Performance evaluation of trimethylamine-carbon dioxide thermolytic draw solution for engineered osmosis

Journal Article · Thu Jan 01 04:00:00 EST 2015 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2014.09.026· OSTI ID:1211088

Boo, C; Khalil, YF; Elimelech, M

We evaluated the performance of trimethylamine-carbon dioxide (TMA-CO2) as a potential thermolytic draw solution for engineered osmosis. Water flux and reverse solute flux with TMA-CO2 draw solution were measured in forward osmosis (FO) and pressure retarded osmosis (PRO) modes using thin-film composite (TFC) and cellulose triacetate (CTA) FO membranes. Water flux with the TMA-CO2 draw solution was comparable to that obtained with the more common ammonia-carbon dioxide (NH3-CO2) thermolytic draw solution at similar (1 M) concentration. Using a TFC-FO membrane, the water fluxes produced by 1 M TMA-CO2 and NH3-CO2 draw solutions with a DI water feed were, respectively, 33.4 and 35.6 L m(-2) h(-1) in PRO mode and 14.5 and 152 L m(-2) h(-1) in FO mode. Reverse draw permeation of TMA-CO2 was relatively low compared to NH3-CO2, ranging from 0.1 to 0.2 mol m(-2) h(-1) in all experiments, due to the larger molecular size of TMA. Thermal separation and recovery efficiency for TMA-CO2 was compared to NH3-CO2 by modeling low-temperature vacuum distillation utilizing low-grade heat sources. We also discuss possible challenges in the use TMA-CO2, including potential adverse impact on human health and environments. (C) 2014 Elsevier B.V. All rights reserved.

• Sponsoring Organization: USDOE Advanced Research Projects Agency - Energy (ARPA-E)
• DOE Contract Number: AR0000306
• OSTI ID: 1211088
• Journal Information: Journal of Membrane Science, Journal Name: Journal of Membrane Science Vol. 473; ISSN 0376-7388
• Country of Publication: United States
• Language: English