Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

Qu, Jun; Barnhill, William C.; Luo, Huimin; Meyer, III, Harry M.; Leonard, Donovan N.; Landauer, Alexander K.; Kheireddin, Bassem; Gao, Hong; Papke, Brian L; Dai, Sheng

doi:10.1002/adma.201502037

Synergistic Effects Between Phosphonium-Alkylphosphate Ionic Liquids and Zinc Dialkyldithiophosphate (ZDDP) as Lubricant Additives

Journal Article · Tue Jul 14 00:00:00 EDT 2015 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201502037· OSTI ID:1212355

Qu, Jun ^[1]; Barnhill, William C. ^[1]; Luo, Huimin ^[2]; Meyer, III, Harry M. ^[1]; Leonard, Donovan N. ^[1]; Landauer, Alexander K. ^[1]; Kheireddin, Bassem ^[3]; Gao, Hong ^[3]; Papke, Brian L ^[3]; Dai, Sheng ^[4]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Div.
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Div.
Shell Global Solutions, Houston, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Div.

Unique synergistic effects between phosphonium-alkylphosphate ionic liquids and zinc dialkyldithiophosphate (ZDDP) are discovered when used together as lubricant additives, resulting in significant friction and wear reduction along with distinct tribofilm composition and mechanical properties. The synergism is attributed to the 30-70× higher-than-nominal concentrations of hypothetical new compounds (via anion exchange between IL and ZDDP) on the fluid surface/interface.

View Accepted Manuscript (DOE)

Research Organization:: Center for Nanophase Materials Sciences (CNMS); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1212355

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 32 Vol. 27; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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