic Behavior in the Row of Pentacoordinated Bis- Ershova, Irina V.; Bogomyakov, Artem S.; Fukin, Georgy K. European Journal of Inorganic Chemistry, Vol. 2019, Issue 7 https://doi.org/10.1002/ejic.201801348	journal	February 2019
Ferrous complexes supported by sterically encumbered asymmetric bis(arylimino)acenaphthene (BIAN) ligands: synthesis, characterization and screening for catalytic hydrosilylation of carbonyl compounds Yu, Xun; Zhu, Feifeng; Bu, Donglei RSC Advances, Vol. 7, Issue 25 https://doi.org/10.1039/c7ra01511a	journal	January 2017
Synthesis, characterization and mass-spectrometric analysis of [LSn(IV)F _4−x ] ^x+ salts [L = tris ((1-ethyl-benzoimidazol-2-yl)methyl)amine, x = 1–4] Suter, Riccardo; Swidan, Ala'aeddeen; Zijlstra, Harmen S. Dalton Transactions, Vol. 47, Issue 46 https://doi.org/10.1039/c8dt03908a	journal	January 2018

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Voltage clustering in redox-active ligand complexes: mitigating electronic communication through choice of metal ion

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