Low Surface Recombination Velocity in Solution-Grown CH3NH3PbBr3 Perovskite Single Crystal

Yang, Ye; Yan, Yong; Yang, Mengjin; Choi, Sukgeun; Zhu, Kai; Luter, Joseph M.; Beard, Matthew C.

doi:10.1038/ncomms8961

Title: Low Surface Recombination Velocity in Solution-Grown CH₃NH₃PbBr₃ Perovskite Single Crystal

Journal Article · Thu Aug 06 00:00:00 EDT 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms8961· OSTI ID:1220695

Yang, Ye ^[1]; Yan, Yong ^[1]; Yang, Mengjin ^[1]; Choi, Sukgeun ^[1]; Zhu, Kai ^[1]; Luter, Joseph M. ^[1]; Beard, Matthew C. ^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)

Organic-inorganic hybrid perovskites are attracting intense research effort due to their impressive performance in solar cells. While the carrier transport parameters such as mobility and bulk carrier lifetime shows sufficient characteristics, the surface recombination, which can have major impact on the solar cell performance, has not been studied. Here we measure surface recombination dynamics in CH₃NH₃PbBr₃ perovskite single crystals using broadband transient reflectance spectroscopy. The surface recombination velocity is found to be 3.4±0.1 10³ cm s^-1, B2–3 orders of magnitude lower than that in many important unpassivated semiconductors employed in solar cells. Our result suggests that the planar grain size for the perovskite thin films should be larger thanB30 mm to avoid the influence of surface recombination on the effective carrier lifetime.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1220695

Report Number(s):: NREL/JA-5900-63911

Journal Information:: Nature Communications, Vol. 6; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 368 works

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