Reversible Dehydration Behavior Reveals Coordinatively Unsaturated Metal Sites in Microporous Aluminum Phosphonates
Journal Article
·
· Crystal Growth and Design
- Texas A & M Univ., College Station, TX (United States)
Incorporation of the same ligand into three different aluminum phenylenediphosphonates (Al(H2O)(O3PC6H4PO3H) (1), Al-4(H2O)(2)(O3PC6H4PO3)(3) (2), and Al-4(H2O)(4)(O3PC6H4PO3)(2.84)(OH)(0.64) (3)) was accomplished by varying the synthetic conditions. The compounds have different sorption properties; however, all exhibit reversible dehydration behavior. The structures of the hydrated and dehydrated phases were determined from powder X-ray diffraction data. Compounds 2 and 3 were found to be microporous, while compound 1 was found to be nonporous. The stability of the dehydrated phase and the resulting porosity was found to be influenced by the change in the structure upon loss of water.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1247158
- Journal Information:
- Crystal Growth and Design, Vol. 14, Issue 10; ISSN 1528-7483
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
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