Capacitance, charge dynamics, and electrolyte-surface interactions in functionalized carbide-derived carbon electrodes

Dyatkin, Boris; Mamontov, Eugene; Cook, Kevin M.; Gogotsi, Yury

doi:10.1016/j.pnsc.2015.11.007

Title: Capacitance, charge dynamics, and electrolyte-surface interactions in functionalized carbide-derived carbon electrodes

Journal Article · Tue Dec 01 00:00:00 EST 2015 · Progress in Natural Science

DOI:https://doi.org/10.1016/j.pnsc.2015.11.007· OSTI ID:1233943

Dyatkin, Boris; Mamontov, Eugene; Cook, Kevin M.; Gogotsi, Yury

Our study analyzed the dynamics of ionic liquid electrolyte inside of defunctionalized, hydrogenated, and aminated pores of carbide-derived carbon supercapacitor electrodes. The approach tailors surface functionalities and tunes nanoporous structures to decouple the influence of pore wall composition on capacitance, ionic resistance, and long-term cyclability. Moreover, quasi-elastic neutron scattering probes the self-diffusion properties and electrode-ion interactions of electrolyte molecules confined in functionalized pores. Room-temperature ionic liquid interactions in confined pores are strongest when the hydrogen-containing groups are present on the surface. This property translates into higher capacitance and greater ion transport through pores during electrochemical cycling. Aminated pores, unlike hydrogenated pores, do not favorably interact with ionic liquid ions and, subsequently, are outperformed by defunctionalized surfaces.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1233943

Alternate ID(s):: OSTI ID: 1265882

Journal Information:: Progress in Natural Science, Journal Name: Progress in Natural Science Vol. 25 Journal Issue: 6; ISSN 1002-0071

Publisher:: ElsevierCopyright Statement

Country of Publication:: China

Language:: English

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Cited by: 25 works

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36 MATERIALS SCIENCE
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Title: Capacitance, charge dynamics, and electrolyte-surface interactions in functionalized carbide-derived carbon electrodes

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