Structure–kinetic relationship study of organozinc reagents
Phenylzinc reagents prepared from various zinc halides show distinct kinetic features in the palladium-catalyzed Negishi-type oxidative coupling reaction, in which the phenylzinc reagent prepared from ZnI2 gives the highest rate. In situ infrared and X-ray absorption spectroscopy studies show that the higher reaction rate was observed for longer Zn–C bond distances.
- Research Organization:
- Argonne National Laboratory (ANL)
- Sponsoring Organization:
- Wuhan University; Argonne National Laboratory - Chemical Sciences and Engineering Division; Chinese Academy of Sciences (CAS); National Natural Science Foundation of China (NSFC); Materials Research Collaborative Access Team (MRCAT); USDOE Office of Science - Office of Basic Energy Sciences
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1241304
- Journal Information:
- ChemComm, Journal Name: ChemComm Vol. 50; ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
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