Flow-enhanced solution printing of all-polymer solar cells

Diao, Ying; Zhou, Yan; Kurosawa, Tadanori; Shaw, Leo; Wang, Cheng; Park, Steve; Guo, Yikun; Reinspach, Julia A.; Gu, Kevin; Gu, Xiaodan; Tee, Benjamin C. K.; Pang, Changhyun; Yan, Hongping; Zhao, Dahui; Toney, Michael F.; Mannsfeld, Stefan C. B.; Bao, Zhenan

doi:10.1038/ncomms8955

Flow-enhanced solution printing of all-polymer solar cells

Journal Article · Wed Aug 12 00:00:00 EDT 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms8955· OSTI ID:1238256

Diao, Ying ^[1]; Zhou, Yan ^[1]; Kurosawa, Tadanori ^[2]; ^[2]; ^[3]; Park, Steve ^[2]; Guo, Yikun ^[4]; Reinspach, Julia A. ^[2]; Gu, Kevin ^[2]; Gu, Xiaodan ^[1]; Tee, Benjamin C. K. ^[2]; Pang, Changhyun ^[5]; Yan, Hongping ^[1]; Zhao, Dahui ^[4]; Toney, Michael F. ^[6]; Mannsfeld, Stefan C. B. ^[7]; Bao, Zhenan ^[1]

SLAC National Accelerator Lab., Menlo Park, CA (United States); Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Peking Univ., Beijing (China)
Sungkyunkwan Univ. (SKKU), Suwon (Republic of Korea); Stanford Univ., Stanford, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States); Dresden Univ. of Technology, Dresden (Germany)

Morphology control of solution coated solar cell materials presents a key challenge limiting their device performance and commercial viability. Here we present a new concept for controlling phase separation during solution printing using an all-polymer bulk heterojunction solar cell as a model system. The key aspect of our method lies in the design of fluid flow using a microstructured printing blade, on the basis of the hypothesis of flow-induced polymer crystallization. Our flow design resulted in a similar to 90% increase in the donor thin film crystallinity and reduced microphase separated donor and acceptor domain sizes. The improved morphology enhanced all metrics of solar cell device performance across various printing conditions, specifically leading to higher short-circuit current, fill factor, open circuit voltage and significantly reduced device-to-device variation. However, we expect our design concept to have broad applications beyond all-polymer solar cells because of its simplicity and versatility.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC03-76SF00515

