Synthesis of phase-pure and monodisperse iron oxide nanoparticles by thermal decomposition

Journal Article · Wed Jun 03 04:00:00 EDT 2015 · Nanoscale, 7(25):11142-11154

DOI:https://doi.org/10.1039/c5nr01651g· OSTI ID:1221470

Hufschmid, Ryan D.; Arami, Hamed; Ferguson, R. Matthew; Gonzales, Marcela; Teeman, Eric M.; Brush, Lucien N.; Browning, Nigel D.; Krishnan, Kannan M.

We present a comprehensive template for the design and synthesis of iron oxide nanoparticles with control over size, size distribution, phase, and resulting properties. Monodisperse superparamagnetic iron oxide nanoparticles were synthesized by thermal decomposition of three different iron containing precursors (iron oleate, iron pentacarbonyl, and iron oxyhydroxide) in organic solvents under a variety of synthetic conditions. We compare the suitability of these three kinetically controlled synthesis protocols, which have in common the use of iron oleate as a starting precursor or reaction intermediate, for producing nanoparticles with specific size and magnetic properties. Monodisperse particles were produced over a tunable range of sizes from approximately 2-30 nm. Reaction parameters such as precursor concentration, addition of surfactant, temperature, ramp rate, and time were adjusted to kinetically control size and size-distribution. In particular, large quantities of excess surfactant (up to 25:1 molar ratio) alter reaction kinetics and result in larger particles with uniform size; however, there is often a trade-off between large particles and a narrow size distribution. Iron oxide phase is also critical for establishing magnetic properties. As an example, we show the importance of obtaining the required iron oxide phase for application to Magnetic Particle Imaging (MPI), and describe how phase purity can be controlled.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1221470
• Report Number(s): PNNL-SA-108942; 48583
• Journal Information: Nanoscale, 7(25):11142-11154, Journal Name: Nanoscale, 7(25):11142-11154
• Country of Publication: United States
• Language: English

Related Subjects

Environmental Molecular Sciences Laboratory
Iron oxide nanoparticles