Shape-controlled narrow-gap SnTe nanostructures: From nanocubes to nanorods and nanowires

Guo, Shaojun; He, Kai; Su, Dong; Chen, Gen; Lin, Qianglu; Pietryga, Jeffrey M.; Klimov, Victor I.

doi:10.1021/jacs.5b09490

Shape-controlled narrow-gap SnTe nanostructures: From nanocubes to nanorods and nanowires

Journal Article · Fri Nov 06 00:00:00 EST 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b09490· OSTI ID:1235859

Guo, Shaojun ^[1]; He, Kai ^[2]; Su, Dong ^[2]; Chen, Gen ^[3]; Lin, Qianglu ^[1]; Pietryga, Jeffrey M. ^[1]; Klimov, Victor I. ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
New Mexico State Univ., Las Cruces, NM (United States)

In this study, the rational design and synthesis of narrow-gap colloidal semiconductor nanocrystals (NCs) is an important step toward the next generation of solution-processable photovoltaics, photodetectors, and thermoelectric devices. SnTe NCs are particularly attractive as a Pb-free alternative to NCs of narrow-gap lead chalcogenides. Previous synthetic efforts on SnTe NCs have focused on spherical nanoparticles. Here we report new strategies for synthesis of SnTe NCs with shapes tunable from highly monodisperse nanocubes, to nanorods (NRs) with variable aspect ratios, and finally to long, straight nanowires (NWs). Reaction at high temperature quickly forms thermodynamically favored nanocubes, but low temperatures lead to elongated particles. Transmission electron microscopy studies of reaction products at various stages of the synthesis reveal that the growth and shape-focusing of monodisperse SnTe nanocubes likely involves interparticle ripening, while directional growth of NRs and NWs may be initiated by particle dimerization via oriented attachment.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC52-06NA25396; SC0012704

OSTI ID:: 1235859

Alternate ID(s):: OSTI ID: 1409770
OSTI ID: 1370917
OSTI ID: 1386887

Report Number(s):: BNL--111619-2015-JA; LA-UR--17-22648; KC0403020

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 48 Vol. 137; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (36)