OSTI ID:: 1238256

Alternate ID(s):: OSTI ID: 1260952

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 6; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells Eperon, Giles E.; Burlakov, Victor M.; Docampo, Pablo Advanced Functional Materials, Vol. 24, Issue 1, p. 151-157 https://doi.org/10.1002/adfm.201302090	journal	September 2013
Relationship between Crystalline Order and Exciton Diffusion Length in Molecular Organic Semiconductors Lunt, Richard R.; Benziger, Jay B.; Forrest, Stephen R. Advanced Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adma.200902827	journal	March 2010
Nanoparticle Stripes, Grids, and Ribbons Produced by Flow Coating Kim, Hyun Suk; Lee, Cheol Hee; Sudeep, P. K. Advanced Materials, Vol. 22, Issue 41 https://doi.org/10.1002/adma.201001892	journal	September 2010
Stability of Polymer Solar Cells Jørgensen, Mikkel; Norrman, Kion; Gevorgyan, Suren A. Advanced Materials, Vol. 24, Issue 5 https://doi.org/10.1002/adma.201104187	journal	December 2011
All-Polymer Bulk Heterojuction Solar Cells with 4.8% Efficiency Achieved by Solution Processing from a Co-Solvent Earmme, Taeshik; Hwang, Ye-Jin; Subramaniyan, Selvam Advanced Materials, Vol. 26, Issue 35, p. 6080-6085 https://doi.org/10.1002/adma.201401490	journal	July 2014
Real-time orientation and crystallinity measurements during the isotactic polypropylene film-casting process Lamberti, Gaetano; Brucato, Valerio Journal of Polymer Science Part B: Polymer Physics, Vol. 41, Issue 9 https://doi.org/10.1002/polb.10411	journal	March 2003
Roll-to-Roll fabrication of large area functional organic materials Søndergaard, Roar R.; Hösel, Markus; Krebs, Frederik C. Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 1 https://doi.org/10.1002/polb.23192	journal	October 2012
Polymer donor–polymer acceptor (all-polymer) solar cells Facchetti, Antonio Materials Today, Vol. 16, Issue 4 https://doi.org/10.1016/j.mattod.2013.04.005	journal	April 2013
Measurement and modelling of the film casting process 1. Width distribution along draw direction Lamberti, G.; Titomanlio, G.; Brucato, V. Chemical Engineering Science, Vol. 56, Issue 20 https://doi.org/10.1016/s0009-2509(01)00286-x	journal	October 2001
Controlling the Morphology and Performance of Bulk Heterojunctions in Solar Cells. Lessons Learned from the Benchmark Poly(3-hexylthiophene):[6,6]-Phenyl-C ₆₁ -butyric Acid Methyl Ester System Dang, Minh Trung; Hirsch, Lionel; Wantz, Guillaume Chemical Reviews, Vol. 113, Issue 5 https://doi.org/10.1021/cr300005u	journal	January 2013
Quantitative Determination of Organic Semiconductor Microstructure from the Molecular to Device Scale Rivnay, Jonathan; Mannsfeld, Stefan C. B.; Miller, Chad E. Chemical Reviews, Vol. 112, Issue 10 https://doi.org/10.1021/cr3001109	journal	June 2012
Bulk Heterojunction Solar Cells: Morphology and Performance Relationships Huang, Ye; Kramer, Edward J.; Heeger, Alan J. Chemical Reviews, Vol. 114, Issue 14 https://doi.org/10.1021/cr400353v	journal	May 2014
Time-Resolved Structural Evolution of Additive-Processed Bulk Heterojunction Solar Cells Rogers, James T.; Schmidt, Kristin; Toney, Michael F. Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja2104747	journal	February 2012
Understanding Polymorphism in Organic Semiconductor Thin Films through Nanoconfinement Diao, Ying; Lenn, Kristina M.; Lee, Wen-Ya Journal of the American Chemical Society, Vol. 136, Issue 49 https://doi.org/10.1021/ja507179d	journal	November 2014
From Convective Assembly to Landau−Levich Deposition of Multilayered Phospholipid Films of Controlled Thickness Le Berre, Maël; Chen, Yong; Baigl, Damien Langmuir, Vol. 25, Issue 5 https://doi.org/10.1021/la803646e	journal	March 2009
Mechanism for Stripe Pattern Formation on Hydrophilic Surfaces by Using Convective Self-Assembly Watanabe, Satoshi; Inukai, Koji; Mizuta, Shunsuke Langmuir, Vol. 25, Issue 13 https://doi.org/10.1021/la900315h	journal	July 2009
Quantification of Thin Film Crystallographic Orientation Using X-ray Diffraction with an Area Detector Baker, Jessy L.; Jimison, Leslie H.; Mannsfeld, Stefan Langmuir, Vol. 26, Issue 11 https://doi.org/10.1021/la904840q	journal	June 2010
Structure Development during Shear Flow-Induced Crystallization of i-PP: In-Situ Small-Angle X-ray Scattering Study Somani, Rajesh H.; Hsiao, Benjamin S.; Nogales, Aurora Macromolecules, Vol. 33, Issue 25 https://doi.org/10.1021/ma001124z	journal	December 2000
Nanomorphology of Bulk Heterojunction Photovoltaic Thin Films Probed with Resonant Soft X-ray Scattering Swaraj, Sufal; Wang, Cheng; Yan, Hongping Nano Letters, Vol. 10, Issue 8 https://doi.org/10.1021/nl1009266	journal	August 2010
Molecular Order in High-Efficiency Polymer/Fullerene Bulk Heterojunction Solar Cells Hammond, Matthew R.; Kline, R. Joseph; Herzing, Andrew A. ACS Nano, Vol. 5, Issue 10 https://doi.org/10.1021/nn202951e	journal	September 2011
Solution-processed small-molecule solar cells with 6.7% efficiency Sun, Yanming; Welch, Gregory C.; Leong, Wei Lin Nature Materials, Vol. 11, Issue 1, p. 44-48 https://doi.org/10.1038/nmat3160	journal	November 2011
Solar cells with one-day energy payback for the factories of the future Espinosa, Nieves; Hösel, Markus; Angmo, Dechan Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/c1ee02728j	journal	January 2012
Flow induced crystallisation of polymers Lamberti, Gaetano Chem. Soc. Rev., Vol. 43, Issue 7 https://doi.org/10.1039/c3cs60308c	journal	January 2014
