Effect of a Size-Dependent Equilibrium Potential on Nano-LiFePO4 Particle Interactions

Orvananos, Bernardo; Yu, Hui-Chia; Malik, Rahul; Abdellahi, Aziz; Grey, Clare P.; Ceder, Gerbrand; Thornton, Katsuyo

doi:10.1149/2.0161509jes

Title: Effect of a Size-Dependent Equilibrium Potential on Nano-LiFePO4 Particle Interactions

Journal Article · Tue Jun 09 00:00:00 EDT 2015 · Journal of Electrochemical Society

DOI:https://doi.org/10.1149/2.0161509jes· OSTI ID:1210852

Orvananos, Bernardo; Yu, Hui-Chia; Malik, Rahul; Abdellahi, Aziz; Grey, Clare P.; Ceder, Gerbrand; Thornton, Katsuyo

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Northeastern Center for Chemical Energy Storage (NECCES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001294

OSTI ID:: 1210852

Journal Information:: Journal of Electrochemical Society, Vol. 162 (9); Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University

Country of Publication:: United States

Language:: English

References (32)

A Critical Review of the Li Insertion Mechanisms in LiFePO ₄ Electrodes Malik, Rahul; Abdellahi, Aziz; Ceder, Gerbrand Journal of The Electrochemical Society, Vol. 160, Issue 5 https://doi.org/10.1149/2.029305jes	journal	January 2013
Olivine LiFePO ₄ : development and future Wang, Yonggang; He, Ping; Zhou, Haoshen Energy Environ. Sci., Vol. 4, Issue 3 https://doi.org/10.1039/C0EE00176G	journal	January 2011
Room-temperature miscibility gap in LixFePO4 Yamada, Atsuo; Koizumi, Hiroshi; Nishimura, Shin-ichi Nature Materials, Vol. 5, Issue 5 https://doi.org/10.1038/nmat1634	journal	April 2006
Kinetics of non-equilibrium lithium incorporation in LiFePO4 Malik, Rahul; Zhou, Fei; Ceder, G. Nature Materials, Vol. 10, Issue 8 https://doi.org/10.1038/nmat3065	journal	July 2011
Suppression of Phase Separation in LiFePO ₄ Nanoparticles During Battery Discharge Bai, Peng; Cogswell, Daniel A.; Bazant, Martin Z. Nano Letters, Vol. 11, Issue 11 https://doi.org/10.1021/nl202764f	journal	November 2011
Coherency Strain and the Kinetics of Phase Separation in LiFePO ₄ Nanoparticles Cogswell, Daniel A.; Bazant, Martin Z. ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn204177u	journal	February 2012
The thermodynamic origin of hysteresis in insertion batteries Dreyer, Wolfgang; Jamnik, Janko; Guhlke, Clemens Nature Materials, Vol. 9, Issue 5 https://doi.org/10.1038/nmat2730	journal	April 2010
The behavior of a many-particle electrode in a lithium-ion battery Dreyer, Wolfgang; Guhlke, Clemens; Huth, Robert Physica D: Nonlinear Phenomena, Vol. 240, Issue 12 https://doi.org/10.1016/j.physd.2011.02.011	journal	June 2011
A comparison of mathematical models for phase-change in high-rate LiFePO4 cathodes Dargaville, S.; Farrell, T. W. Electrochimica Acta, Vol. 111 https://doi.org/10.1016/j.electacta.2013.08.014	journal	November 2013
Nonequilibrium Thermodynamics of Porous Electrodes Ferguson, Todd R.; Bazant, Martin Z. Journal of The Electrochemical Society, Vol. 159, Issue 12 https://doi.org/10.1149/2.048212jes	journal	January 2012
Phase Transformation Dynamics in Porous Battery Electrodes Ferguson, Todd R.; Bazant, Martin Z. Electrochimica Acta, Vol. 146 https://doi.org/10.1016/j.electacta.2014.08.083	journal	November 2014
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes Liu, H.; Strobridge, F. C.; Borkiewicz, O. J. Science, Vol. 344, Issue 6191 https://doi.org/10.1126/science.1252817	journal	June 2014
Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes Li, Yiyang; El Gabaly, Farid; Ferguson, Todd R. Nature Materials, Vol. 13, Issue 12 https://doi.org/10.1038/nmat4084	journal	September 2014
Particle-Level Modeling of the Charge-Discharge Behavior of Nanoparticulate Phase-Separating Li-Ion Battery Electrodes Orvananos, Bernardo; Ferguson, Todd R.; Yu, Hui-Chia Journal of The Electrochemical Society, Vol. 161, Issue 4 https://doi.org/10.1149/2.024404jes	journal	January 2014
Architecture Dependence on the Dynamics of Nano-LiFePO4 Electrodes Orvananos, Bernardo; Malik, Rahul; Yu, Hui-Chia Electrochimica Acta, Vol. 137 https://doi.org/10.1016/j.electacta.2014.06.029	journal	August 2014
Kinetics of Nanoparticle Interactions in Battery Electrodes Orvananos, Bernardo; Yu, Hui-Chia; Abdellahi, Aziz Journal of The Electrochemical Society, Vol. 162, Issue 6 https://doi.org/10.1149/2.0481506jes	journal	January 2015
Memory effect in a lithium-ion battery Sasaki, Tsuyoshi; Ukyo, Yoshio; Novák, Petr Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3623	journal	April 2013
