Metal-organic framework materials with ultrahigh surface areas

Farha, Omar K.; Hupp, Joseph T.; Wilmer, Christopher E.; Eryazici, Ibrahim; Snurr, Randall Q.; Gomez-Gualdron, Diego A.; Borah, Bhaskarjyoti

Metal-organic framework materials with ultrahigh surface areas

Patent · Mon Dec 21 23:00:00 EST 2015

OSTI ID:1233374

Farha, Omar K.; Hupp, Joseph T.; Wilmer, Christopher E.; Eryazici, Ibrahim; Snurr, Randall Q.; Gomez-Gualdron, Diego A.; Borah, Bhaskarjyoti

A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

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Research Organization:: Northwestern University, Evanston, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-08ER15967

Assignee:: Northwestern University (Evanston, IL)

Patent Number(s):: 9,216,939

Application Number:: 13/920,828

OSTI ID:: 1233374

Country of Publication:: United States

Language:: English

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