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A study on the superconducting properties of YBa{sub 2}Cu{sub 9-x}Nb{sub x}O{sup y} thin films

Conference ·
OSTI ID:121664
;  [1];  [2]
  1. Univ. of Hyderabad (India)
  2. Solid State Electronics Group, Bombay (India); and others

Effect of niobium substitution at the copper site in YBa{sub 2}Cu{sub 9}O{sub 7-x} was studied in thin film form. The films were deposited by laser ablation technique using the targets of the YBa{sub 2}Cu{sub 3-x}Nb{sub x}O{sub y} where x = 0.0, 0.025, 0.05, 0.1, 0.2, 0.4, 0.8 and 1.0 under identical deposition conditions on SrTiO{sub 9} <100> substrates. Films were characterized by XRD, resistivity, I-V and J{sub c} measurements. Films made from x = 0.025 and 0.05 concentrations of Nb substituted targets showed relatively improved superconducting properties compared to that of undoped films. The best 7 realized for x = 0.025 Nb concentration was 1.8 x 10{sup {sigma}} A/cm{sup 2} and for 0.05 Nb concentration it was 3.2x10{sup {sigma}} A/cm{sup 2} at 77K. However, degradation of the superconducting properties, with the increase of x {ge} 0.1 Nb concentration and drastic suppression and complete loss of superconductivity was noticed for x {ge} 0.4. The growth of impurity phase YBa{sub 2}NbO{sub 6} for x = 0.1 and above of Nb concentration was noticed from XRD patterns. However, the site occupancy of Nb could not be confirmed from these studies.

Research Organization:
National Aeronautics and Space Administration, Washington, DC (United States); National Aeronautics and Space Administration, Houston, TX (United States). Lyndon B. Johnson Space Center
OSTI ID:
121664
Report Number(s):
CONF-940627--Vol.2; ON: TI95017155
Country of Publication:
United States
Language:
English

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