Effect of surface energies and nano-particle size distribution on open circuit voltage of Li-electrodes Van der Ven, A.; Wagemaker, M. Electrochemistry Communications, Vol. 11, Issue 4 https://doi.org/10.1016/j.elecom.2009.02.015	journal	April 2009
Size-Dependent Lithium Miscibility Gap in Nanoscale Li[sub 1−x]FePO[sub 4] Meethong, Nonglak; Huang, Hsiao-Ying Shadow; Carter, W. Craig Electrochemical and Solid-State Letters, Vol. 10, Issue 5 https://doi.org/10.1149/1.2710960	journal	January 2007
Proof of Intercrystallite Ionic Transport in LiMPO ₄ Electrodes (M = Fe, Mn) Lee, Kyu Tae; Kan, Wang H.; Nazar, Linda F. Journal of the American Chemical Society, Vol. 131, Issue 17 https://doi.org/10.1021/ja8090559	journal	May 2009
Extended smoothed boundary method for solving partial differential equations with general boundary conditions on complex boundaries Yu, Hui-Chia; Chen, Hsun-Yi; Thornton, K. Modelling and Simulation in Materials Science and Engineering, Vol. 20, Issue 7 https://doi.org/10.1088/0965-0393/20/7/075008	journal	September 2012
Rate-Induced Solubility and Suppression of the First-Order Phase Transition in Olivine LiFePO ₄ Zhang, Xiaoyu; van Hulzen, Martijn; Singh, Deepak P. Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl404285y	journal	April 2014
Theoretical Analysis of Current Distribution in Porous Electrodes Newman, John S.; Tobias, Charles W. Journal of The Electrochemical Society, Vol. 109, Issue 12 https://doi.org/10.1149/1.2425269	journal	January 1962
First-principles study of surface properties of $Li Fe P O_{4}$ : Surface energy, structure, Wulff shape, and surface redox potential Wang, L.; Zhou, F.; Meng, Y. S. Physical Review B, Vol. 76, Issue 16 https://doi.org/10.1103/PhysRevB.76.165435	journal	October 2007
Li-ion diffusion kinetics in LiFePO4 thin film prepared by radio frequency magnetron sputtering Xie, J.; Imanishi, N.; Zhang, T. Electrochimica Acta, Vol. 54, Issue 20 https://doi.org/10.1016/j.electacta.2009.03.007	journal	August 2009
Galvanostatic Intermittent Titration Technique for Phase-Transformation Electrodes Zhu, Yujie; Wang, Chunsheng The Journal of Physical Chemistry C, Vol. 114, Issue 6 https://doi.org/10.1021/jp9113333	journal	January 2010
Ion–ion interactions of LiPF6 and LiBF4 in propylene carbonate solutions Takeuchi, Munetaka; Kameda, Yasuo; Umebayashi, Yasuhiro Journal of Molecular Liquids, Vol. 148, Issue 2-3 https://doi.org/10.1016/j.molliq.2009.07.003	journal	September 2009
Alternating-Direction Line-Relaxation Methods on Multicomputers Hofhaus, Jörn; Van de Velde, Eric F. SIAM Journal on Scientific Computing, Vol. 17, Issue 2 https://doi.org/10.1137/S1064827593253872	journal	March 1996
Concurrent Scientific Computing Van de Velde, Eric F. Texts in Applied Mathematics https://doi.org/10.1007/978-1-4612-0849-5	book	January 1994
MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO ₄ /FePO ₄ System ^† Cabana, Jordi; Shirakawa, Junichi; Chen, Guoying Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902714v	journal	February 2010
Mapping the Inhomogeneous Electrochemical Reaction Through Porous LiFePO ₄ -Electrodes in a Standard Coin Cell Battery Strobridge, Fiona C.; Orvananos, Bernardo; Croft, Mark Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/cm504317a	journal	March 2015
Tracking inhomogeneity in high-capacity lithium iron phosphate batteries Paxton, William A.; Zhong, Zhong; Tsakalakos, Thomas Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.035	journal	February 2015

Similar Records

Particle-size and morphology dependence of the preferred interface orientation in LiFePO₄ nano-particles

Journal Article · Wed Jan 01 00:00:00 EST 2014 · Journal of Materials Chemistry. A · OSTI ID:1210852

Abdellahi, Aziz; Akyildiz, Oncu; Malik, Rahul; +2 more

Particle-size and morphology dependence of the preferred interface orientation in LiFePO ₄ nano-particles

Journal Article · Wed Jan 01 00:00:00 EST 2014 · Journal of Materials Chemistry. A · OSTI ID:1210852

Abdellahi, Aziz; Akyildiz, Oncu; Malik, Rahul; +2 more

Architecture Dependence on the Dynamics of Nano-LiFePO4 Electrodes

Journal Article · · Electrochimica Acta · OSTI ID:1210852

Orvananos, Bernardo; Yu, Hui-Chia; Thornton, Katsuyo; +4 more

Related Subjects

energy storage (including batteries and capacitors)
defects
charge transport
materials and chemistry by design
synthesis (novel materials)

Title: Effect of a Size-Dependent Equilibrium Potential on Nano-LiFePO4 Particle Interactions

Citation Formats

References (32)

Similar Records

Related Subjects