Efficient Infrared Electroluminescent Devices Using Solution-Processed Colloidal Quantum Dots Konstantatos, G.; Huang, C.; Levina, L. Advanced Functional Materials, Vol. 15, Issue 11 https://doi.org/10.1002/adfm.200500379	journal	November 2005
1.3μm to 1.55μm Tunable Electroluminescence from PbSe Quantum Dots Embedded within an Organic Device Steckel, J. S.; Coe-Sullivan, S.; Bulović, V. Advanced Materials, Vol. 15, Issue 21 https://doi.org/10.1002/adma.200305449	journal	November 2003
Stability Assessment on a 3% Bilayer PbS/ZnO Quantum Dot Heterojunction Solar Cell Luther, Joseph M.; Gao, Jianbo; Lloyd, Matthew T. Advanced Materials, Vol. 22, Issue 33, p. 3704-3707 https://doi.org/10.1002/adma.201001148	journal	August 2010
Selective p- and n-Doping of Colloidal PbSe Nanowires To Construct Electronic and Optoelectronic Devices Oh, Soong Ju; Uswachoke, Chawit; Zhao, Tianshuo ACS Nano, Vol. 9, Issue 7 https://doi.org/10.1021/acsnano.5b02734	journal	June 2015
Carrier Multiplication in Semiconductor Nanocrystals: Influence of Size, Shape, and Composition Padilha, Lazaro A.; Stewart, John T.; Sandberg, Richard L. Accounts of Chemical Research, Vol. 46, Issue 6 https://doi.org/10.1021/ar300228x	journal	March 2013
Composition and Size-Dependent Extinction Coefficient of Colloidal PbSe Quantum Dots Moreels, Iwan; Lambert, Karel; De Muynck, David Chemistry of Materials, Vol. 19, Issue 25 https://doi.org/10.1021/cm071410q	journal	December 2007
Pushing the Band Gap Envelope: Mid-Infrared Emitting Colloidal PbSe Quantum Dots Pietryga, Jeffrey M.; Schaller, Richard D.; Werder, Donald Journal of the American Chemical Society, Vol. 126, Issue 38 https://doi.org/10.1021/ja047659f	journal	September 2004
Designing PbSe Nanowires and Nanorings through Oriented Attachment of Nanoparticles Cho, Kyung-Sang; Talapin, Dmitri V.; Gaschler, Wolfgang Journal of the American Chemical Society, Vol. 127, Issue 19 https://doi.org/10.1021/ja050107s	journal	May 2005
PbTe Colloidal Nanocrystals: Synthesis, Characterization, and Multiple Exciton Generation Murphy, James E.; Beard, Matthew C.; Norman, Andrew G. Journal of the American Chemical Society, Vol. 128, Issue 10 https://doi.org/10.1021/ja0574973	journal	March 2006
On the Mechanism of Lead Chalcogenide Nanocrystal Formation Steckel, Jonathan S.; Yen, Brian K. H.; Oertel, David C. Journal of the American Chemical Society, Vol. 128, Issue 40 https://doi.org/10.1021/ja062626g	journal	October 2006
SnTe Nanocrystals: A New Example of Narrow-Gap Semiconductor Quantum Dots Kovalenko, Maksym V.; Heiss, Wolfgang; Shevchenko, Elena V. Journal of the American Chemical Society, Vol. 129, Issue 37 https://doi.org/10.1021/ja074481z	journal	September 2007
High Performance Na-doped PbTe–PbS Thermoelectric Materials: Electronic Density of States Modification and Shape-Controlled Nanostructures Girard, Steven N.; He, Jiaqing; Zhou, Xiaoyuan Journal of the American Chemical Society, Vol. 133, Issue 41 https://doi.org/10.1021/ja206380h	journal	October 2011
Synthesis and Crystallographic Analysis of Shape-Controlled SnS Nanocrystal Photocatalysts: Evidence for a Pseudotetragonal Structural Modification Biacchi, Adam J.; Vaughn, Dimitri D.; Schaak, Raymond E. Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja405203e	journal	July 2013
High ZT in p-Type (PbTe) _{1–2 x} (PbSe) _x (PbS) _x Thermoelectric Materials Korkosz, Rachel J.; Chasapis, Thomas C.; Lo, Shih-han Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja4121583	journal	February 2014
High Thermoelectric Performance of p-Type SnTe via a Synergistic Band Engineering and Nanostructuring Approach Tan, Gangjian; Zhao, Li-Dong; Shi, Fengyuan Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja500860m	journal	May 2014
A Reduction Pathway in the Synthesis of PbSe Nanocrystal Quantum Dots Joo, Jin; Pietryga, Jeffrey M.; McGuire, John A. Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja903445f	journal	August 2009
Synthesis of Monodisperse PbSe Nanorods: A Case for Oriented Attachment Koh, Weon-kyu; Bartnik, Adam C.; Wise, Frank W. Journal of the American Chemical Society, Vol. 132, Issue 11 https://doi.org/10.1021/ja9105682	journal	March 2010
