Guest-induced emergent properties in Metal–Organic Frameworks

Allendorf, Mark D.; Foster, Michael E.; Léonard, François; Stavila, Vitalie; Feng, Patrick L.; Doty, F. Patrick; Leong, Kirsty; Ma, Eric Yue; Johnston, Scott R.; Talin, A. Alec; Shen, Zhi -Xun

doi:10.1021/jz5026883

Title: Guest-induced emergent properties in Metal–Organic Frameworks

Journal Article · Thu Mar 19 00:00:00 EDT 2015 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/jz5026883· OSTI ID:1235927

Allendorf, Mark D. ^[1]; Foster, Michael E. ^[1]; Léonard, François ^[1]; Stavila, Vitalie ^[1]; Feng, Patrick L. ^[1]; Doty, F. Patrick ^[1]; Leong, Kirsty ^[1]; Ma, Eric Yue ^[2]; Johnston, Scott R. ^[2]; Talin, A. Alec ^[1]; Shen, Zhi -Xun ^[2]

Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Stanford Univ., Stanford, CA (United States)

Metal–Organic frameworks (MOFs) are crystalline nanoporous materials comprised of organic electron donors linked to metal ions by strong coordination bonds. Applications such as gas storage and separations are currently receiving considerable attention, but if the unique properties of MOFs could be extended to electronics, magnetics, and photonics, the impact on material science would greatly increase. Recently, we obtained “emergent properties,” such as electronic conductivity and energy transfer, by infiltrating MOF pores with “guest” molecules that interact with the framework electronic structure. In this Perspective, we define a path to emergent properties based on the Guest@MOF concept, using zinc-carboxylate and copper-paddlewheel MOFs for illustration. Energy transfer and light harvesting are discussed for zinc carboxylate frameworks infiltrated with triplet-scavenging organometallic compounds and thiophene- and fullerene-infiltrated MOF-177. In addition, we discuss the mechanism of charge transport in TCNQ-infiltrated HKUST-1, the first MOF with electrical conductivity approaching conducting organic polymers. Lastly, these examples show that guest molecules in MOF pores should be considered not merely as impurities or analytes to be sensed but also as an important aspect of rational design.

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Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1235927

Report Number(s):: SAND-2015-20820J; 558248

Journal Information:: Journal of Physical Chemistry Letters, Vol. 6, Issue 7; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 138 works

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Doping of metal–organic frameworks towards resistive sensing Shiozawa, Hidetsugu; Bayer, Bernhard C.; Peterlik, Herwig Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-02618-y	journal	May 2017
A highly emissive and stable zinc( ii ) metal–organic framework as a host–guest chemopalette for approaching white-light-emission Cai, Hong; Xu, Li-Li; Lai, He-Yun Chemical Communications, Vol. 53, Issue 56 https://doi.org/10.1039/c7cc03350h	journal	January 2017
Understanding and Controlling the Dielectric Response of Metal-Organic Frameworks Ryder, Matthew R.; Donà, Lorenzo; Vitillo, Jenny G. ChemPlusChem, Vol. 83, Issue 4 https://doi.org/10.1002/cplu.201700558	journal	March 2018
Elektrisch leitfähige poröse Metall-organische Gerüstverbindungen Sun, Lei; Campbell, Michael G.; Dincă, Mircea Angewandte Chemie, Vol. 128, Issue 11 https://doi.org/10.1002/ange.201506219	journal	January 2016
Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity Erickson, Kristopher J.; Léonard, François; Stavila, Vitalie Advanced Materials, Vol. 27, Issue 22 https://doi.org/10.1002/adma.201501078	journal	April 2015
Photonic hybrid crystals constructed from in situ host–guest nanoconfinement of a light-emitting complex in metal–organic framework pores Chaudhari, Abhijeet K.; Ryder, Matthew R.; Tan, Jin-Chong Nanoscale, Vol. 8, Issue 12 https://doi.org/10.1039/c6nr01122e	journal	January 2016
Application of a novel 2D cadmium( ii )-MOF in the formation of a photo-switch with a substantial on–off ratio Roy, Sumit; Dey, Arka; Ray, Partha Pratim Chemical Communications, Vol. 51, Issue 65 https://doi.org/10.1039/c5cc04323a	journal	January 2015
Water-triggered macroscopic structural transformation of a metal–organic framework Ohtani, Masataka; Takase, Kazutaka; Wang, Pengyu CrystEngComm, Vol. 18, Issue 11 https://doi.org/10.1039/c6ce00031b	journal	January 2016
Rational modifications of PCN-700 to induce electrical conductivity: a computational study Chong, Sanggyu; Kim, Jihan Dalton Transactions, Vol. 49, Issue 1 https://doi.org/10.1039/c9dt03865e	journal	January 2020
Switching in Metal–Organic Frameworks Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali Angewandte Chemie International Edition, Vol. 59, Issue 12 https://doi.org/10.1002/anie.201900666	journal	December 2019
Electrically Conducting Nanocomposites of Carbon Nanotubes and Metal‐Organic Frameworks with Strong Interactions between the two Components Schulze, Hendrik A.; Hoppe, Bastian; Schäfer, Malte ChemNanoMat, Vol. 5, Issue 9 https://doi.org/10.1002/cnma.201900110	journal	July 2019
Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework Castaldelli, Evandro; Imalka Jayawardena, K. D. G.; Cox, David C. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02215-7	journal	December 2017
Electrochromic thin films of Zn-based MOF-74 nanocrystals facilely grown on flexible conducting substrates at room temperature Chaudhari, Abhijeet K.; Souza, Barbara E.; Tan, Jin-Chong APL Materials, Vol. 7, Issue 8 https://doi.org/10.1063/1.5108948	journal	August 2019
Reversible Optical Writing and Data Storage in an Anthracene‐Loaded Metal‐Organic Framework Tu, Min; Reinsch, Helge; Rodríguez-Hermida, Sabina Angewandte Chemie https://doi.org/10.1002/ange.201813996	journal	December 2018
Semiconducting Coordination Polymers Based on the Predesigned Ternary Te-Fe-Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers Shieh, Minghuey; Yu, Chia-Chi; Miu, Chia-Yeh Chemistry - A European Journal, Vol. 23, Issue 47 https://doi.org/10.1002/chem.201702641	journal	July 2017
Doping of metal-organic frameworks towards resistive sensing Shiozawa, Hidetsugu; Bayer, Bernhard C.; Peterlik, Herwig arXiv https://doi.org/10.48550/arxiv.1611.09138	preprint	January 2016
Metal–Organic Framework Co-MOF-74-Based Host–Guest Composites for Resistive Gas Sensing Strauss, Ina; Mundstock, Alexander; Treger, Marvin Washington D.C. : American Chemical Society https://doi.org/10.15488/9172	text	January 2019

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