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Guest-induced emergent properties in Metal–Organic Frameworks

Journal Article · · Journal of Physical Chemistry Letters
DOI:https://doi.org/10.1021/jz5026883· OSTI ID:1235927
Metal–Organic frameworks (MOFs) are crystalline nanoporous materials comprised of organic electron donors linked to metal ions by strong coordination bonds. Applications such as gas storage and separations are currently receiving considerable attention, but if the unique properties of MOFs could be extended to electronics, magnetics, and photonics, the impact on material science would greatly increase. Recently, we obtained “emergent properties,” such as electronic conductivity and energy transfer, by infiltrating MOF pores with “guest” molecules that interact with the framework electronic structure. In this Perspective, we define a path to emergent properties based on the Guest@MOF concept, using zinc-carboxylate and copper-paddlewheel MOFs for illustration. Energy transfer and light harvesting are discussed for zinc carboxylate frameworks infiltrated with triplet-scavenging organometallic compounds and thiophene- and fullerene-infiltrated MOF-177. In addition, we discuss the mechanism of charge transport in TCNQ-infiltrated HKUST-1, the first MOF with electrical conductivity approaching conducting organic polymers. Lastly, these examples show that guest molecules in MOF pores should be considered not merely as impurities or analytes to be sensed but also as an important aspect of rational design.
Research Organization:
Sandia National Laboratories (SNL-CA), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Program (EE-2A)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1235927
Report Number(s):
SAND--2015-20820J; 558248
Journal Information:
Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 7 Vol. 6; ISSN 1948-7185
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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Doping of metal-organic frameworks towards resistive sensing preprint January 2016
Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity journal April 2015
Optochemically Responsive 2D Nanosheets of a 3D Metal-Organic Framework Material journal May 2017
Mechanical Properties in Metal-Organic Frameworks: Emerging Opportunities and Challenges for Device Functionality and Technological Applications journal November 2017
Defective Metal-Organic Frameworks journal January 2018
New OLEDs Based on Zirconium Metal-Organic Framework journal January 2018
Elektrisch leitfähige poröse Metall-organische Gerüstverbindungen journal January 2016
Reversible Optical Writing and Data Storage in an Anthracene‐Loaded Metal‐Organic Framework journal December 2018
Schalten in Metall‐organischen Gerüsten journal December 2019
Electrically Conductive Porous Metal-Organic Frameworks journal January 2016
Reversible Optical Writing and Data Storage in an Anthracene‐Loaded Metal–Organic Framework journal February 2019
Switching in Metal–Organic Frameworks journal December 2019
2D → 3D corrugated structure self‐assembled from 4,4′‐methylenebis( N ‐(pyridin‐2‐ylmethylene)aniline and terephthalic acid: Crystal structure and selective anion separations via anion exchange journal May 2020
Semiconducting Coordination Polymers Based on the Predesigned Ternary Te-Fe-Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers journal June 2017
Semiconducting Coordination Polymers Based on the Predesigned Ternary Te-Fe-Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers journal July 2017
Electrically Conducting Nanocomposites of Carbon Nanotubes and Metal‐Organic Frameworks with Strong Interactions between the two Components journal July 2019
Understanding and Controlling the Dielectric Response of Metal-Organic Frameworks journal March 2018
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