Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates

Aytug, Tolga; Meyer III, Harry M.; Ozcan, Soydan; Lu, Yuan; Poole II, Joseph E.

doi:10.1039/C5RA23054C

Title: Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates

Journal Article · Mon Nov 30 00:00:00 EST 2015 · RSC Advances

DOI:https://doi.org/10.1039/C5RA23054C· OSTI ID:1244181

Aytug, Tolga ^[1]; Meyer III, Harry M. ^[1]; Ozcan, Soydan ^[1]; Lu, Yuan ^[1]; Poole II, Joseph E. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Metal oxide nanostructures have emerged as an important family of materials for various device applications. The performance is highly dependent on the morphology of the metal oxide nanostructures. Here we report a completely green approach to prepare indium tin oxide (ITO) nanoparticles using only water and cellulose nanofibril (CNF) in addition to the ITO precursor. Surface hydroxyl groups of the CNFs allow for efficient conjugation of ITO precursors (e.g., metal ions) in aqueous solution. The resulting CNF film allows for controllable spatial arrangement of metal oxide precursors, which results in tunable particle morphology (e.g., nanowires, nanospheres, and octahedral nanoparticles). These ITO nanoparticles can also form conductive and transparent ITO films. This study opens a new perspective on developing metal oxide nanostructures.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; USDA

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1244181

Journal Information:: RSC Advances, Vol. 5, Issue 125; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 4 works

Citation information provided by
Web of Science

References (38)

