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Charging-free electrochemical system for harvesting low-grade thermal energy

Journal Article · · Proceedings of the National Academy of Sciences of the United States of America
 [1];  [2];  [1];  [1];  [1];  [1];  [3];  [4];  [1]
  1. Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139,
  2. Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305,
  3. Department of Chemical Engineering, Stanford University, Stanford, CA 94305, and
  4. Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305,, Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, CA 94025
Significance

Tremendous low-grade heat is stored in industrial processes and the environment. Efficient and low-cost utilization of the low-grade heat is critical to imminent energy and environmental challenges. Here, a rechargeable electrochemical cell (battery) is used to harvest such thermal energy because its voltage changes significantly with temperature. Moreover, by carefully tuning the composition of electrodes, the charging process is purely powered by thermal energy and no electricity is required to charge it. A high heat-to-electricity conversion efficiency of 2.0% can be reached when it is operated between 20 and 60 °C. Such charging-free characteristic may have potential application for harvesting low-grade heat from the environment, especially in remote areas.

Sponsoring Organization:
USDOE
OSTI ID:
1235150
Alternate ID(s):
OSTI ID: 1210634
OSTI ID: 1385293
Journal Information:
Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 48 Vol. 111; ISSN 0027-8424
Publisher:
Proceedings of the National Academy of SciencesCopyright Statement
Country of Publication:
United States
Language:
English

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