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Title: Analysis and Simulation of a Blue Energy Cycle

Journal Article · · Renewable Energy
 [1];  [1];  [1];  [2];  [3];  [3];  [3];  [3];  [3]
  1. Georgia Inst. of Technology, Atlanta, GA (United States)
  2. Prairie View A & M Univ., Prairie View, TX (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The mixing process of fresh water and seawater releases a significant amount of energy and is a potential source of renewable energy. The so called ‘blue energy’ or salinity-gradient energy can be harvested by a device consisting of carbon electrodes immersed in an electrolyte solution, based on the principle of capacitive double layer expansion (CDLE). In this study, we have investigated the feasibility of energy production based on the CDLE principle. Experiments and computer simulations were used to study the process. Mesoporous carbon materials, synthesized at the Oak Ridge National Laboratory, were used as electrode materials in the experiments. Neutron imaging of the blue energy cycle was conducted with cylindrical mesoporous carbon electrodes and 0.5 M lithium chloride as the electrolyte solution. For experiments conducted at 0.6 V and 0.9 V applied potential, a voltage increase of 0.061 V and 0.054 V was observed, respectively. From sequences of neutron images obtained for each step of the blue energy cycle, information on the direction and magnitude of lithium ion transport was obtained. A computer code was developed to simulate the process. Experimental data and computer simulations allowed us to predict energy production.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)
Sponsoring Organization:
Work for Others (WFO); USDOE Laboratory Directed Research and Development (LDRD) Program
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1240530
Alternate ID(s):
OSTI ID: 1348261
Journal Information:
Renewable Energy, Vol. 91; ISSN 0960-1481
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

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Cited By (3)

Blue Energy and Desalination with Nanoporous Carbon Electrodes: Capacitance from Molecular Simulations to Continuous Models journal April 2018
Electrosorption at functional interfaces: from molecular-level interactions to electrochemical cell design journal January 2017
Potential limits of capacitive deionization and membrane capacitive deionization for water electrolysis journal May 2019

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