Shape transformation of bimetallic Au–Pd core–shell nanocubes to multilayered Au–Pd–Au core–shell hexagonal platelets

Bhattarai, Nabraj; Prozorov, Tanya

doi:10.1007/s13632-015-0246-9

Shape transformation of bimetallic Au–Pd core–shell nanocubes to multilayered Au–Pd–Au core–shell hexagonal platelets

Journal Article · Thu Nov 05 00:00:00 EST 2015 · Metallography, Microstructure and Analysis

DOI:https://doi.org/10.1007/s13632-015-0246-9· OSTI ID:1227433

Bhattarai, Nabraj ^[1]; Prozorov, Tanya ^[1]

Ames Lab. (AMES), Ames, IA (United States)

Transformation of metallic or bimetallic (BM) nanoparticles (NPs) from one shape to another desired shape is of importance to nanoscience and nanotechnology, where new morphologies of NPs lead to enhancement of their exploitable properties. In this report, we present the shape transformation of Au octahedral NPs to Au–Pd core–shell nanocubes, followed by their transformation to nanostars and finally to multilayered Au–Pd–Au core–shell hexagonal platelets in the presence of T30 DNA. The weaker binding affinity of T30 DNA directs the growth to favor the formation of lower energy {111} facets, changing the morphology from nanocubes to nanostar. The nanostars, exhibiting unusual intermediate morphologies, are comprised two sets of shell layers and have Au core, Pd intermediate shell, and Au outer shell. Similarly, the hexagonal platelets, which also have Au core and inner Pd shell, are encased in an external gold shell. As a result, the formation of multilayered Au–Pd–Au core–shell hexagonal platelets from Au–Pd core–shell nanocubes via the multilayered nanostars is monitored using scanning/transmission electron microscopy analysis.

View Accepted Manuscript (DOE)

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1227433

Report Number(s):: IS-J--8646; PII: 246

Journal Information:: Metallography, Microstructure and Analysis, Journal Name: Metallography, Microstructure and Analysis Journal Issue: 6 Vol. 4; ISSN 2192-9262