Nonaqueous Sol–Gel Routes to Metal Oxide Nanoparticles Niederberger, Markus Accounts of Chemical Research, Vol. 40, Issue 9 https://doi.org/10.1021/ar600035e	journal	September 2007
The Future Prospects of Microbial Cellulose in Biomedical Applications Czaja, Wojciech K.; Young, David J.; Kawecki, Marek Biomacromolecules, Vol. 8, Issue 1 https://doi.org/10.1021/bm060620d	journal	January 2007
Embedded indium-tin-oxide nanoelectrodes for efficiency and lifetime enhancement of polymer-based solar cells Yu, Peichen; Chang, Chia-Hua; Su, Ming-Shin Applied Physics Letters, Vol. 96, Issue 15 https://doi.org/10.1063/1.3395395	journal	April 2010
Seed Layer-Assisted Chemical Bath Deposition of CuO Films on ITO-Coated Glass Substrates with Tunable Crystallinity and Morphology Zhu, Changqiong; Panzer, Matthew J. Chemistry of Materials, Vol. 26, Issue 9 https://doi.org/10.1021/cm500762w	journal	April 2014
Protein Microarrays on ITO Surfaces by a Direct Covalent Attachment Scheme Ng, Hou Tee; Fang, Aiping; Huang, Liqun Langmuir, Vol. 18, Issue 16 https://doi.org/10.1021/la0255828	journal	July 2002
Porous Indium Oxide Nanotubes: Layer-by-Layer Assembly on Carbon-Nanotube Templates and Application for Room-Temperature NH3 Gas Sensors Du, N.; Zhang, H.; Chen, B. D. Advanced Materials, Vol. 19, Issue 12 https://doi.org/10.1002/adma.200602128	journal	June 2007
Indium tin oxide nano-particles through an emulsion technique Sujatha Devi, P.; Chatterjee, M.; Ganguli, D. Materials Letters, Vol. 55, Issue 4 https://doi.org/10.1016/S0167-577X(01)00647-4	journal	August 2002
Preparation and Optical Properties of Colloidal, Monodisperse, and Highly Crystalline ITO Nanoparticles Choi, Sang-Il; Nam, Ki Min; Park, Bo Keun Chemistry of Materials, Vol. 20, Issue 8 https://doi.org/10.1021/cm703706m	journal	April 2008
Templated Nanocrystal-Based Porous TiO₂ Films for Next-Generation Electrochemical Capacitors Brezesinski, Torsten; Wang, John; Polleux, Julien Journal of the American Chemical Society, Vol. 131, Issue 5, p. 1802-1809 https://doi.org/10.1021/ja8057309	journal	February 2009
The effect of substrate temperature on the properties of ITO thin films for OLED applications Reddy, V. Sivaji; Das, K.; Dhar, A. Semiconductor Science and Technology, Vol. 21, Issue 12 https://doi.org/10.1088/0268-1242/21/12/043	journal	November 2006
Improving lithium–sulphur batteries through spatial control of sulphur species deposition on a hybrid electrode surface Yao, Hongbin; Zheng, Guangyuan; Hsu, Po-Chun Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4943	journal	May 2014
Cation-Induced Hydrogels of Cellulose Nanofibrils with Tunable Moduli Dong, Hong; Snyder, James F.; Williams, Kristen S. Biomacromolecules, Vol. 14, Issue 9 https://doi.org/10.1021/bm400993f	journal	August 2013
Microbial cellulose—the natural power to heal wounds Czaja, W.; Krystynowicz, A.; Bielecki, S. Biomaterials, Vol. 27, Issue 2 https://doi.org/10.1016/j.biomaterials.2005.07.035	journal	January 2006
ITO nanowires and nanoparticles for transparent films Dattoli, Eric N.; Lu, Wei MRS Bulletin, Vol. 36, Issue 10 https://doi.org/10.1557/mrs.2011.212	journal	October 2011
Transparent conducting oxide semiconductors for transparent electrodes Minami, Tadatsugu Semiconductor Science and Technology, Vol. 20, Issue 4 https://doi.org/10.1088/0268-1242/20/4/004	journal	March 2005
A Novel Route to Octahedral In ₂ O ₃ Particles Exhibiting Near Band Emission Zhang, Wu; Huang, Zhen; Li, Ting Chemistry Letters, Vol. 34, Issue 1 https://doi.org/10.1246/cl.2005.118	journal	January 2005
Microfibrillated cellulose and new nanocomposite materials: a review Siró, István; Plackett, David Cellulose, Vol. 17, Issue 3 https://doi.org/10.1007/s10570-010-9405-y	journal	February 2010
Unusually High Performance Photovoltaic Cell Based on a [60]Fullerene Metal Cluster−Porphyrin Dyad SAM on an ITO Electrode Cho, Youn-Jaung; Ahn, Tae Kyu; Song, Hyunjoon Journal of the American Chemical Society, Vol. 127, Issue 8 https://doi.org/10.1021/ja044847x	journal	March 2005
Three-Color, Tunable, Organic Light-Emitting Devices Shen, Z. Science, Vol. 276, Issue 5321 https://doi.org/10.1126/science.276.5321.2009	journal	June 1997
High-yield synthesis of single crystalline tin-doped indium oxide octahedrons via a low-temperature, catalyst-free process Wei, Ming; Zhi, Dan; MacManus-Driscoll, Judith L. Nanotechnology, Vol. 17, Issue 14 https://doi.org/10.1088/0957-4484/17/14/027	journal	June 2006
Assembly of mesoporous indium tin oxide electrodes from nano-hydroxide building blocks Liu, Yujing; Štefanić, Goran; Rathouský, Jiří Chemical Science, Vol. 3, Issue 7 https://doi.org/10.1039/c2sc20042b	journal	January 2012
Direct preparation of anatase TiO2 nanotubes in porous alumina membranes Imai, Hiroaki; Takei, Yuko; Shimizu, Kazuhiko Journal of Materials Chemistry, Vol. 9, Issue 12 https://doi.org/10.1039/a906005g	journal	January 1999
