Surface protected lithium-metal-oxide electrodes

Thackeray, Michael M.; Kang, Sun-Ho

Surface protected lithium-metal-oxide electrodes

Patent · 05 April 2016

OSTI ID:1248481

Thackeray, Michael M.; Kang, Sun-Ho

A lithium-metal-oxide positive electrode having a layered or spinel structure for a non-aqueous lithium electrochemical cell and battery is disclosed comprising electrode particles that are protected at the surface from undesirable effects, such as electrolyte oxidation, oxygen loss or dissolution by one or more lithium-metal-polyanionic compounds, such as a lithium-metal-phosphate or a lithium-metal-silicate material that can act as a solid electrolyte at or above the operating potential of the lithium-metal-oxide electrode. The surface protection significantly enhances the surface stability, rate capability and cycling stability of the lithium-metal-oxide electrodes, particularly when charged to high potentials.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: W-31109-ENG-38;

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Number(s):: 9,306,210

Application Number:: 14/326,845

OSTI ID:: 1248481

Country of Publication:: United States

Language:: English

References (21)

Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells Gummow, R. J.; de Kock, A.; Thackeray, M. M. Solid State Ionics, Vol. 69, Issue 1, p. 59-67 https://doi.org/10.1016/0167-2738(94)90450-2	journal	April 1994
The significance of the Li₂MnO₃ component in ‘composite’ xLi₂MnO₃·(1−x)LiMn_0.5Ni_0.5O₂ electrodes Johnson, C. S.; Kim, J-S.; Lefief, C. Electrochemistry Communications, Vol. 6, Issue 10, p. 1085-1091 https://doi.org/10.1016/j.elecom.2004.08.002	journal	October 2004
Lithium–manganese oxide electrodes with layered–spinel composite structures xLi₂MnO₃·(1−x)Li_1+yMn_2−yO₄ (0 Johnson, C. S.; Li, N.; Vaughey, J. T. Electrochemistry Communications, Vol. 7, Issue 5, p. 528-536 https://doi.org/10.1016/j.elecom.2005.02.027	journal	May 2005
Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries Kang, S.-H.; Amine, K. Journal of Power Sources, Vol. 146, Issue 1-2, p. 654-657 https://doi.org/10.1016/j.jpowsour.2005.03.152	journal	August 2005
Improvement of structural and electrochemical properties of AlF₃-coated Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathode materials on high voltage region Park, B.-C.; Kim, H.-B.; Myung, S.-T. Journal of Power Sources, Vol. 178, Issue 2, p. 826-831 https://doi.org/10.1016/j.jpowsour.2007.08.034	journal	April 2008
Novel LiCoO₂ Cathode Material with Al₂O₃ Coating for a Li Ion Cell Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791 https://doi.org/10.1021/cm000511k	journal	December 2000
Electrochemical and Structural Properties of xLi₂M‘O₃ ·(1− x )LiMn_0.5Ni_0.5O₂ Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3) Kim, Jeom-Soo; Johnson, Christopher S.; Vaughey, John T. Chemistry of Materials, Vol. 16, Issue 10, p. 1996-2006 https://doi.org/10.1021/cm0306461	journal	May 2004
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T. Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267 https://doi.org/10.1039/B417616M	journal	March 2005
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/B702425H	journal	January 2007
High-Performance ZrO₂-Coated LiNiO₂ Cathode Material Cho, Jaephil; Kim, Tae-Joon; Kim, Yong Jeong Electrochemical and Solid-State Letters, Vol. 4, Issue 10, p. A159-A161 https://doi.org/10.1149/1.1398556	journal	January 2001
Effect of a ZrO₂ Coating on the Structure and Electrochemistry of Li_xCoO₂ When Cycled to 4.5 V Chen, Zhaohui; Dahn, J. R. Electrochemical and Solid-State Letters, Vol. 5, Issue 10, p. A213-A216 https://doi.org/10.1149/1.1503202	journal	January 2002
Optimization of Insertion Compounds Such as LiMn₂O₄ for Li-Ion Batteries Amatucci, G.; Tarascon, J.-M. Journal of The Electrochemical Society, Vol. 149, Issue 12, p. K31-K46 https://doi.org/10.1149/1.1516778	journal	November 2002
The Electrochemical Stability of Spinel Electrodes Coated with ZrO₂, Al₂O₃, and SiO₂ from Colloidal Suspensions Kim, J.-S.; Johnson, C. S.; Vaughey, J. T. Journal of The Electrochemical Society, Vol. 151, Issue 10, p. A1755-A1761 https://doi.org/10.1149/1.1793713	journal	January 2004
Controlled Nanoparticle Metal Phosphates (Metal = Al , Fe, Ce, and Sr) Coatings on LiCoO₂ Cathode Materials Kim, Jisuk; Noh, Mijung; Cho, Jaephil Journal of The Electrochemical Society, Vol. 152, Issue 6, p. A1142-A1148 https://doi.org/10.1149/1.1896526	journal	January 2005
Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries Kim, G.-H.; Kim, J.-H.; Myung, S.-T. Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1707-A1713 https://doi.org/10.1149/1.1952747	journal	July 2005
Synthesis and Characterization of Carbon-Coated Lithium Transition Metal Phosphates LiMPO₄ (M = Fe , Mn, Co, Ni) Prepared via a Nonaqueous Sol-Gel Route Yang, Jingsi; Xu, Jun John Journal of The Electrochemical Society, Vol. 153, Issue 4, p. A716-A723 https://doi.org/10.1149/1.2168410	journal	January 2006
Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries Choi, W.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 9, Issue 5, p. A245-A248 https://doi.org/10.1149/1.2186022	journal	March 2006
The Effects of Acid Treatment on the Electrochemical Properties of 0.5 Li₂MnO₃ ∙ 0.5 LiNi_0.44Co_0.25Mn_0.31O₂ Electrodes in Lithium Cells Kang, S.-H.; Johnson, C. S.; Vaughey, J. T. Journal of The Electrochemical Society, Vol. 153, Issue 6, p. A1186-A1192 https://doi.org/10.1149/1.2194764	journal	January 2006
AlF₃-Coating to Improve High Voltage Cycling Performance of Li[Ni_1∕3]Co_1∕3]Mn_1∕3]O₂ Cathode Materials for Lithium Secondary Batteries Sun, Y.-K.; Cho, S.-W.; Lee, S.-W. Journal of The Electrochemical Society, Vol. 154, Issue 3, p. A168-A172 https://doi.org/10.1149/1.2422890	journal	January 2007
Stabilization of xLi₂MnO₃ ⋅ ( 1 − x ) LiMO₂ Electrode Surfaces ( M = Mn , Ni , Co ) with Mildly Acidic, Fluorinated Solutions Kang, S.-H.; Thackeray, M. M. Journal of The Electrochemical Society, Vol. 155, Issue 4, p. A269-A275 https://doi.org/10.1149/1.2834904	journal	January 2008
Surface Modification of High Capacity Layered Li [ Li_0.2Mn_0.54Ni_0.13Co_0.13 ] O₂ Cathodes by AlPO₄ Wu, Y.; Vadivel Murugan, A.; Manthiram, A. Journal of The Electrochemical Society, Vol. 155, Issue 9, p. A635-A641 https://doi.org/10.1149/1.2948350	journal	January 2008

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