Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core

Elbert, Katherine; Hu, Jue; Ma, Zhong; Zhang, Yu; Chen, Guangyu; An, Wei; Liu, Ping; Isaacs, Hugh S.; Adzic, Radoslav R.; Wang, Jia X.

doi:10.1021/acscatal.5b01670

Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core

Journal Article · Tue Oct 13 00:00:00 EDT 2015 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.5b01670· OSTI ID:1223544

Elbert, Katherine ^[1]; Hu, Jue ^[1]; Ma, Zhong ^[1]; Zhang, Yu ^[1]; Chen, Guangyu ^[1]; An, Wei ^[1]; Liu, Ping ^[1]; Isaacs, Hugh S. ^[1]; Adzic, Radoslav R. ^[1]; Wang, Jia X. ^[1]

Chemistry Department, Brookhaven National Laboratory, Upton, New York 11973, United States

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1223544

Alternate ID(s):: OSTI ID: 1235883

Report Number(s):: BNL--111721-2016-JA

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 11 Vol. 5; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (42)

Modeling the electro-oxidation of CO and H2/CO on Pt, Ru, PtRu and Pt3Sn Liu, P.; Logadottir, A.; Nørskov, J. K. Electrochimica Acta, Vol. 48, Issue 25-26 https://doi.org/10.1016/S0013-4686(03)00538-3	journal	November 2003
A model for electrochemical proton-transfer reactions Pecina, O.; Schmickler, W. Chemical Physics, Vol. 228, Issue 1-3 https://doi.org/10.1016/S0301-0104(97)00299-1	journal	March 1998
Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs Gasteiger, Hubert A.; Kocha, Shyam S.; Sompalli, Bhaskar Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 9-35 https://doi.org/10.1016/j.apcatb.2004.06.021	journal	March 2005
Ruthenium-Alloy Electrocatalysts with Tunable Hydrogen Oxidation Kinetics in Alkaline Electrolyte St. John, Samuel; Atkinson, Robert W.; Unocic, Raymond R. The Journal of Physical Chemistry C, Vol. 119, Issue 24 https://doi.org/10.1021/acs.jpcc.5b03284	journal	June 2015
Solid-State Water Electrolysis with an Alkaline Membrane Leng, Yongjun; Chen, Guang; Mendoza, Alfonso J. Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja302439z	journal	May 2012
Platinum-Coated Copper Nanowires with High Activity for Hydrogen Oxidation Reaction in Base Alia, Shaun M.; Pivovar, Bryan S.; Yan, Yushan Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja405598a	journal	August 2013
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Intrinsic Barriers for Proton Transfer Reactions Involving Electronegative Atoms, and the Water Mediated Proton Switch: An Analysis in Terms of Marcus Theory Guthrie, J. Peter Journal of the American Chemical Society, Vol. 118, Issue 51 https://doi.org/10.1021/ja9618614	journal	January 1996
Effect of Temperature on Hydrogen Adsorption on Pt(111), Pt(110), and Pt(100) Electrodes in 0.1 M HClO ₄ Gómez, Roberto; Orts, José M.; Álvarez-Ruiz, Bernabé The Journal of Physical Chemistry B, Vol. 108, Issue 1 https://doi.org/10.1021/jp034982g	journal	January 2004
Electrocatalysis under Conditions of High Mass Transport: Investigation of Hydrogen Oxidation on Single Submicron Pt Particles Supported on Carbon Chen, Shengli; Kucernak, Anthony The Journal of Physical Chemistry B, Vol. 108, Issue 37 https://doi.org/10.1021/jp048641u	journal	September 2004
Hydrogen Oxidation Reaction on Pt in Acidic Media: Adsorption Isotherm and Activation Free Energies Wang, Jia. X.; Springer, Thomas E.; Liu, Ping The Journal of Physical Chemistry C, Vol. 111, Issue 33 https://doi.org/10.1021/jp073400i	journal	August 2007
Enthalpic and Entropic Effects on Hydrogen and OH Adsorption on Pt(111), Pt(100), and Pt(110) Electrodes As Evaluated by Gibbs Thermodynamics Garcia-Araez, Nuria The Journal of Physical Chemistry C, Vol. 115, Issue 2 https://doi.org/10.1021/jp1088146	journal	December 2010
Bifunctional Catalysts for Alkaline Oxygen Reduction Reaction via Promotion of Ligand and Ensemble Effects at Ag/MnO _x Nanodomains Slanac, Daniel A.; Lie, Anthony; Paulson, Joel A. The Journal of Physical Chemistry C, Vol. 116, Issue 20 https://doi.org/10.1021/jp3012816	journal	May 2012
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1574	journal	February 2013
High-performance Ag–Co alloy catalysts for electrochemical oxygen reduction Holewinski, Adam; Idrobo, Juan-Carlos; Linic, Suljo Nature Chemistry, Vol. 6, Issue 9 https://doi.org/10.1038/nchem.2032	journal	August 2014
Active and stable carbon nanotube/nanoparticle composite electrocatalyst for oxygen reduction Chung, Hoon T.; Won, Jong H.; Zelenay, Piotr Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2944	journal	May 2013
