The study of electrolyte solutions based on ethylene and diethyl carbonates for rechargeable Li batteries. 1: Li metal anodes

Journal Article · Fri Sep 01 04:00:00 EDT 1995 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1.2048658· OSTI ID:122708

Aurbach, D; Zaban, A; Schechter, A; Ein-Eli, Y; Zinigrad, E; Markovsky, B ^[1]

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1. Bar-Ilan Univ., Ramat Gan (Israel). Dept. of Chemistry

The behavior of Li electrodes was studied in ethylene and diethyl carbonates (EC-DEC) solutions of LiAsF{sub 6}, LiClO{sub 4}, LiBF{sub 4}, and LiPF{sub 6}. The correlation of the surface chemistry to the interfacial properties, morphology, and Li cycling efficiency was investigated using surface sensitive Fourier transform infrared spectroscopy and impedance spectroscopy, scanning electron microscopy, X-ray energy dispersive microanalysis, and standard electrochemical techniques. The Li surface chemistry is initially dominated by EC reduction to an insoluble species, probably (CH{sub 2}OCO{sub 2}Li){sub 2}. Upon storage, several aging processes may take place, depending on the salt used. Their mechanisms are discussed. Although EC-DEC solutions were found to be adequate for Li ion rechargeable batteries, this work indicates that they are not suitable as electrolyte solutions for batteries with Li metal electrodes. This is mostly because Li electrodes cannot be considered stable in these systems and Li deposition is highly dendritic.

• Sponsoring Organization: USDOE
• OSTI ID: 122708
• Journal Information: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 9 Vol. 142; ISSN 0013-4651; ISSN JESOAN
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
ANODES
ARSENIC FLUORIDES
BATTERY CHARGING
BORON FLUORIDES
CARBONIC ACID ESTERS
CHLORATES
ELECTRIC BATTERIES
ELECTROLYTES
INTERFACES
LITHIUM COMPOUNDS
MEASURING METHODS
MORPHOLOGY
PERFORMANCE
PHOSPHORUS FLUORIDES
STABILITY
SURFACE PROPERTIES
VOLTAGE DROP