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

Plasmonics-A Route to Nanoscale Optical Devices Maier, S. A.; Brongersma, M. L.; Kik, P. G. Advanced Materials, Vol. 13, Issue 19, p. 1501-1505 https://doi.org/10.1002/1521-4095(200110)13:19<1501::AID-ADMA1501>3.0.CO;2-Z	journal	September 2001
Shape-Controlled Synthesis of Polyhedral Nanocrystals and Their Facet-Dependent Properties Huang, Michael H.; Lin, Po-Heng Advanced Functional Materials, Vol. 22, Issue 1 https://doi.org/10.1002/adfm.201101784	journal	September 2011
Atomic-Distribution-Dependent Electrocatalytic Activity of Au-Pd Bimetallic Nanocrystals Hong, Jong Wook; Kim, Dongheun; Lee, Young Wook Angewandte Chemie, Vol. 123, Issue 38 https://doi.org/10.1002/ange.201102578	journal	August 2011
Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? Xia, Younan; Xiong, Yujie; Lim, Byungkwon Angewandte Chemie International Edition, Vol. 48, Issue 1, p. 60-103 https://doi.org/10.1002/anie.200802248	journal	December 2008
Discovery of the DNA “Genetic Code” for Abiological Gold Nanoparticle Morphologies Wang, Zidong; Tang, Longhua; Tan, Li Huey Angewandte Chemie International Edition, Vol. 51, Issue 36 https://doi.org/10.1002/anie.201203716	journal	August 2012
DNA-Encoded Tuning of Geometric and Plasmonic Properties of Nanoparticles Growing from Gold Nanorod Seeds Song, Tingjie; Tang, Longhua; Tan, Li Huey Angewandte Chemie International Edition, Vol. 54, Issue 28 https://doi.org/10.1002/anie.201500838	journal	June 2015
Core/Shell Semiconductor Nanocrystals Reiss, Peter; Protière, Myriam; Li, Liang Small, Vol. 5, Issue 2 https://doi.org/10.1002/smll.200800841	journal	January 2009
Heteroepitaxial Growth of Core-Shell and Core-Multishell Nanocrystals Composed of Palladium and Gold Wang, Feng; Sun, Ling-Dong; Feng, Wei Small, Vol. 6, Issue 22 https://doi.org/10.1002/smll.201000817	journal	October 2010
Origin and shape evolution of core–shell nanoparticles in Au–Pd: from few atoms to high Miller index facets Bhattarai, Nabraj; Casillas, Gilberto; Khanal, Subarna Journal of Nanoparticle Research, Vol. 15, Issue 6 https://doi.org/10.1007/s11051-013-1660-z	journal	May 2013
Strain-release mechanisms in bimetallic core–shell nanoparticles as revealed by Cs-corrected STEM Bhattarai, Nabraj; Casillas, Gilberto; Ponce, Arturo Surface Science, Vol. 609 https://doi.org/10.1016/j.susc.2012.12.001	journal	March 2013
DNA as a Powerful Tool for Morphology Control, Spatial Positioning, and Dynamic Assembly of Nanoparticles Tan, Li Huey; Xing, Hang; Lu, Yi Accounts of Chemical Research, Vol. 47, Issue 6 https://doi.org/10.1021/ar500081k	journal	May 2014
Chemistry and Properties of Nanocrystals of Different Shapes Burda, Clemens; Chen, Xiaobo; Narayanan, Radha Chemical Reviews, Vol. 105, Issue 4 https://doi.org/10.1021/cr030063a	journal	April 2005
Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles Ferrando, Riccardo; Jellinek, Julius; Johnston, Roy L. Chemical Reviews, Vol. 108, Issue 3, p. 845-910 https://doi.org/10.1021/cr040090g	journal	March 2008
Base-Dependent Competitive Adsorption of Single-Stranded DNA on Gold Kimura-Suda, Hiromi; Petrovykh, Dmitri Y.; Tarlov, Michael J. Journal of the American Chemical Society, Vol. 125, Issue 30 https://doi.org/10.1021/ja035756n	journal	July 2003
Au Nanocube-Directed Fabrication of Au−Pd Core−Shell Nanocrystals with Tetrahexahedral, Concave Octahedral, and Octahedral Structures and Their Electrocatalytic Activity Lu, Chun-Lun; Prasad, Kariate Sudhakara; Wu, Hsin-Lun Journal of the American Chemical Society, Vol. 132, Issue 41 https://doi.org/10.1021/ja105401p	journal	October 2010
Atomic Structure of Au−Pd Bimetallic Alloyed Nanoparticles Ding, Yong; Fan, Fengru; Tian, Zhongqun Journal of the American Chemical Society, Vol. 132, Issue 35 https://doi.org/10.1021/ja105614q	journal	September 2010
Cu ²⁺ -Assisted Synthesis of Hexoctahedral Au–Pd Alloy Nanocrystals with High-Index Facets Zhang, Lei; Zhang, Jiawei; Kuang, Qin Journal of the American Chemical Society, Vol. 133, Issue 43 https://doi.org/10.1021/ja2063617	journal	November 2011
Fabrication of Au–Pd Core–Shell Heterostructures with Systematic Shape Evolution Using Octahedral Nanocrystal Cores and Their Catalytic Activity Yang, Chih-Wen; Chanda, Kaushik; Lin, Po-Heng Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja209121x	journal	December 2011
