Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

Firlar, Emre; Çınar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

doi:10.1038/srep09830

Title: Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

Journal Article · Thu May 21 00:00:00 EDT 2015 · Scientific Reports

DOI:https://doi.org/10.1038/srep09830· OSTI ID:1225384

Firlar, Emre ^[1]; Çınar, Simge ^[2]; Kashyap, Sanjay ^[1]; Akinc, Mufit ^[3]; Prozorov, Tanya ^[1]

Ames Lab., Ames, IA (United States)
Iowa State Univ., Ames, IA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions. We discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. As a result, our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1225384

Report Number(s):: IS-J-8517; srep09830

Journal Information:: Scientific Reports, Vol. 5, Issue 2; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 15 works

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References (48)

Superviscosity and electroviscous effects at an electrode/aqueous electrolyte interface: An atomic force microscope study Guriyanova, Svetlana; Mairanovsky, Victor G.; Bonaccurso, Elmar Journal of Colloid and Interface Science, Vol. 360, Issue 2 https://doi.org/10.1016/j.jcis.2011.04.072	journal	August 2011
Problems in line broadening and ionization lowering Davis, J.; Blaha, M. Atomic processes in plasmas, AIP Conference Proceedings https://doi.org/10.1063/1.39284	conference	January 1990
Application of nmr spectroscopy to determine the thermodynamic characteristics of water bound to OX-50 nanosilica Turov, V. V.; Gun’ko, V. M.; Gaishun, V. E. Journal of Applied Spectroscopy, Vol. 77, Issue 4 https://doi.org/10.1007/s10812-010-9373-x	journal	August 2010
Direct Tape Casting of Nanosized Al ₂ O ₃ Slurries Derived from Autogenous Nanomilling Vozdecky, Pavel; Roosen, Andreas; Knieke, Catharina Journal of the American Ceramic Society https://doi.org/10.1111/j.1551-2916.2009.03597.x	journal	February 2010
Viscosity of alumina nanoparticles dispersed in car engine coolant Kole, Madhusree; Dey, T. K. Experimental Thermal and Fluid Science, Vol. 34, Issue 6 https://doi.org/10.1016/j.expthermflusci.2009.12.009	journal	September 2010
Small particles, big impacts: A review of the diverse applications of nanofluids Taylor, Robert; Coulombe, Sylvain; Otanicar, Todd Journal of Applied Physics, Vol. 113, Issue 1 https://doi.org/10.1063/1.4754271	journal	January 2013
Co–Al mixed metal oxides/carbon nanotubes nanocomposite prepared via a precursor route and enhanced catalytic property Fan, Guoli; Wang, Hui; Xiang, Xu Journal of Solid State Chemistry, Vol. 197 https://doi.org/10.1016/j.jssc.2012.08.016	journal	January 2013
The rheology of concentrated suspensions of arbitrarily-shaped particles Santamarı´a-Holek, I.; Mendoza, Carlos I. Journal of Colloid and Interface Science, Vol. 346, Issue 1 https://doi.org/10.1016/j.jcis.2010.02.033	journal	June 2010
Low-dose aberration corrected cryo-electron microscopy of organic specimens Evans, James E.; Hetherington, Crispin; Kirkland, Angus Ultramicroscopy, Vol. 108, Issue 12 https://doi.org/10.1016/j.ultramic.2008.06.004	journal	November 2008
Grey Goo on the Skin? Nanotechnology, Cosmetic and Sunscreen Safety Nohynek, Gerhard J.; Lademann, Jürgen; Ribaud, Christele Critical Reviews in Toxicology, Vol. 37, Issue 3 https://doi.org/10.1080/10408440601177780	journal	January 2007
Electrostatic Stabilization of Alumina Nanopowder Suspensions Çınar, Simge; Akinc, Mufit Science of Advanced Materials, Vol. 6, Issue 3 https://doi.org/10.1166/sam.2014.1773	journal	March 2014
In situ EELS study of dehydration of Al(OH)3 by electron beam irradiation Jiang, Nan; Spence, John C. H. Ultramicroscopy, Vol. 111, Issue 7 https://doi.org/10.1016/j.ultramic.2010.11.004	journal	June 2011
Nanominerals and nanoparticles in feed coal and bottom ash: implications for human health effects Silva, Luis F. O.; da Boit, Kátia M. Environmental Monitoring and Assessment, Vol. 174, Issue 1-4 https://doi.org/10.1007/s10661-010-1449-9	journal	April 2010