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution Grimaud, Alexis; May, Kevin J.; Carlton, Christopher E. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3439	journal	September 2013
Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts Hsieh, Yu-Chi; Zhang, Yu; Su, Dong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3466	journal	September 2013
Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy Sheng, Wenchao; Zhuang, Zhongbin; Gao, Minrui Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6848	journal	January 2015
Ultralow charge-transfer resistance with ultralow Pt loading for hydrogen evolution and oxidation using Ru@Pt core-shell nanocatalysts Wang, Jia X.; Zhang, Yu; Capuano, Christopher B. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12220	journal	July 2015
Pt–Ru catalyzed hydrogen oxidation in alkaline media: oxophilic effect or electronic effect? Wang, Ying; Wang, Gongwei; Li, Guangwei Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE02564D	journal	January 2015
Scalable synthesis of bi-functional high-performance carbon nanotube sponge catalysts and electrodes with optimum C–N–Fe coordination for oxygen reduction reaction Yang, Gang; Choi, Woongchul; Pu, Xiong Energy & Environmental Science, Vol. 8, Issue 6 https://doi.org/10.1039/C5EE00682A	journal	January 2015
High pressure pyrolyzed non-precious metal oxygen reduction catalysts for alkaline polymer electrolyte membrane fuel cells Sanetuntikul, Jakkid; Shanmugam, Sangaraju Nanoscale, Vol. 7, Issue 17 https://doi.org/10.1039/C5NR00311C	journal	January 2015
Fabrication of spinel ferrite based alkaline anion exchange membrane water electrolysers for hydrogen production Pandiarajan, T.; John Berchmans, L.; Ravichandran, S. RSC Advances, Vol. 5, Issue 43 https://doi.org/10.1039/C5RA01123J	journal	January 2015
Pyrochlore electrocatalysts for efficient alkaline water electrolysis Parrondo, Javier; George, Morgan; Capuano, Christopher Journal of Materials Chemistry A, Vol. 3, Issue 20 https://doi.org/10.1039/C5TA01771H	journal	January 2015
Density functional theory calculations for the hydrogen evolution reaction in an electrochemical double layer on the Pt(111) electrode Skúlason, Egill; Karlberg, Gustav S.; Rossmeisl, Jan Phys. Chem. Chem. Phys., Vol. 9, Issue 25 https://doi.org/10.1039/b700099e	journal	January 2007
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism Durst, J.; Siebel, A.; Simon, C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/c4ee00440j	journal	January 2014
Alkaline polymer electrolyte fuel cells completely free from noble metal catalysts Lu, S.; Pan, J.; Huang, A. Proceedings of the National Academy of Sciences, Vol. 105, Issue 52, p. 20611-20614 https://doi.org/10.1073/pnas.0810041106	journal	December 2008
"Special points for Brillouin-zone integrations"—a reply Pack, James D.; Monkhorst, Hendrik J. Physical Review B, Vol. 16, Issue 4 https://doi.org/10.1103/PhysRevB.16.1748	journal	August 1977
High-precision sampling for Brillouin-zone integration in metals Methfessel, M.; Paxton, A. T. Physical Review B, Vol. 40, Issue 6 https://doi.org/10.1103/PhysRevB.40.3616	journal	August 1989
Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation Perdew, John P.; Chevary, J. A.; Vosko, S. H. Physical Review B, Vol. 46, Issue 11 https://doi.org/10.1103/PhysRevB.46.6671	journal	September 1992
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Erratum: Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation Perdew, John P.; Chevary, J. A.; Vosko, S. H. Physical Review B, Vol. 48, Issue 7 https://doi.org/10.1103/PhysRevB.48.4978.2	journal	August 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Surface Strain versus Substrate Interaction in Heteroepitaxial Metal Layers: Pt on Ru(0001) Schlapka, A.; Lischka, M.; Groß, A. Physical Review Letters, Vol. 91, Issue 1 https://doi.org/10.1103/PhysRevLett.91.016101	journal	June 2003
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
Can CO-Tolerant Anodes be Economically Viable for PEMFC Applications with Reformates? Wang, J. X.; He, P.; Zhang, Y. ECS Transactions, Vol. 64, Issue 3 https://doi.org/10.1149/06403.0121ecst	journal	August 2014
Dual-Pathway Kinetic Equation for the Hydrogen Oxidation Reaction on Pt Electrodes Wang, Jia X.; Springer, Thomas E.; Adzic, Radoslav R. Journal of The Electrochemical Society, Vol. 153, Issue 9 https://doi.org/10.1149/1.2218756	journal	January 2006
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010

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Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core

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