Visualizing non-equilibrium lithiation of spinel oxide via in situ transmission electron microscopy

He, Kai; Zhang, Sen; Li, Jing; Yu, Xiqian; Meng, Qingping; Zhu, Yizhou; Hu, Enyuan; Sun, Ke; Yun, Hongseok; Yang, Xiao -Qing; Zhu, Yimei; Gan, Hong; Mo, Yifei; Stach, Eric A.; Murray, Christopher B.; Su, Dong

doi:10.1038/ncomms11441

Visualizing non-equilibrium lithiation of spinel oxide via in situ transmission electron microscopy

Journal Article · Mon May 09 00:00:00 EDT 2016 · Nature Communications

DOI:https://doi.org/10.1038/ncomms11441· OSTI ID:1247969

He, Kai ^[1]; Zhang, Sen ^[2]; Li, Jing ^[1]; Yu, Xiqian ^[1]; Meng, Qingping ^[1]; Zhu, Yizhou ^[3]; Hu, Enyuan ^[1]; Sun, Ke ^[1]; Yun, Hongseok ^[2]; Yang, Xiao -Qing ^[1]; Zhu, Yimei ^[1]; Gan, Hong ^[1]; Mo, Yifei ^[3]; Stach, Eric A. ^[1]; Murray, Christopher B. ^[2]; Su, Dong ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)
Univ. of Pennsylvania, Philadelphia, PA (United States)
Univ. of Maryland, College Park, MD (United States)

In this study, spinel transition metal oxides are an important class of materials that are being considered as electrodes for lithium-ion batteries, due to their low cost and high theoretical capacity. The lithiation of these compounds is known to undergo a two-step reaction, whereby intercalation and conversion occur in a sequential fashion. These two reactions are known to have distinct reaction dynamics, but it is unclear how the kinetics of these processes affect the overall electrochemical response. Here, we explore the lithiation of nanosized magnetite (F_e3O₄) by employing a new strain-sensitive, bright-field scanning transmission electron microscopy approach.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1247969

Alternate ID(s):: OSTI ID: 1259885

Report Number(s):: BNL--112013-2016-JA

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 9 Vol. 7; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Visualizing non-equilibrium lithiation of spinel oxide via in situ transmission electron microscopy

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