The rheology of concentrated suspensions of arbitrarily-shaped particles Santamaria-Holek, I.; Mendoza, Carlos I. arXiv https://doi.org/10.48550/arxiv.1005.5707	text	January 2010
Titanium Dioxide Nanoparticles in Food and Personal Care Products Weir, Alex; Westerhoff, Paul; Fabricius, Lars Environmental Science & Technology, Vol. 46, Issue 4 https://doi.org/10.1021/es204168d	journal	February 2012
Relation between the Infrared Spectra and the Lateral Specific Surface Areas of Gibbsite Samples Phambu, Nsoki; Humbert, Bernard; Burneau, Andre Langmuir, Vol. 16, Issue 15 https://doi.org/10.1021/la000098v	journal	July 2000
Preparation of transparent Y2O3 ceramic by slip casting and vacuum sintering Huo, Di; Zheng, Yanchun; Sun, Xudong Journal of Rare Earths, Vol. 30, Issue 1 https://doi.org/10.1016/s1002-0721(10)60639-4	journal	January 2012
Synthesis, rheological properties and magnetoviscos effect of Fe2O3/paraffin ferrofluids Hezaveh, Hadi; Fazlali, Alireza; Noshadi, Iman Journal of the Taiwan Institute of Chemical Engineers, Vol. 43, Issue 1 https://doi.org/10.1016/j.jtice.2011.07.003	journal	January 2012
Multisite proton adsorption modeling at the solid/solution interface of (hydr)oxides: A new approach Hiemstra, T.; De Wit, J. C. M.; Van Riemsdijk, W. H. Journal of Colloid and Interface Science, Vol. 133, Issue 1 https://doi.org/10.1016/0021-9797(89)90285-3	journal	November 1989
Interfacial behavior of water bound to zirconia/nanosilica with adsorbed poly(dimethylsiloxane) Gun’ko, V. M.; Sulym, I. Y.; Borysenko, M. V. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 426 https://doi.org/10.1016/j.colsurfa.2013.02.063	journal	June 2013
Formation of (H ⁺ , Al ⁺ , Al ²⁺ ) Co-Doped Bayerite and γ -Al ₂ O ₃ Plates from Spinel-Type Related Nanocondensates in Water Liu, I-Lung; Chen, Shuei-Yuan; Shen, Pouyan Journal of Nanoscience and Nanotechnology, Vol. 11, Issue 1 https://doi.org/10.1166/jnn.2011.3045	journal	January 2011
Bayerite (β-Al(OH) ₃ ) by XPS Rotole, John A.; Sherwood, Peter M. A. Surface Science Spectra, Vol. 5, Issue 1 https://doi.org/10.1116/1.1247855	journal	January 1998
Nordstrandite (Al(OH) ₃ ) by XPS Rotole, John A.; Sherwood, Peter M. A. Surface Science Spectra, Vol. 5, Issue 1 https://doi.org/10.1116/1.1247854	journal	January 1998
Gibbsite (α-Al(OH) ₃ ) by XPS Rotole, John A.; Sherwood, Peter M. A. Surface Science Spectra, Vol. 5, Issue 1 https://doi.org/10.1116/1.1247853	journal	January 1998
Calcination products of gibbsite studied by X-ray diffraction, XPS and solid-state NMR Malki, A.; Mekhalif, Z.; Detriche, S. Journal of Solid State Chemistry, Vol. 215 https://doi.org/10.1016/j.jssc.2014.03.019	journal	July 2014
Multiple scattering theory applied to ELNES of interfaces Brydson, Rik Journal of Physics D: Applied Physics, Vol. 29, Issue 7 https://doi.org/10.1088/0022-3727/29/7/004	journal	July 1996
A Mechanism for Non‐Newtonian Flow in Suspensions of Rigid Spheres Krieger, Irvin M.; Dougherty, Thomas J. Transactions of the Society of Rheology, Vol. 3, Issue 1 https://doi.org/10.1122/1.548848	journal	March 1959
In situ liquid-cell electron microscopy of colloid aggregation and growth dynamics Grogan, Joseph M.; Rotkina, Lolita; Bau, Haim H. Physical Review E, Vol. 83, Issue 6 https://doi.org/10.1103/PhysRevE.83.061405	journal	June 2011
Non‐Newtonian Viscosity of Solutions of Ellipsoidal Particles Scheraga, Harold A. The Journal of Chemical Physics, Vol. 23, Issue 8 https://doi.org/10.1063/1.1742341	journal	August 1955
Nanosized Carbon-Supported Manganese Oxide Phases as Lithium-Oxygen Battery Cathode Catalysts Kavakli, Cüneyt; Meini, Stefano; Harzer, Gregor ChemCatChem, Vol. 5, Issue 11 https://doi.org/10.1002/cctc.201300331	journal	September 2013
Nanoenhanced Materials for Reclamation of Mine Lands and Other Degraded Soils: A Review Liu, Ruiqiang; Lal, Rattan Journal of Nanotechnology, Vol. 2012 https://doi.org/10.1155/2012/461468	journal	January 2012
