skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Rotational spectroscopy as a tool to investigate interactions between vibrational polyads in symmetric top molecules: Low-lying states v 8 2 of methyl cyanide, CH3CN

Journal Article · · Journal of Molecular Spectroscopy

Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
AC05-76RLO1830
OSTI ID:
1246618
Journal Information:
Journal of Molecular Spectroscopy, Journal Name: Journal of Molecular Spectroscopy Vol. 312 Journal Issue: C; ISSN 0022-2852
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 31 works
Citation information provided by
Web of Science

References (80)

The Millimeter- and Submillimeter-Wave Spectrum of HC3N in the Ground and Vibrationally Excited States journal November 2000
Molecular spectroscopy and dynamics: a polyad-based perspective journal January 2013
The 2ν8 Band of CH3CN journal August 1993
The rotational spectrum of acrylonitrile up to 1.67THz journal November 2009
The Lamb-dip spectrum of methylcyanide: Precise rotational transition frequencies and improved ground-state rotational parameters journal December 2006
The Infrared Spectrum of Methyl Cyanide Between 850 and 1150 cm−1: Analysis of the ν4, ν7, and 3ν18 Bands with Resonances journal August 1993
Rotational and Rovibrational Spectroscopy of CH 3 NC of the Ground and ν 4 = 1 Vibrational States journal February 2011
New wavenumber calibration tables from heterodyne frequency measurements journal July 1992
The Hot Core around the Low-Mass Protostar IRAS 16293-2422: Scoundrels Rule! journal July 2003
Terahertz and far-infrared synchrotron spectroscopy and global modeling of methyl mercaptan, CH 3 32 SH journal September 2012
High-resolution rotational spectrum of methyl cyanide journal February 1977
Laboratory Characterization and Astrophysical Detection of Vibrationally Excited States of Ethyl Cyanide journal April 2013
Boreal forest fire emissions in fresh Canadian smoke plumes: C 1 -C 10 volatile organic compounds (VOCs), CO 2 , CO, NO 2 , NO, HCN and CH 3 CN journal January 2011
Chemistry of the Organic‐rich Hot Core G327.3−0.6 journal December 2000
Measurements of line intensities and half-widths in the 10-μm bands of journal February 2004
A simultaneous analysis of ν5, ν6, and the ground state of hydrazoic acid journal August 1987
Rotational and rovibrational spectroscopy of the v 8  = 1 and 2 vibrational states of CH 3 NC journal September 2011
High resolution measurements of 14 N, D quadrupole coupling in CH 3 CN and CD 3 CN journal April 1973
Application of cascaded frequency multiplication to molecular spectroscopy journal September 2005
Detection of Millimeter Emission Lines from Interstellar Methyl Cyanide journal August 1971
Vibrationally excited CH3CN and HC3N in Orion journal November 1983
Enhancements in lower stratospheric CH 3 CN observed by the Upper Atmosphere Research Satellite Microwave Limb Sounder following boreal forest fires: ENHANCED MLS CH 3 CN IN STRATOSPHERE journal March 2004
Detection of interstellar ethyl cyanide journal December 1977
Isotopic ethyl cyanide $^{\mathsf{13}}$CH$_\mathsf{3}$CH$_\mathsf{2}$CN, CH$_\mathsf{3}$$^{\mathsf{13}}$CH$_\mathsf{2}$CN, and CH$_\mathsf{3}$CH$_\mathsf{2}$$^{\mathsf{13}}$CN: laboratory rotational spectrum and detection in Orion journal February 2007
Stratospheric CH 3 CN from the UARS Microwave Limb Sounder journal March 2001
Étude en ondes millimétriques de l'acétonitrile CH3C 14N et CH3C 15N : effets de l'interaction de vibration-rotation et de la perturbation quadripolaire journal January 1969
Moment dipolaire de CH 3 CN journal January 1995
Detection of methyl cyanide in Comet Kohoutek journal March 1974
TERAHERTZ SPECTROSCOPY AND GLOBAL ANALYSIS OF H 3 O + journal December 2008
Detection of a branched alkyl molecule in the interstellar medium: iso-propyl cyanide journal September 2014
Microwave Spectra: Methyl Cyanide and Methyl Isocyanide journal December 1947
Interactions between vibrational polyads of propyne, H3CCCH: Rotational and rovibrational spectroscopy of the levels around 1000cm−1 journal July 2009
Detection of Vibrationally Excited Ethyl Cyanide in the Interstellar Medium journal June 2004
Precision broadband Spectroscopy in the Terahertz Region journal May 1994
Submillimeter, Millimeter, and Microwave Spectral line Catalog journal November 1998
Empirical line parameters of NH3 from 4791 to 5294 cm−1 journal August 1996
Resonance between ground and excited vibrational state due to centrifugal distortion coupling in the rotational spectrum of HNCO journal May 1980
Temperature-dependent infrared absorption cross sections of methyl cyanide (acetonitrile) journal December 2005
