Olefin metathesis for effective polymer healing via dynamic exchange of strong carbon-carbon bonds

Guan, Zhibin; Lu, Yixuan

Olefin metathesis for effective polymer healing via dynamic exchange of strong carbon-carbon bonds

Patent · Tue Sep 15 04:00:00 EDT 2015

OSTI ID:1215548

Guan, Zhibin; Lu, Yixuan

A method of preparing a malleable and/or self-healing polymeric or composite material is provided. The method includes providing a polymeric or composite material comprising at least one alkene-containing polymer, combining the polymer with at least one homogeneous or heterogeneous transition metal olefin metathesis catalyst to form a polymeric or composite material, and performing an olefin metathesis reaction on the polymer so as to form reversible carbon-carbon double bonds in the polymer. Also provided is a method of healing a fractured surface of a polymeric material. The method includes bringing a fractured surface of a first polymeric material into contact with a second polymeric material, and performing an olefin metathesis reaction in the presence of a transition metal olefin metathesis catalyst such that the first polymeric material forms reversible carbon-carbon double bonds with the second polymeric material. Compositions comprising malleable and/or self-healing polymeric or composite material are also provided.

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Research Organization:: The Regents of the University of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-04ER46162

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Number(s):: 9,133,313

Application Number:: 13/962,380

OSTI ID:: 1215548

Country of Publication:: United States

Language:: English

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