Effect of SiO2 and Al2O3 on the setting and hardening of high calcium fly ash-based geopolymer systems Chindaprasirt, Prinya; De Silva, Pre; Sagoe-Crentsil, Kwesi Journal of Materials Science, Vol. 47, Issue 12 https://doi.org/10.1007/s10853-012-6353-y	journal	March 2012
Elucidation of Viscosity Reduction Mechanism of Nano Alumina Suspensions with Fructose Addition by DSC Çinar, Simge; van Steenhuyse, Laura; Akinc, Mufit Journal of the American Ceramic Society, Vol. 96, Issue 4 https://doi.org/10.1111/jace.12232	journal	February 2013
Influence of bound water layer on the viscosity of oxide nanopowder suspensions Çınar, Simge; Anderson, Daniel D.; Akinc, Mufit Journal of the European Ceramic Society, Vol. 35, Issue 2 https://doi.org/10.1016/j.jeurceramsoc.2014.09.031	journal	February 2015
Relationship Between Water Mobility and Viscosity of Nanometric Alumina Suspensions Li, Chuanping; Akinc, Mufit; Wiench, Jerzy Journal of the American Ceramic Society, Vol. 88, Issue 10 https://doi.org/10.1111/j.1551-2916.2005.00535.x	journal	October 2005
Cryo-electron microscopy of biological nanostructures Glaeser, Robert M. Physics Today, Vol. 61, Issue 1 https://doi.org/10.1063/1.2835153	journal	January 2008
TiO ₂ and ZnO Nanoparticles in Photocatalytic and Hygienic Coatings Jašková, Veronika; Hochmannová, Libuše; Vytřasová, Jarmila International Journal of Photoenergy, Vol. 2013 https://doi.org/10.1155/2013/795060	journal	January 2013
Hydration of γ-Alumina in Water and Its Effects on Surface Reactivity Lefèvre, Grégory; Duc, Myriam; Lepeut, Patrick Langmuir, Vol. 18, Issue 20 https://doi.org/10.1021/la025651i	journal	October 2002
In Situ TEM Studies of Vapor- and Liquid-Phase Crystal Growth Ross, Frances M. In‐Situ Electron Microscopy: Applications in Physics, Chemistry and Materials Science https://doi.org/10.1002/9783527652167.ch7	book	April 2012
Multisite proton adsorption modeling at the solid/solution interface of (hydr)oxides: A new approach Hiemstra, T.; Van Riemsdijk, W. H.; Bolt, G. H. Journal of Colloid and Interface Science, Vol. 133, Issue 1 https://doi.org/10.1016/0021-9797(89)90284-1	journal	November 1989
Nanodiamonds Ho, Dean https://doi.org/10.1007/978-1-4419-0531-4	book	January 2010
Advanced Engineering Ceramics Greil, P. Advanced Engineering Materials, Vol. 4, Issue 5 https://doi.org/10.1002/1527-2648(20020503)4:5<247::aid-adem247>3.0.co;2-n	journal	May 2002
Viscosity affected by nanoparticle aggregation in Al2O3-water nanofluids Duan, Fei; Kwek, Dingtian; Crivoi, Alexandru Nanoscale Research Letters, Vol. 6, Issue 1 https://doi.org/10.1186/1556-276x-6-248	journal	March 2011
Practical surface analysis by Auger and X-ray photoelectron spectroscopy. D. Briggs and M. P. Seah (Editors). John Wiley and Sons Ltd, Chichester, 1983, 533 pp., £44.50 Castle, J. E. Surface and Interface Analysis, Vol. 6, Issue 6 https://doi.org/10.1002/sia.740060611	journal	December 1984
Influence of anisotropic pressure on viscosity and electrorheology of diethylene glycol-based MgAl2O4 nanofluids żyła, Gaweł; Grzywa, Joanna; Witek, Adam Nanoscale Research Letters, Vol. 9, Issue 1 https://doi.org/10.1186/1556-276x-9-170	journal	January 2014
Titanium dioxide and zinc oxide nanoparticles in sunscreens: focus on their safety and effectiveness Smijs, Threes Nanotechnology, Science and Applications, p. 95 https://doi.org/10.2147/NSA.S19419	journal	October 2011
Oxygen K-edge electron energy loss spectra of hydrous and anhydrous compounds Winkler, B.; Avalos-Borja, M.; Milman, V. Journal of Physics: Condensed Matter, Vol. 25, Issue 48 https://doi.org/10.1088/0953-8984/25/48/485401	journal	October 2013
Advanced Engineering Ceramics Greil, P. Advanced Materials, Vol. 14, Issue 10 https://doi.org/10.1002/1521-4095(20020517)14:10<709::AID-ADMA709>3.0.CO;2-9	journal	May 2002

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Title: Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

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