Towards low-cost, environmentally friendly printed chalcopyrite and kesterite solar cells Azimi, Hamed; Hou, Yi; Brabec, Christoph J. Energy Environ. Sci., Vol. 7, Issue 6 https://doi.org/10.1039/c3ee43865a	journal	January 2014
Comparison of the device physics principles of planar and radial p-n junction nanorod solar cells Kayes, Brendan M.; Atwater, Harry A.; Lewis, Nathan S. Journal of Applied Physics, Vol. 97, Issue 11, Article No. 114302 https://doi.org/10.1063/1.1901835	journal	June 2005
Soft x-ray scattering facility at the Advanced Light Source with real-time data processing and analysis Gann, E.; Young, A. T.; Collins, B. A. Review of Scientific Instruments, Vol. 83, Issue 4 https://doi.org/10.1063/1.3701831	journal	April 2012
Observation of Polymer Conformation Hysteresis in Extensional Flow Schroeder, C. M. Science, Vol. 301, Issue 5639 https://doi.org/10.1126/science.1086070	journal	September 2003
Phase Separation in Bulk Heterojunctions of Semiconducting Polymers and Fullerenes for Photovoltaics Treat, Neil D.; Chabinyc, Michael L. Annual Review of Physical Chemistry, Vol. 65, Issue 1 https://doi.org/10.1146/annurev-physchem-040513-103712	journal	April 2014
“Solvent Annealing” Effect in Polymer Solar Cells Based on Poly(3-hexylthiophene) and Methanofullerenes Li, G.; Yao, Y.; Yang, H. Advanced Functional Materials, Vol. 17, Issue 10, p. 1636-1644 https://doi.org/10.1002/adfm.200600624	journal	July 2007
High‐Performance Organic Thin‐Film Transistors through Solution‐Sheared Deposition of Small‐Molecule Organic Semiconductors Becerril, Héctor A.; Roberts, Mark E.; Liu, Zihong Advanced Materials, Vol. 20, Issue 13, p. 2588-2594 https://doi.org/10.1002/adma.200703120	journal	July 2008
A Mechanistic Understanding of Processing Additive-Induced Efficiency Enhancement in Bulk Heterojunction Organic Solar Cells Schmidt, Kristin; Tassone, Christopher J.; Niskala, Jeremy R. Advanced Materials, Vol. 26, Issue 2 https://doi.org/10.1002/adma.201303622	journal	October 2013
High Performance All-Polymer Solar Cell via Polymer Side-Chain Engineering Zhou, Yan; Kurosawa, Tadanori; Ma, Wei Advanced Materials, Vol. 26, Issue 22 https://doi.org/10.1002/adma.201306242	journal	March 2014
Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in PTB7:PC ₇₁ BM Solar Cells Collins, Brian A.; Li, Zhe; Tumbleston, John R. Advanced Energy Materials, Vol. 3, Issue 1 https://doi.org/10.1002/aenm.201200377	journal	October 2012
Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells Zhou, Nanjia; Lin, Hui; Lou, Sylvia J. Advanced Energy Materials, Vol. 4, Issue 3 https://doi.org/10.1002/aenm.201300785	journal	October 2013
All-Polymer Solar Cells from Perylene Diimide Based Copolymers: Material Design and Phase Separation Control Zhou, Erjun; Cong, Junzi; Wei, Qingshuo Angewandte Chemie International Edition, Vol. 50, Issue 12, p. 2799-2803 https://doi.org/10.1002/anie.201005408	journal	February 2011
Flow-induced crystallization during isotactic polypropylene film casting Lamberti, Gaetano Polymer Engineering & Science, Vol. 51, Issue 5 https://doi.org/10.1002/pen.21891	journal	January 2011
An experimental study of the kinetics of polymer crystallization during shear flow Lagasse, R. R.; Maxwell, B. Polymer Engineering and Science, Vol. 16, Issue 3 https://doi.org/10.1002/pen.760160312	journal	March 1976
Time dependence of shear and normal stresses of polystyrene and poly(ethylene oxide) solutions Laufer, Z.; Jalink, H. L.; Staverman, A. J. Journal of Polymer Science: Polymer Chemistry Edition, Vol. 11, Issue 11 https://doi.org/10.1002/pol.1973.170111119	journal	November 1973
Flow-induced mixing, demixing, and phase transitions in polymeric fluids Larson, R. G. Rheologica Acta, Vol. 31, Issue 6 https://doi.org/10.1007/BF00367006	journal	January 1992
Hydrodynamically induced crystallization of polymers from solution: II. The effect of secondary flow Pennings, A. J.; Mark, J. M. A. A.; Booij, H. C. Kolloid-Zeitschrift & Zeitschrift für Polymere, Vol. 236, Issue 2 https://doi.org/10.1007/BF02086621	journal	February 1970
Hydrodynamically induced crystallization of polymers from solution: III. Morphology Pennings, A. J.; Mark, J. M. A. A.; Kiel, A. M. Kolloid-Zeitschrift & Zeitschrift für Polymere, Vol. 237, Issue 2 https://doi.org/10.1007/BF02086847	journal	April 1970
Hydrodynamically induced crystallization of polymers from solution: VII.: On the origin of persistent lamellar overgrowth of Shish-kebab fibers Pennings, A. J.; Lageveen, R.; de Vries, R. S. Colloid and Polymer Science, Vol. 255, Issue 6 https://doi.org/10.1007/bf01549739	journal	June 1977
Measurement and modelling of the film casting process 1. Width distribution along draw direction Lamberti, G.; Titomanlio, G.; Brucato, V. Chemical Engineering Science, Vol. 56, Issue 20 https://doi.org/10.1016/S0009-2509(01)00286-X	journal	October 2001
Relation between absorption and crystallinity of poly(3-hexylthiophene)/fullerene films for plastic solar cells Zhokhavets, Uladzimir; Erb, Tobias; Gobsch, Gerhard Chemical Physics Letters, Vol. 418, Issue 4-6 https://doi.org/10.1016/j.cplett.2005.11.020	journal	February 2006
Fabrication and processing of polymer solar cells: A review of printing and coating techniques Krebs, Frederik C. Solar Energy Materials and Solar Cells, Vol. 93, Issue 4, p. 394-412 https://doi.org/10.1016/j.solmat.2008.10.004	journal	April 2009
