Liquidus temperature and chemical durability of selected glasses to immobilize rare earth oxides waste

Journal Article · Tue Jun 30 04:00:00 EDT 2015 · Journal of Nuclear Materials, 465:657-663

DOI:https://doi.org/10.1016/j.jnucmat.2015.06.050· OSTI ID:1222890

Mohd Fadzil, Syazwani Binti; Hrma, Pavel R.; Schweiger, Michael J.; Riley, Brian J.

Pyroprocessing is a reprocessing method for managing and reusing used nuclear fuel (UNF) by dissolving it in an electrorefiner with a molten alkali or alkaline earth chloride salt mixture while avoiding wet reprocessing. Pyroprocessing UNF with a LiCl-KCl eutectic salt releases the fission products from the fuel and generates a variety of metallic and salt-based species, including rare earth (RE) chlorides. If the RE-chlorides are converted to oxides, borosilicate glass is a prime candidate for their immobilization because of its durability and ability to dissolve almost any RE waste component into the matrix at high loadings. Crystallization that occurs in waste glasses as the waste loading increases may complicate glass processing and affect the product quality. This work compares three types of borosilicate glasses in terms of liquidus temperature (TL): the International Simple Glass designed by the International Working Group, sodium borosilicate glass developed by Korea Hydro and Nuclear Power, and the lanthanide aluminoborosilicate (LABS) glass established in the United States. The LABS glass allows the highest waste loadings (over 50 mass% RE2O3) while possessing an acceptable chemical durability.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1222890
• Report Number(s): PNNL-SA-111234; 830403000
• Journal Information: Journal of Nuclear Materials, 465:657-663, Journal Name: Journal of Nuclear Materials, 465:657-663
• Country of Publication: United States
• Language: English

Related Subjects

crystallization
durability
liquidus temperature
rare earth waste glass