Performance improvement of Li-rich layer-structured Li 1.2 Mn 0.54 Ni 0.13 Co 0.13 O 2 by integration with spinel LiNi 0.5 Mn 1.5 O 4
Journal Article
·
· Physical Chemistry Chemical Physics. PCCP (Print)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Argonne National Lab. (ANL), Argonne, IL (United States)
Li-rich layered Li1+xMnyM1-x-yO2 (or denoted xLi2MnO3center dot1-xLiMO2, M = Ni, Co, Mn, etc.) are promising cathode materials for high energy-density Li-ion batteries. However, their commercial applications suffer from problems such as a drop in the capacity and discharge voltage during cycling. In this work, the cycling performance of a layered oxide Li1.2Ni0.13Co0.13Mn0.54O2 is improved by integration with spinel LiNi0.5Mn1.5O4 to obtain a layered-spinel composite. Characterization by powder X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) as well as cyclic voltammetry (CV) indicates that delayed degradation of layered Li2MnO3 and the suppressed growth of LiMn2O4-like spinel are responsible for the performance improvement.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- National Natural Science Foundation of China (NSFC)
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1247156
- Journal Information:
- Physical Chemistry Chemical Physics. PCCP (Print), Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Issue: 2 Vol. 17; ISSN 1463-9076; ISSN PPCPFQ
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
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