All polymer photovoltaics: From small inverted devices to large roll-to-roll coated and printed solar cells Liu, Yao; Larsen-Olsen, Thue T.; Zhao, Xingang Solar Energy Materials and Solar Cells, Vol. 112 https://doi.org/10.1016/j.solmat.2013.01.025	journal	May 2013
Comparison of the Photovoltaic Characteristics and Nanostructure of Fullerenes Blended with Conjugated Polymers with Siloxane-Terminated and Branched Aliphatic Side Chains Kim, Do Hwan; Ayzner, Alexander L.; Appleton, Anthony L. Chemistry of Materials, Vol. 25, Issue 3 https://doi.org/10.1021/cm303572d	journal	January 2013
Side-Chain Engineering of Isoindigo-Containing Conjugated Polymers Using Polystyrene for High-Performance Bulk Heterojunction Solar Cells Fang, Lei; Zhou, Yan; Yao, Yu-Xing Chemistry of Materials, Vol. 25, Issue 24 https://doi.org/10.1021/cm4024259	journal	December 2013
Polymer-Fullerene Miscibility: A Metric for Screening New Materials for High-Performance Organic Solar Cells Treat, Neil D.; Varotto, Alessandro; Takacs, Christopher J. Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja305875u	journal	September 2012
Dependence of Exciton Diffusion Length on Crystalline Order in Conjugated Polymers Sim, Myungsun; Shin, Jisoo; Shim, Chiyeoung The Journal of Physical Chemistry C, Vol. 118, Issue 2 https://doi.org/10.1021/jp409776s	journal	December 2013
Cheap solar cells tempt businesses Van Noorden, Richard Nature, Vol. 513, Issue 7519 https://doi.org/10.1038/513470a	journal	September 2014
Tuning charge transport in solution-sheared organic semiconductors using lattice strain Giri, Gaurav; Verploegen, Eric; Mannsfeld, Stefan C. B. Nature, Vol. 480, Issue 7378, p. 504-508 https://doi.org/10.1038/nature10683	journal	December 2011
Efficient planar heterojunction perovskite solar cells by vapour deposition Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J. Nature, Vol. 501, Issue 7467, p. 395-398 https://doi.org/10.1038/nature12509	journal	September 2013
Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells Liu, Yuhang; Zhao, Jingbo; Li, Zhengke Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6293	journal	November 2014
A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells Kim, Youngkyoo; Cook, Steffan; Tuladhar, Sachetan M. Nature Materials, Vol. 5, Issue 3 https://doi.org/10.1038/nmat1574	journal	February 2006
Observation of long-range exciton diffusion in highly ordered organic semiconductors Najafov, H.; Lee, B.; Zhou, Q. Nature Materials, Vol. 9, Issue 11 https://doi.org/10.1038/nmat2872	journal	October 2010
Polarized X-ray scattering reveals non-crystalline orientational ordering in organic films Collins, B. A.; Cochran, J. E.; Yan, H. Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3310	journal	April 2012
Solution coating of large-area organic semiconductor thin films with aligned single-crystalline domains Diao, Ying; Tee, Benjamin C-K.; Giri, Gaurav Nature Materials, Vol. 12, Issue 7 https://doi.org/10.1038/nmat3650	journal	June 2013
Microstructure formation in molecular and polymer semiconductors assisted by nucleation agents Treat, Neil D.; Nekuda Malik, Jennifer A.; Reid, Obadiah Nature Materials, Vol. 12, Issue 7 https://doi.org/10.1038/nmat3655	journal	June 2013
Polymer solar cells Li, Gang; Zhu, Rui; Yang, Yang Nature Photonics, Vol. 6, Issue 3 https://doi.org/10.1038/nphoton.2012.11	journal	February 2012
Solar cells with one-day energy payback for the factories of the future Espinosa, Nieves; Hösel, Markus; Angmo, Dechan Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE02728J	journal	January 2012
Soft X-ray characterisation of organic semiconductor films McNeill, Christopher R.; Ade, Harald J. Mater. Chem. C, Vol. 1, Issue 2 https://doi.org/10.1039/C2TC00001F	journal	January 2013
Flow induced crystallisation of polymers Lamberti, Gaetano Chem. Soc. Rev., Vol. 43, Issue 7 https://doi.org/10.1039/C3CS60308C	journal	January 2014
Towards low-cost, environmentally friendly printed chalcopyrite and kesterite solar cells Azimi, Hamed; Hou, Yi; Brabec, Christoph J. Energy Environ. Sci., Vol. 7, Issue 6 https://doi.org/10.1039/C3EE43865A	journal	January 2014
Probing the interfacial molecular packing in TIPS-pentacene organic semiconductors by surface enhanced Raman scattering Xu, Jie; Diao, Ying; Zhou, Dongshan J. Mater. Chem. C, Vol. 2, Issue 16 https://doi.org/10.1039/C3TC32581D	journal	January 2014
Morphology control strategies for solution-processed organic semiconductor thin films Diao, Ying; Shaw, Leo; Bao, Zhenan Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00688G	journal	January 2014
Performance, morphology and photophysics of high open-circuit voltage, low band gap all-polymer solar cells Deshmukh, Kedar D.; Qin, Tianshi; Gallaher, Joseph K. Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE03059A	journal	January 2015
In situ measurement of power conversion efficiency and molecular ordering during thermal annealing in P3HT:PCBM bulk heterojunction solar cells Treat, Neil D.; Shuttle, Chris G.; Toney, Michael F. Journal of Materials Chemistry, Vol. 21, Issue 39 https://doi.org/10.1039/c1jm12677f	journal	January 2011
Polymer Solar Cells Zhuravleva, T. S.; Vannikov, A. V. Materials Science Forum, Vol. 21 https://doi.org/10.4028/www.scientific.net/msf.21.203	journal	January 1991

