A new equation of state for square-well molecules
Journal Article
·
· International Journal of Thermophysics
- John Hopkins Univ., Baltimore, MD (United States)
This paper presents a new equation of state for the square-well fluid based on perturbation theory. This equation has the exact second virial coefficient behavior, converges to the correct mean-field behavior at high densities, and accurately interpolates between the two limits. Monte Carlo simulations were performed to evaluate the limiting behavior of the theory in the dilute-gas regime. Comparison of the theory with the simulation results shows excellent agreement between the equation-of-state predictions and the data.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 123383
- Report Number(s):
- CONF-940633--
- Journal Information:
- International Journal of Thermophysics, Journal Name: International Journal of Thermophysics Journal Issue: 5 Vol. 16; ISSN 0195-928X; ISSN IJTHDY
- Country of Publication:
- United States
- Language:
- English
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