Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

Sun, Xiao -Guang; Fang, Youxing; Jiang, Xueguang; Yoshii, Kazuki; Tsuda, Tetsuya; Dai, Sheng

doi:10.1039/C5CC06643C

Polymer gel electrolytes for application in aluminum deposition and rechargeable aluminum ion batteries

Journal Article · Thu Oct 22 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/C5CC06643C· OSTI ID:1237640

Sun, Xiao -Guang ^[1]; Fang, Youxing ^[2]; Jiang, Xueguang ^[2]; Yoshii, Kazuki ^[3]; Tsuda, Tetsuya ^[3]; Dai, Sheng ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Osaka Univ., Suita (Japan)

Polymer gel electrolyte using AlCl3 complexed acrylamide as functional monomer and ionic liquids based on acidic mixture of 1-ethyl-3-methylimidazolium chloride (EMImCl) and AlCl₃ as plasticizer has been successfully prepared for the first time by free radical polymerization. Aluminum deposition is successfully obtained with a polymer gel membrane contianing 80 wt% ionic liquid. As a result, the polymer gel membranes are also good candidates for rechargeable aluminum ion batteries.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1237640

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 2 Vol. 52; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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