Cited By (64)

Recent Progress in Inkjet‐Printed Thin‐Film Transistors Chung, Seungjun; Cho, Kyungjune; Lee, Takhee Advanced Science, Vol. 6, Issue 6 https://doi.org/10.1002/advs.201801445	journal	January 2019
The meniscus-guided deposition of semiconducting polymers Gu, Xiaodan; Shaw, Leo; Gu, Kevin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02833-9	journal	February 2018
Soft crystal martensites: An in situ resonant soft x-ray scattering study of a liquid crystal martensitic transformation Jin, Hyeong Min; Li, Xiao; Dolan, James A. Science Advances, Vol. 6, Issue 13 https://doi.org/10.1126/sciadv.aay5986	journal	March 2020
High-resolution patterning of solution-processable materials via externally engineered pinning of capillary bridges Li, Shunpu; Chun, Youngtea; Zhao, Shuo Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.17384	text	January 2018
Solution-Processed Nanoporous Organic Semiconductor Thin Films: Toward Health and Environmental Monitoring of Volatile Markers Zhang, Fengjiao; Qu, Ge; Mohammadi, Erfan Advanced Functional Materials, Vol. 27, Issue 23 https://doi.org/10.1002/adfm.201701117	journal	May 2017
Effect of Nonconjugated Spacers on Mechanical Properties of Semiconducting Polymers for Stretchable Transistors Mun, Jaewan; Wang, Ging-Ji Nathan; Oh, Jin Young Advanced Functional Materials, Vol. 28, Issue 43 https://doi.org/10.1002/adfm.201804222	journal	September 2018
Revealing the Impact of F4-TCNQ as Additive on Morphology and Performance of High-Efficiency Nonfullerene Organic Solar Cells Xiong, Yuan; Ye, Long; Gadisa, Abay Advanced Functional Materials, Vol. 29, Issue 1 https://doi.org/10.1002/adfm.201806262	journal	November 2018
Imide‐Functionalized Heteroarene‐Based n‐Type Terpolymers Incorporating Intramolecular Noncovalent Sulfur∙∙∙Oxygen Interactions for Additive‐Free All‐Polymer Solar Cells Sun, Huiliang; Liu, Bin; Koh, Chang Woo Advanced Functional Materials, Vol. 29, Issue 42 https://doi.org/10.1002/adfm.201903970	journal	August 2019
Epidermal Inorganic Optoelectronics for Blood Oxygen Measurement Li, Haicheng; Xu, Yun; Li, Xiaomin Advanced Healthcare Materials, Vol. 6, Issue 9 https://doi.org/10.1002/adhm.201601013	journal	February 2017
A Vinylene-Bridged Perylenediimide-Based Polymeric Acceptor Enabling Efficient All-Polymer Solar Cells Processed under Ambient Conditions Guo, Yikun; Li, Yunke; Awartani, Omar Advanced Materials, Vol. 28, Issue 38 https://doi.org/10.1002/adma.201602387	journal	August 2016
Improved Performance of All-Polymer Solar Cells Enabled by Naphthodiperylenetetraimide-Based Polymer Acceptor Guo, Yikun; Li, Yunke; Awartani, Omar Advanced Materials, Vol. 29, Issue 26 https://doi.org/10.1002/adma.201700309	journal	May 2017
Imaging Nanoscale Morphology of Semiconducting Polymer Films with Photoemission Electron Microscopy Neff, Andreas; Niefind, Falk; Abel, Bernd Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201701012	journal	May 2017
Surpassing 10% Efficiency Benchmark for Nonfullerene Organic Solar Cells by Scalable Coating in Air from Single Nonhalogenated Solvent Ye, Long; Xiong, Yuan; Zhang, Qianqian Advanced Materials, Vol. 30, Issue 8 https://doi.org/10.1002/adma.201705485	journal	January 2018
Balanced Partnership between Donor and Acceptor Components in Nonfullerene Organic Solar Cells with >12% Efficiency Lin, Yuze; Zhao, Fuwen; Prasad, Shyamal K. K. Advanced Materials, Vol. 30, Issue 16 https://doi.org/10.1002/adma.201706363	journal	March 2018
Achieving Balanced Crystallinity of Donor and Acceptor by Combining Blade-Coating and Ternary Strategies in Organic Solar Cells Zhang, Lin; Xu, Xianbin; Lin, Baojun Advanced Materials, Vol. 30, Issue 51 https://doi.org/10.1002/adma.201805041	journal	October 2018
High‐Performance All‐Polymer Solar Cells Enabled by an n‐Type Polymer Based on a Fluorinated Imide‐Functionalized Arene Sun, Huiliang; Tang, Yumin; Koh, Chang Woo Advanced Materials, Vol. 31, Issue 15 https://doi.org/10.1002/adma.201807220	journal	February 2019
Single‐Junction Polymer Solar Cells with 16.35% Efficiency Enabled by a Platinum(II) Complexation Strategy Xu, Xiaopeng; Feng, Kui; Bi, Zhaozhao Advanced Materials, Vol. 31, Issue 29 https://doi.org/10.1002/adma.201901872	journal	May 2019