Crystallization of Indium Tin Oxide Nanoparticles: From Cooperative Behavior to Individuality Ba, Jianhua; Feldhoff, Armin; Fattakhova Rohlfing, Dina Small, Vol. 3, Issue 2 https://doi.org/10.1002/smll.200600425	journal	February 2007
Progress in Modification of Indium-Tin Oxide/Organic Interfaces for Organic Light-Emitting Diodes Wu, Qi-Hui Critical Reviews in Solid State and Materials Sciences, Vol. 38, Issue 4 https://doi.org/10.1080/10408436.2011.654006	journal	January 2013
Nonaqueous Synthesis of Uniform Indium Tin Oxide Nanocrystals and Their Electrical Conductivity in Dependence of the Tin Oxide Concentration Ba, Jianhua; Fattakhova Rohlfing, Dina; Feldhoff, Armin Chemistry of Materials, Vol. 18, Issue 12 https://doi.org/10.1021/cm060548q	journal	June 2006
A Facile Solution-Phase Approach to Transparent and Conducting ITO Nanocrystal Assemblies Lee, Jonghun; Lee, Sunghwan; Li, Guanglai Journal of the American Chemical Society, Vol. 134, Issue 32 https://doi.org/10.1021/ja3044807	journal	August 2012
Inorganic Hollow Nanotube Aerogels by Atomic Layer Deposition onto Native Nanocellulose Templates Korhonen, Juuso T.; Hiekkataipale, Panu; Malm, Jari ACS Nano, Vol. 5, Issue 3 https://doi.org/10.1021/nn200108s	journal	February 2011
A Surface Sol−Gel Process of TiO ₂ and Other Metal Oxide Films with Molecular Precision Ichinose, Izumi; Senzu, Hiroyuki; Kunitake, Toyoki Chemistry of Materials, Vol. 9, Issue 6 https://doi.org/10.1021/cm970008g	journal	June 1997
Photocatalytic properties of visible-light enabling layered titanium oxide/tin indium oxide films Wu, K.; Cho, T. Applied Catalysis B: Environmental, Vol. 80, Issue 3-4 https://doi.org/10.1016/j.apcatb.2007.09.045	journal	May 2008
Effects of temperature on indium tin oxide particles synthesized by co-precipitation Li, Shitao; Qiao, Xueliang; Chen, Jianguo Journal of Crystal Growth, Vol. 289, Issue 1 https://doi.org/10.1016/j.jcrysgro.2005.11.012	journal	March 2006
A room temperature indium tin oxide/quartz crystal microbalance gas sensor for nitric oxide Hu, Jianqiao; Zhu, Furong; Zhang, Jian Sensors and Actuators B: Chemical, Vol. 93, Issue 1-3 https://doi.org/10.1016/S0925-4005(03)00186-2	journal	August 2003
Optical Transmittance of Indium Tin Oxide Nanoparticles Prepared by Laser-Induced Fragmentation in Water Usui, Hiroyuki; Sasaki, Takeshi; Koshizaki, Naoto The Journal of Physical Chemistry B, Vol. 110, Issue 26 https://doi.org/10.1021/jp061866f	journal	June 2006
SnO ₂ −In ₂ O ₃ Nanocomposites as Semiconductor Gas Sensors for CO and NO _x Detection McCue, Justin T.; Ying, Jackie Y. Chemistry of Materials, Vol. 19, Issue 5 https://doi.org/10.1021/cm0617283	journal	March 2007
Low temperature high sensor response nano gas sensor using ITO nanofibers Xu, Shiyou; Shi, Yong Sensors and Actuators B: Chemical, Vol. 143, Issue 1 https://doi.org/10.1016/j.snb.2009.08.057	journal	December 2009
Atomic Layer Deposition of TiO ₂ on Mesoporous nanoITO: Conductive Core–Shell Photoanodes for Dye-Sensitized Solar Cells Alibabaei, Leila; Farnum, Byron H.; Kalanyan, Berç Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl5006433	journal	May 2014
Growth and luminescence of zinc-blende-structured ZnSe nanowires by metal-organic chemical vapor deposition Zhang, X. T.; Liu, Z.; Leung, Y. P. Applied Physics Letters, Vol. 83, Issue 26 https://doi.org/10.1063/1.1638633	journal	December 2003
Cellulose Nanocrystals: Chemistry, Self-Assembly, and Applications Habibi, Youssef; Lucia, Lucian A.; Rojas, Orlando J. Chemical Reviews, Vol. 110, Issue 6 https://doi.org/10.1021/cr900339w	journal	June 2010
Keimbildung in übersättigten Gebilden Volmer, M.; Weber, Α. Zeitschrift für Physikalische Chemie, Vol. 119U, Issue 1 https://doi.org/10.1515/zpch-1926-11927	journal	January 1926

Similar Records

Defect engineered d{sup 0} ferromagnetism in tin-doped indium oxide nanostructures and nanocrystalline thin-films

Journal Article · Fri Aug 21 00:00:00 EDT 2015 · Journal of Applied Physics · OSTI ID:1244181

Sarkar, Ayan; Ghosh, Shyamsundar; Mandal, Guruprasad; +4 more

Fabrication and characterization of copper oxide (CuO)–gold (Au)–titania (TiO{sub 2}) and copper oxide (CuO)–gold (Au)–indium tin oxide (ITO) nanowire heterostructures

Journal Article · Wed Oct 15 00:00:00 EDT 2014 · Materials Characterization · OSTI ID:1244181

Chopra, Nitin; Shi, Wenwu; Lattner, Andrew

Parameters study on the growth of GaAs nanowires on indium tin oxide by metal-organic chemical vapor deposition

Journal Article · Mon Mar 07 00:00:00 EST 2016 · Journal of Applied Physics · OSTI ID:1244181

Wu, Dan; Tang, Xiaohong; Li, Xianqiang; +2 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY

Title: Tunable morphologies of indium tin oxide nanostructures using nanocellulose templates

Citation Formats

References (38)

Similar Records

Related Subjects