Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media

Babiniec, Sean Michael; Coker, Eric Nicholas; Miller, James E.; Ambrosini, Andrea

doi:10.1016/j.solener.2015.05.040

Investigation of La_xSr_1-xCo_yM_1-yO_3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media

Journal Article · Tue Jun 23 00:00:00 EDT 2015 · Solar Energy

DOI:https://doi.org/10.1016/j.solener.2015.05.040· OSTI ID:1235322

Babiniec, Sean Michael ^[1]; Coker, Eric Nicholas ^[1]; Miller, James E. ^[1]; Ambrosini, Andrea ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Materials in the La_xSr_1–xCo_yMn_1–yO_3–δ (LSCM) and La_xSr_1–xCo_yFe_1–yO_3–δ (LSCF) families are candidates for high-temperature thermochemical energy storage due to their facility for cyclic endothermic reduction and exothermic oxidation. A set of 16 LSCM and 21 LSCF compositions were synthesized by a modified Pechini method and characterized by powder X-ray diffraction and thermogravimetric analysis. All materials were found to be various symmetries of the perovskite phase. LSCM was indexed as tetragonal, cubic, rhombohedral, or orthorhombic as a function of increased lanthanum content. For LSCF, compositions containing low lanthanum content were indexed as cubic while materials with high lanthanum content were indexed as rhombohedral. An initial screening of redox activity was completed by thermogravimetric analysis for each composition. The top three compositions with the greatest recoverable redox capacity for each family were further characterized in equilibrium thermogravimetric experiments over a range of temperatures and oxygen partial pressures. As a result, these equilibrium experiments allowed the extraction of thermodynamic parameters for LSCM and LSCF compositions operated in thermochemical energy storage conditions.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Program (EE-2A)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1235322

Alternate ID(s):: OSTI ID: 1237378
OSTI ID: 1245221

Report Number(s):: SAND--2015-4972J; 594399

Journal Information:: Solar Energy, Journal Name: Solar Energy Journal Issue: C Vol. 118; ISSN 0038-092X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Progress in thermochemical energy storage for concentrated solar power: A review Liu, Dai; Xin-Feng, Long; Bo, Lou International Journal of Energy Research, Vol. 42, Issue 15 https://doi.org/10.1002/er.4183	journal	August 2018
Thermodynamic and mechanism study of syngas production via integration of nitrous oxide decomposition and methane partial oxidation in the presence of 10%NiO–La0.3Sr0.7Co0.7Fe0.3O3−δ Khajonvittayakul, C.; Tongnan, V.; Kangsadan, T. Reaction Kinetics, Mechanisms and Catalysis, Vol. 127, Issue 2 https://doi.org/10.1007/s11144-019-01600-1	journal	June 2019
Theoretical study of the optical and thermodynamic properties of La _x Sr _1−x Co _1−y Fe _y O _3−δ ( x / y = 0.25, 0.5, 0.75) perovskites Jia, Ting; Ohodnicki, Paul; Chorpening, Benjamin Physical Chemistry Chemical Physics, Vol. 21, Issue 47 https://doi.org/10.1039/c9cp04921e	journal	January 2019
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