Aggregation‐Induced Multilength Scaled Morphology Enabling 11.76% Efficiency in All‐Polymer Solar Cells Using Printing Fabrication Zhu, Lei; Zhong, Wenkai; Qiu, Chaoqun Advanced Materials, Vol. 31, Issue 41 https://doi.org/10.1002/adma.201902899	journal	August 2019
Conjugated Carbon Cyclic Nanorings as Additives for Intrinsically Stretchable Semiconducting Polymers Mun, Jaewan; Kang, Jiheong; Zheng, Yu Advanced Materials, Vol. 31, Issue 42 https://doi.org/10.1002/adma.201903912	journal	September 2019
A Narrow‐Bandgap n‐Type Polymer Semiconductor Enabling Efficient All‐Polymer Solar Cells Shi, Shengbin; Chen, Peng; Chen, Yao Advanced Materials, Vol. 31, Issue 46 https://doi.org/10.1002/adma.201905161	journal	September 2019
Enhanced Vertical Charge Transport of Homo‐ and Blended Semiconducting Polymers by Nanoconfinement Ko, Jongkuk; Kim, Youngkeol; Kang, Jin Soo Advanced Materials, Vol. 32, Issue 10 https://doi.org/10.1002/adma.201908087	journal	January 2020
Phthalimide‐Based High Mobility Polymer Semiconductors for Efficient Nonfullerene Solar Cells with Power Conversion Efficiencies over 13% Yu, Jianwei; Chen, Peng; Koh, Chang Woo Advanced Science https://doi.org/10.1002/advs.201801743	journal	December 2018
Enhancing Molecular Alignment and Charge Transport of Solution-Sheared Semiconducting Polymer Films by the Electrical-Blade Effect Molina-Lopez, Francisco; Wu, Hung-Chin; Wang, Ging-Ji Nathan Advanced Electronic Materials, Vol. 4, Issue 7 https://doi.org/10.1002/aelm.201800110	journal	May 2018
The Critical Role of Electron‐Donating Thiophene Groups on the Mechanical and Thermal Properties of Donor–Acceptor Semiconducting Polymers Zhang, Song; Ocheje, Michael U.; Huang, Lifeng Advanced Electronic Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aelm.201800899	journal	March 2019
The Motivation for and Challenges to Scaling Down Organic Field‐Effect Transistors Chan, Paddy Kwok Leung Advanced Electronic Materials, Vol. 5, Issue 7 https://doi.org/10.1002/aelm.201900029	journal	April 2019
Structure Evolution of Oligomer Fused-Ring Electron Acceptors toward High Efficiency of As-Cast Polymer Solar Cells Lin, Yuze; Li, Tengfei; Zhao, Fuwen Advanced Energy Materials, Vol. 6, Issue 18 https://doi.org/10.1002/aenm.201600854	journal	July 2016
Roll-to-Roll Printed Large-Area All-Polymer Solar Cells with 5% Efficiency Based on a Low Crystallinity Conjugated Polymer Blend Gu, Xiaodan; Zhou, Yan; Gu, Kevin Advanced Energy Materials, Vol. 7, Issue 14 https://doi.org/10.1002/aenm.201602742	journal	March 2017
Multiple Cases of Efficient Nonfullerene Ternary Organic Solar Cells Enabled by an Effective Morphology Control Method Jiang, Kui; Zhang, Guangye; Yang, Guofang Advanced Energy Materials, Vol. 8, Issue 9 https://doi.org/10.1002/aenm.201701370	journal	December 2017
Understanding the Impact of Oligomeric Polystyrene Side Chain Arrangement on the All-Polymer Solar Cell Performance Kurosawa, Tadanori; Gu, Xiaodan; Gu, Kevin L. Advanced Energy Materials, Vol. 8, Issue 2 https://doi.org/10.1002/aenm.201701552	journal	September 2017
Printed Nonfullerene Organic Solar Cells with the Highest Efficiency of 9.5% Lin, Yuanbao; Jin, Yingzhi; Dong, Sheng Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201701942	journal	January 2018
Photoactive Blend Morphology Engineering through Systematically Tuning Aggregation in All-Polymer Solar Cells Wang, Gang; Eastham, Nicholas D.; Aldrich, Thomas J. Advanced Energy Materials, Vol. 8, Issue 12 https://doi.org/10.1002/aenm.201702173	journal	January 2018
Polymersolarzellen: Fortschritt, Herausforderungen und Perspektiven Wang, Gang; Melkonyan, Ferdinand S.; Facchetti, Antonio Angewandte Chemie, Vol. 131, Issue 13 https://doi.org/10.1002/ange.201808976	journal	March 2019
All-Polymer Solar Cells: Recent Progress, Challenges, and Prospects Wang, Gang; Melkonyan, Ferdinand S.; Facchetti, Antonio Angewandte Chemie International Edition, Vol. 58, Issue 13 https://doi.org/10.1002/anie.201808976	journal	February 2019
