Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD

Garcia, Gustavo A.; Tang, Xiaofeng; Gil, Jean -Francois; Nahon, Laurent; Ward, Michael; Batut, Sebastien; Fittschen, Christa; Taatjes, Craig A.; Osborn, David L.; Loison, Jean -Christophe

doi:10.1063/1.4918634

Synchrotron-based double imaging photoelectron/photoion coincidence spectroscopy of radicals produced in a flow tube: OH and OD

Journal Article · Thu Apr 23 00:00:00 EDT 2015 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4918634· OSTI ID:1235922

^[1]; Tang, Xiaofeng ^[1]; Gil, Jean -Francois ^[1]; Nahon, Laurent ^[1]; Ward, Michael ^[2]; Batut, Sebastien ^[2]; Fittschen, Christa ^[2]; Taatjes, Craig A. ^[3]; Osborn, David L. ^[3]; Loison, Jean -Christophe ^[4]

Synchrotron SOLEIL, L'Orme des Merisiers, Gif sur Yvette (France)
Univ. de Lille, Villeneuve d'Ascq (France)
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Univ. Bordeaux, Talence Cedex (France)

In this study, we present a microwave discharge flow tube coupled with a double imaging electron/ion coincidence device and vacuum ultraviolet (VUV) synchrotron radiation. The system has been applied to the study of the photoelectron spectroscopy of the well-known radicals OH and OD. The coincidence imaging scheme provides a high selectivity and yields the spectra of the pure radicals, removing the ever-present contributions from excess reactants, background, or secondary products, and therefore obviating the need for a prior knowledge of all possible byproducts. The photoelectron spectra encompassing the X³Σ^– ground state of the OH⁺ and OD⁺ cations have been extracted and the vibrational constants compared satisfactorily to existing literature values. Future advantages of this approach include measurement of high resolution VUV spectroscopy of radicals, their absolute photoionization cross section, and species/isomer identification in chemical reactions as a function of time.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1235922

Alternate ID(s):: OSTI ID: 1228217
OSTI ID: 22415703

Report Number(s):: SAND--2015-3596J; 583721

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 16 Vol. 142; ISSN JCPSA6; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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