An Exceptionally Simple Strategy for DNA-Functionalized Up-Conversion Nanoparticles as Biocompatible Agents for Nanoassembly, DNA Delivery, and Imaging Li, Le-Le; Wu, Peiwen; Hwang, Kevin Journal of the American Chemical Society, Vol. 135, Issue 7 https://doi.org/10.1021/ja310432u	journal	February 2013
Spatially-Directed Oxidation of Gold Nanoparticles by Au(III)−CTAB Complexes Rodríguez-Fernández, Jessica; Pérez-Juste, Jorge; Mulvaney, Paul The Journal of Physical Chemistry B, Vol. 109, Issue 30 https://doi.org/10.1021/jp052516g	journal	August 2005
DNA as a Selective Metallization Template Mertig, Michael; Colombi Ciacchi, Lucio; Seidel, Ralf Nano Letters, Vol. 2, Issue 8 https://doi.org/10.1021/nl025612r	journal	August 2002
Three-Layer Core/Shell Structure in Au−Pd Bimetallic Nanoparticles Ferrer, D.; Torres-Castro, A.; Gao, X. Nano Letters, Vol. 7, Issue 6 https://doi.org/10.1021/nl070694a	journal	June 2007
DNA-Mediated Control of Metal Nanoparticle Shape: One-Pot Synthesis and Cellular Uptake of Highly Stable and Functional Gold Nanoflowers Wang, Zidong; Zhang, Jieqian; Ekman, Jonathan M. Nano Letters, Vol. 10, Issue 5 https://doi.org/10.1021/nl100675p	journal	May 2010
Shape-Controlled Synthesis of Gold Nanostructures Using DNA Origami Molds Helmi, Seham; Ziegler, Christoph; Kauert, Dominik J. Nano Letters, Vol. 14, Issue 11 https://doi.org/10.1021/nl503441v	journal	October 2014
Synthesis and Catalytic Properties of Au–Pd Nanoflowers Xu, Jianguang; Wilson, Adria R.; Rathmell, Aaron R. ACS Nano, Vol. 5, Issue 8 https://doi.org/10.1021/nn201161m	journal	July 2011
A total-synthesis framework for the construction of high-order colloidal hybrid nanoparticles Buck, Matthew R.; Bondi, James F.; Schaak, Raymond E. Nature Chemistry, Vol. 4, Issue 1 https://doi.org/10.1038/nchem.1195	journal	November 2011
New views of catalysts Kiely, Chris Nature Materials, Vol. 9, Issue 4 https://doi.org/10.1038/nmat2728	journal	April 2010
DNA-based programming of quantum dot valency, self-assembly and luminescence Tikhomirov, Grigory; Hoogland, Sjoerd; Lee, P. E. Nature Nanotechnology, Vol. 6, Issue 8 https://doi.org/10.1038/nnano.2011.100	journal	July 2011
Highly size-controlled synthesis of Au/Pd nanoparticles by inert-gas condensation Pérez-Tijerina, E.; Gracia Pinilla, M.; Mejía-Rosales, S. Faraday Discuss., Vol. 138 https://doi.org/10.1039/B705913M	journal	January 2008
A plasmonic nanosensor with inverse sensitivity for circulating cell-free DNA quantification Pallares, Roger M.; Kong, Say Li; Hui Ru, Tan Chemical Communications, Vol. 51, Issue 77 https://doi.org/10.1039/C5CC05331E	journal	January 2015
Functionalization of DNA nanostructures with proteins Saccà, Barbara; Niemeyer, Christof M. Chemical Society Reviews, Vol. 40, Issue 12 https://doi.org/10.1039/c1cs15212b	journal	January 2011
Tuning and assembling metal nanostructures with DNA Kumar, Amit; Hwang, Jae-Ho; Kumar, Sumit Chemical Communications, Vol. 49, Issue 26 https://doi.org/10.1039/c2cc37536b	journal	January 2013
Epitaxial growth of Au@Pd core–shell nanocrystals prepared using a PVP-assisted polyol reduction method Tsuji, Masaharu; Ikedo, Koji; Matsunaga, Mika CrystEngComm, Vol. 14, Issue 10 https://doi.org/10.1039/c2ce00037g	journal	January 2012
Nonepitaxial Growth of Hybrid Core-Shell Nanostructures with Large Lattice Mismatches Zhang, J.; Tang, Y.; Lee, K. Science, Vol. 327, Issue 5973 https://doi.org/10.1126/science.1184769	journal	March 2010
DNA-incorporating nanomaterials in biotechnological applications Stadler, Andrea; Chi, Cheng; van der Lelie, Daniel Nanomedicine, Vol. 5, Issue 2 https://doi.org/10.2217/nnm.10.2	journal	February 2010
Nanomaterial-Assisted Signal Enhancement of Hybridization for DNA Biosensors: A Review Liu, Jinhuai; Liu, Jinyun; Yang, Liangbao Sensors, Vol. 9, Issue 9 https://doi.org/10.3390/s90907343	journal	September 2009

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Direct Observation of Early Stages of Growth of Multilayered DNA-Templated Au-Pd-Au Core-Shell Nanoparticles in Liquid Phase Bhattarai, Nabraj; Prozorov, Tanya Frontiers in Bioengineering and Biotechnology, Vol. 7 https://doi.org/10.3389/fbioe.2019.00019	journal	February 2019
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