Imide‐Functionalized Polymer Semiconductors Sun, Huiliang; Wang, Lei; Wang, Yingfeng Chemistry – A European Journal, Vol. 25, Issue 1 https://doi.org/10.1002/chem.201803605	journal	December 2018
Challenges to the Stability of Active Layer Materials in Organic Solar Cells Wang, Kun; Li, Yaowen; Li, Yongfang Macromolecular Rapid Communications, Vol. 41, Issue 4 https://doi.org/10.1002/marc.201900437	journal	January 2020
Fiber-Shaped Perovskite Solar Cells with High Power Conversion Efficiency Qiu, Longbin; He, Sisi; Yang, Jiahua Small, Vol. 12, Issue 18 https://doi.org/10.1002/smll.201600326	journal	March 2016
High-Performance Non-Fullerene Polymer Solar Cells Based on Fluorine Substituted Wide Bandgap Copolymers Without Extra Treatments Fan, Qunping; Su, Wenyan; Meng, Xiangyi Solar RRL, Vol. 1, Issue 5 https://doi.org/10.1002/solr.201700020	journal	March 2017
In Situ Structure Characterization in Slot‐Die‐Printed All‐Polymer Solar Cells with Efficiency Over 9% Zhong, Wenkai; Hu, Qin; Jiang, Yufeng Solar RRL, Vol. 3, Issue 7 https://doi.org/10.1002/solr.201900032	journal	May 2019
Triimide‐Functionalized n‐Type Polymer Semiconductors Enabling All‐Polymer Solar Cells with Power Conversion Efficiencies Approaching 9% Wang, Yingfeng; Yan, Zhenglong; Uddin, Mohammad Afsar Solar RRL, Vol. 3, Issue 7 https://doi.org/10.1002/solr.201900107	journal	May 2019
In Situ Structure Characterization in Slot‐Die‐Printed All‐Polymer Solar Cells with Efficiency Over 9% Zhong, Wenkai; Hu, Qin; Jiang, Yufeng Solar RRL, Vol. 3, Issue 7 https://doi.org/10.1002/solr.201970073	journal	May 2019
Rhodanine flanked indacenodithiophene as non-fullerene acceptor for efficient polymer solar cells Jia, Boyu; Wu, Yao; Zhao, Fuwen Science China Chemistry, Vol. 60, Issue 2 https://doi.org/10.1007/s11426-016-0336-6	journal	January 2017
Non-fullerene acceptors for organic solar cells Yan, Cenqi; Barlow, Stephen; Wang, Zhaohui Nature Reviews Materials, Vol. 3, Issue 3 https://doi.org/10.1038/natrevmats.2018.3	journal	February 2018
High-resolution patterning of solution-processable materials via externally engineered pinning of capillary bridges Li, Shunpu; Chun, Young Tea; Zhao, Shuo Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02835-7	journal	January 2018
Next-generation organic photovoltaics based on non-fullerene acceptors Cheng, Pei; Li, Gang; Zhan, Xiaowei Nature Photonics, Vol. 12, Issue 3 https://doi.org/10.1038/s41566-018-0104-9	journal	February 2018
Highly efficient polymer solar cells with printed photoactive layer: rational process transfer from spin-coating Zhao, K.; Hu, H.; Spada, E. Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/c6ta06258j	journal	January 2016
Optimisation of processing solvent and molecular weight for the production of green-solvent-processed all-polymer solar cells with a power conversion efficiency over 9% Fan, Baobing; Ying, Lei; Wang, Zhenfeng Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/c7ee00619e	journal	January 2017
Rational design of conjugated side chains for high-performance all-polymer solar cells Huang, Wei; Li, Meilin; Lin, Fengyuan Molecular Systems Design & Engineering, Vol. 3, Issue 1 https://doi.org/10.1039/c7me00088j	journal	January 2018
A novel high-performance electrode architecture for supercapacitors: Fe ₂ O ₃ nanocube and carbon nanotube functionalized carbon Wang, Rui; Cai, Shichang; Yan, Yizhi Journal of Materials Chemistry A, Vol. 5, Issue 43 https://doi.org/10.1039/c7ta07043h	journal	January 2017
Vapor phase organic chemistry to deposit conjugated polymer films on arbitrary substrates Cheng, Nongyi; Zhang, Lushuai; Joon Kim, Jae Journal of Materials Chemistry C, Vol. 5, Issue 23 https://doi.org/10.1039/c7tc00293a	journal	January 2017
Efficient and thermally stable all-polymer solar cells based on a fluorinated wide-bandgap polymer donor with high crystallinity Su, Wenyan; Meng, Yuan; Guo, Xia Journal of Materials Chemistry A, Vol. 6, Issue 34 https://doi.org/10.1039/c8ta05376f	journal	January 2018
Laser-induced orientation transformation of a conjugated polymer thin film with enhanced vertical charge transport Chae, Sangmin; Yi, Ahra; Lee, Hyun Hwi Journal of Materials Chemistry C, Vol. 6, Issue 35 https://doi.org/10.1039/c8tc02393j	journal	January 2018