Aspect Ratio Dependence of Auger Recombination and Carrier Multiplication in PbSe Nanorods Padilha, Lazaro A.; Stewart, John T.; Sandberg, Richard L. Nano Letters, Vol. 13, Issue 3 https://doi.org/10.1021/nl304426y	journal	February 2013
Shape control of CdSe nanocrystals Peng, Xiaogang; Manna, Liberato; Yang, Weidong Nature, Vol. 404, Issue 6773, p. 59-61 https://doi.org/10.1038/35003535	journal	March 2000
Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals Zhao, Li-Dong; Lo, Shih-Han; Zhang, Yongsheng Nature, Vol. 508, Issue 7496, p. 373-377 https://doi.org/10.1038/nature13184	journal	April 2014
Localized surface plasmon resonances arising from free carriers in doped quantum dots Luther, Joseph M.; Jain, Prashant K.; Ewers, Trevor Nature Materials, Vol. 10, Issue 5, p. 361-366 https://doi.org/10.1038/nmat3004	journal	April 2011
Improved performance and stability in quantum dot solar cells through band alignment engineering Chuang, Chia-Hao M.; Brown, Patrick R.; Bulović, Vladimir Nature Materials, Vol. 13, Issue 8, p. 796-801 https://doi.org/10.1038/nmat3984	journal	May 2014
Nanostructured materials for photon detection Konstantatos, Gerasimos; Sargent, Edward H. Nature Nanotechnology, Vol. 5, Issue 6 https://doi.org/10.1038/nnano.2010.78	journal	May 2010
Bright infrared quantum-dot light-emitting diodes through inter-dot spacing control Sun, Liangfeng; Choi, Joshua J.; Stachnik, David Nature Nanotechnology, Vol. 7, Issue 6 https://doi.org/10.1038/nnano.2012.63	journal	May 2012
The promise and challenge of nanostructured solar cells Beard, Matthew C.; Luther, Joseph M.; Nozik, Arthur J. Nature Nanotechnology, Vol. 9, Issue 12 https://doi.org/10.1038/nnano.2014.292	journal	December 2014
Importance of non-parabolic band effects in the thermoelectric properties of semiconductors Chen, Xin; Parker, David; Singh, David J. Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep03168	journal	November 2013
Synthesis of narrow band gap SnTe nanocrystals: nanoparticles and single crystal nanowires via oriented attachment Ning, Jiajia; Men, Kangkang; Xiao, Guanjun CrystEngComm, Vol. 12, Issue 12 https://doi.org/10.1039/c004098n	journal	January 2010
Continuous synthesis of SnTe nanorods Jin, Hyung Dae; Chang, Chih-Hung Journal of Materials Chemistry, Vol. 21, Issue 33 https://doi.org/10.1039/c1jm12211h	journal	January 2011
Crystal growth in colloidal tin oxide nanocrystals induced by coalescence at room temperature Leite, E. R.; Giraldi, T. R.; Pontes, F. M. Applied Physics Letters, Vol. 83, Issue 8 https://doi.org/10.1063/1.1605241	journal	August 2003
Optical and Electrical Properties and Band Structure of GeTe and SnTe Tsu, R.; Howard, W. E.; Esaki, L. Physical Review, Vol. 172, Issue 3 https://doi.org/10.1103/PhysRev.172.779	journal	August 1968
Electronic states and optical properties of PbSe nanorods and nanowires Bartnik, A. C.; Efros, Al. L.; Koh, W. -K. Physical Review B, Vol. 82, Issue 19 https://doi.org/10.1103/PhysRevB.82.195313	journal	November 2010
Band Structure of SnTe Studied by Photoemission Spectroscopy Littlewood, P. B.; Mihaila, B.; Schulze, R. K. Physical Review Letters, Vol. 105, Issue 8 https://doi.org/10.1103/PhysRevLett.105.086404	journal	August 2010
High Efficiency Carrier Multiplication in PbSe Nanocrystals: Implications for Solar Energy Conversion Schaller, R. D.; Klimov, V. I. Physical Review Letters, Vol. 92, Issue 18 https://doi.org/10.1103/PhysRevLett.92.186601	journal	May 2004
Colloidal Quantum-Dot Photodetectors Exploiting Multiexciton Generation Sukhovatkin, V.; Hinds, S.; Brzozowski, L. Science, Vol. 324, Issue 5934 https://doi.org/10.1126/science.1173812	journal	June 2009
Multiple Exciton Collection in a Sensitized Photovoltaic System Sambur, J. B.; Novet, T.; Parkinson, B. A. Science, Vol. 330, Issue 6000 https://doi.org/10.1126/science.1191462	journal	September 2010
Peak External Photocurrent Quantum Efficiency Exceeding 100% via MEG in a Quantum Dot Solar Cell Semonin, O. E.; Luther, J. M.; Choi, S. Science, Vol. 334, Issue 6062 https://doi.org/10.1126/science.1209845	journal	December 2011

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