Precipitation pathways for ferrihydrite formation in acidic solutions

Zhu, Mengqiang; Khalid, Syed; Frandsen, Cathrine; Wallace, Adam F.; Legg, Benjamin; Zhang, Hengzhong; Morup, Steen; Banfield, Jillian F.; Waychunas, Glenn A.

doi:10.1016/j.gca.2015.09.015

Title: Precipitation pathways for ferrihydrite formation in acidic solutions

Journal Article · Sat Oct 03 00:00:00 EDT 2015 · Geochimica et Cosmochimica Acta

DOI:https://doi.org/10.1016/j.gca.2015.09.015· OSTI ID:1228832

Zhu, Mengqiang ^[1]; Khalid, Syed ^[2]; Frandsen, Cathrine ^[3]; Wallace, Adam F. ^[4]; Legg, Benjamin ^[5]; Zhang, Hengzhong ^[5]; Morup, Steen ^[3]; Banfield, Jillian F. ^[6]; Waychunas, Glenn A. ^[7]

Univ. of Wyoming, Laramie, WY (United States). Dept. of Ecosystem Science and Management; Lawrence Berkeley National Lab., Berkeley, CA (United States). Earth Sciences Division
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Physics
Univ. of Delaware, Newark, DE (United States). Dept. of Geological Sciences
Univ. of California, Berkeley, CA (United States). Dept. of Earth and Planetary Science
Univ. of California, Berkeley, CA (United States). Dept. of Earth and Planetary Science; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Earth Sciences Division

Iron oxides and oxyhydroxides form via Fe³⁺ hydrolysis and polymerization in many aqueous environments, but the pathway from Fe³⁺ monomers to oligomers and then to solid phase nuclei is unknown. In this work, using combined X-ray, UV-vis, and Mössbauer spectroscopic approaches, we were able to identify and quantify the long-time sought ferric speciation over time during ferric oxyhydroxide formation in partially-neutralized ferric nitrate solutions ([Fe³⁺]=0.2M, 1.8

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Danish Council for Independent Research (DFF)

Grant/Contract Number:: SC00112704; AC02-05CH11231; EAR-1529937; AC02-98CH10886; AC02-06CH11357; AC02-76SF00515

OSTI ID:: 1228832

Alternate ID(s):: OSTI ID: 1398140; OSTI ID: 1456925

Report Number(s):: BNL-108457-2015-JA; R&D Project: LS001

Journal Information:: Geochimica et Cosmochimica Acta, Vol. 172, Issue C; ISSN 0016-7037

Publisher:: The Geochemical Society; The Meteoritical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 54 works

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