On the understanding of energetic disorder, charge recombination and voltage losses in all-polymer solar cells Yin, Ao; Zhang, Dongyang; Cheung, Sin Hang Journal of Materials Chemistry C, Vol. 6, Issue 29 https://doi.org/10.1039/c8tc02689k	journal	January 2018
Pt complex-based terpolymer acceptors linked through ancillary ligand for all-polymer solar cells Gao, Xuyu; Shi, Dengke; Wang, Menghan Journal of Materials Chemistry C, Vol. 6, Issue 37 https://doi.org/10.1039/c8tc03409e	journal	January 2018
Fluorinated D1 _(0.5) –A–D2 _(0.5) –A model terpolymer: ultrafast charge separation kinetics and electron transfer at the fluorinated D/A interface for power conversion Li, Xiaoming; Liang, Zezhou; Wang, Huan Journal of Materials Chemistry A, Vol. 8, Issue 3 https://doi.org/10.1039/c9ta10610c	journal	January 2020
Benzodithiophene-modified terpolymer acceptors with reduced molecular planarity and crystallinity: improved performance and stability for all-polymer solar cells Gao, Xuyu; Gao, Jiaxin; Xue, Zhongyuan Journal of Materials Chemistry C, Vol. 7, Issue 33 https://doi.org/10.1039/c9tc03142a	journal	January 2019
Optimizing domain size and phase purity in all-polymer solar cells by solution ordered aggregation and confinement effect of the acceptor Zhang, Qiang; Chen, Zhenyu; Ma, Wei Journal of Materials Chemistry C, Vol. 7, Issue 40 https://doi.org/10.1039/c9tc03697k	journal	January 2019
Competition between deformability and charge transport in semiconducting polymers for flexible and stretchable electronics Printz, Adam D.; Lipomi, Darren J. Applied Physics Reviews, Vol. 3, Issue 2 https://doi.org/10.1063/1.4947428	journal	June 2016
Aggregation control in natural brush-printed conjugated polymer films and implications for enhancing charge transport Wang, Gang; Huang, Wei; Eastham, Nicholas D. Proceedings of the National Academy of Sciences, Vol. 114, Issue 47 https://doi.org/10.1073/pnas.1713634114	journal	November 2017
Origin and role of gap states in organic semiconductor studied by UPS: as the nature of organic molecular crystals Yang, Jin-Peng; Bussolotti, Fabio; Kera, Satoshi Journal of Physics D: Applied Physics, Vol. 50, Issue 42 https://doi.org/10.1088/1361-6463/aa840f	journal	September 2017
Scalable fabrication of organic solar cells based on non-fullerene acceptors Gertsen, Anders S.; Castro, Marcial Fernández; Søndergaard, Roar R. Flexible and Printed Electronics, Vol. 5, Issue 1 https://doi.org/10.1088/2058-8585/ab5f57	journal	January 2020
Tuning conformation, assembly, and charge transport properties of conjugated polymers by printing flow Park, Kyung Sun; Kwok, Justin J.; Dilmurat, Rishat Science Advances, Vol. 5, Issue 8 https://doi.org/10.1126/sciadv.aaw7757	journal	August 2019
Three-dimensional molecular and nanoparticle crystallization by DNA nanotechnology Seeman, Nadrian C.; Gang, Oleg MRS Bulletin, Vol. 42, Issue 12 https://doi.org/10.1557/mrs.2017.280	journal	December 2017
Surpassing 10% Efficiency Benchmark for Nonfullerene Organic Solar Cells by Scalable Coating in Air from Single Nonhalogenated Solvent Y., Xiong,; W., You,; C., Wang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/jhpv-dy32	text	January 2018
Revealing the Impact of F4-TCNQ as Additive on Morphology and Performance of High-Efficiency Nonfullerene Organic Solar Cells J. J., Rech,; W., You,; Q., Zhang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/tghg-rb29	text	January 2019

Similar Records

Roll-to-Roll Printed Large-Area All-Polymer Solar Cells with 5% Efficiency Based on a Low Crystallinity Conjugated Polymer Blend

Journal Article · Mon Mar 06 19:00:00 EST 2017 · Advanced Energy Materials · OSTI ID:1390316

Controlling Polymer Morphology in Blade-Coated All-Polymer Solar Cells

Journal Article · Thu Jul 29 20:00:00 EDT 2021 · Chemistry of Materials · OSTI ID:1845106

Related Subjects

14 SOLAR ENERGY
36 MATERIALS SCIENCE
chemical sciences
fluids and plasma physics
materials science
physical chemistry

Flow-enhanced solution printing of all-polymer solar cells

Citation Formats

References (69)

Cited By (64)

Similar Records

Related Subjects