The Cologne Database for Molecular Spectroscopy, CDMS journal May 2001
Direct l-type doubling transitions in some axially symmetric molecules journal March 1968
Infrared measurements of atmospheric CH 3 CN journal January 2005
Increased complexity in interstellar chemistry: detection and chemical modeling of ethyl formate and n -propyl cyanide in Sagittarius B2(N) journal March 2009
Millimeter wave and terahertz spectra and global fit of torsion–rotation transitions in the ground, first and second excited torsional states of 13 CH 3 OH methanol journal September 2014
An analysis of a preliminary ALMA Orion KL spectrum via the use of complete experimental spectra from the laboratory journal October 2012
Rotational spectra and hyperfine structure of isotopic species of deuterated cyanoacetylene, DC3N journal May 2008
K-Dependence and temperature dependence of N2-, H2-, and He-broadening coefficients for the J=12–11 transition of acetonitrile CH3C14N located near 220.7GHz journal July 2006
Vibration-rotation spectra of CH3CN: The ν7 band and its hot bands near 1040 cm−1 journal April 1984
High-resolution study of the infrared band ν8 of CH3CN journal April 1992
Beam maser spectroscopy on J = 1 → 2, K = 1, and K = 0 transitions in CH 3 CN and CH 313 CN journal January 1982
Detection of circumstellar CH 2 CHCN, CH 2 CN, CH 3 CCH, and H 2 CS journal January 2008
The Cologne Database for Molecular Spectroscopy, CDMS: a useful tool for astronomers and spectroscopists journal May 2005
General Impact Theory of Pressure Broadening journal November 1958
Complex organic molecules in the interstellar medium: IRAM 30 m line survey of Sagittarius B2(N) and (M) journal November 2013
Infrared spectra of gaseous mononitriles: Application to the atmosphere of Titan journal May 1985
Rotational spectrum of acetonitrile CH3C14N and CH3C15N in a doubly excited degenerate vibrational state journal November 1971
Multispectrum analysis of the ν4 band of CH3CN: Positions, intensities, self- and N2-broadening, and pressure-induced shifts journal April 2008
The 2009 edition of the GEISA spectroscopic database journal October 2011
Interactions in symmetric top molecules between vibrational polyads: rotational and rovibrational spectroscopy of low-lying states of propyne, H 3 C–C≡CH journal August 2004
Infrared spectra of gaseous ethanenitrile in the 3500-250 cm−1 region: absolute band intensity and implications for the atmosphere of Titan journal April 1995
The submillimeter-wave rotational spectrum of methyl cyanide: Analysis of the ground and the low-lying excited vibrational states journal February 1988
Computer Measurement of Line Strengths with Application to the Methane Spectrum journal May 1983
Rotational spectra of isotopic species of methyl cyanide, CH 3 CN, in their ground vibrational states up to terahertz frequencies journal August 2009
The rotational spectrum of methyl cyanide-d3 analysis of the low-lying excited vibrational states journal September 1991
Methyl cianide journal January 1978
Broadband rotational spectroscopy of acrylonitrile: Vibrational energies from perturbations journal October 2012
Infrared intensities of acetonitrile journal July 1984
The submillimeterwave rotational spectra of CH3CN and CD3CN. Analysis of the v8 = 1 and v8 = 2 excited vibrational states journal December 1991
The HITRAN2012 molecular spectroscopic database journal November 2013
The Infrared Spectrum of Methyl Cyanide Between 1240 and 1650 cm−1: The Coupled Band System ν3, ν±16, and ν7 + ν±28 journal June 1994
Ground State Constants A0, DK0 and HK0 of CH3CN journal January 1993
Detection of the J = 1 - 0 transition of CH3CN journal April 1983
Ground state spectrum of methylcyanide journal August 2004
The fitting and prediction of vibration-rotation spectra with spin interactions journal August 1991
The v10=1 Level of Propyne, H3CCCH, and Its Interactions with v9=1 and v10=2 journal December 2002
Effective Hamiltonians for the Fermi resonance – Interacting states of C3v molecules journal May 2015
Special issue dedicated to the pioneering work of Drs. Edward A. Cohen and Herbert M. Pickett on spectroscopy relevant to the Earth’s atmosphere and astrophysics journal September 2008
Rotational spectroscopy of isotopic vinyl cyanide, H2CCHCN, in the laboratory and in space journal September 2008
The millimeter wave spectrum of methyl cyanide and the l-type doubling journal January 1961
Introduction to submillimeter, millimeter and microwave spectral line catalog journal July 2010
Methyl Isocyanide: The Low-Frequency Bands ν8 and ν7, and a Determination of the Rotational Constant A0 journal October 1995