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Title: The influence of temperature, pH, and growth rate on the δ18O composition of inorganically precipitated calcite

Journal Article · · Earth and Planetary Science Letters

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Nanoscale Control of Geologic CO2 (NCGC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
AC02–05CH11231
OSTI ID:
1210714
Journal Information:
Earth and Planetary Science Letters, Vol. 404; Related Information: NCGC partners with Lawrence Berkeley National Laboratory (lead); University of California, Davis; Lawrence Livermore National Laboratory; Massachusetts Institute of Technology; Ohio State University; Oak Ridge National Laboratory; Washington University, St. Louis
Country of Publication:
United States
Language:
English

References (52)

Clumped isotopic equilibrium and the rate of isotope exchange between CO2 and water journal April 2013
Experimental studies of oxygen isotope fractionation in the carbonic acid system at 15°, 25°, and 40°C journal July 2005
Reevaluation of the oxygen isotopic composition of planktonic foraminifera: Experimental results and revised paleotemperature equations journal April 1998
Stable isotope disequilibria in travertine from high pH waters: Laboratory investigations and field observations from Oman journal May 1992
Calibration of the calcite–water oxygen-isotope geothermometer at Devils Hole, Nevada, a natural laboratory journal August 2007
Comment on “An explanation of the effect of seawater carbonate concentration on foraminiferal oxygen isotopes,” by R. E. Zeebe (1999) journal February 2005
Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solutions journal February 2011
Oxygen isotopic fractionation during inorganic calcite precipitation ― Effects of temperature, precipitation rate and pH journal October 2009
“Clumped-isotope” geochemistry—The study of naturally-occurring, multiply-substituted isotopologues journal October 2007
Surface speciation of calcite observed in situ by high-resolution X-ray reflectivity journal April 2000
Oxygen isotope fractionation between calcite and fluid as a function of growth rate and temperature: An in situ study journal May 2012
13C–18O bonds in carbonate minerals: A new kind of paleothermometer journal March 2006
Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems journal October 2012
Equilibrium and nonequilibrium oxygen isotope effects in synthetic carbonates journal August 1997
Devils Hole paleotemperatures and implications for oxygen isotope equilibrium fractionation journal August 2014
The chemical microenvironment of the symbiotic planktonic foraminifer Orbulina universa journal March 2005
Carbonic anhydrase: Enzyme that has transformed the biosphere journal March 2011
Near-surface controls on the composition of growing crystals: Car–Parrinello molecular dynamics (CPMD) simulations of Ti energetics and diffusion in alpha quartz journal April 2014
The effect of the Ca2+ to activity ratio on spiral growth at the calcite surface journal April 2010
On the Isotopic Chemistry of Carbonates and a Paleotemperature Scale journal June 1950
Dissociation constants of carbonic acid in seawater as a function of salinity and temperature journal June 2006
Calcium Carbonate Formation and Dissolution journal February 2007
Dependence of calcite growth rate and Sr partitioning on solution stoichiometry: Non-Kossel crystal growth journal May 2007
Electrolyte crystal growth mechanisms journal July 1984
Self-consistent ion-by-ion growth model for kinetic isotopic fractionation during calcite precipitation journal June 2012
A mechanistic model for calcite crystal growth using surface speciation journal January 1999
Seasonal climate signals (1990–2008) in a modern Soreq Cave stalagmite as revealed by high-resolution geochemical analysis journal January 2014
Paleoelevation Reconstruction using Pedogenic Carbonates journal October 2007
Microsensor studies of photosynthesis and respiration in the symbiotic foraminifer Orbulina universa journal July 1998
Carbon isotopic fractionation in synthetic aragonite and calcite: Effects of temperature and precipitation rate journal January 1992
A new approach to stable isotope-based paleoaltimetry: implications for paleoaltimetry and paleohypsometry of the High Himalaya since the Late Miocene journal May 2001
Effect of pH on calcite growth at constant ratio and supersaturation journal January 2011
Effect of seawater carbonate concentration on foraminiferal carbon and oxygen isotopes journal December 1997
Sr2+/Ca2+ and 44Ca/40Ca fractionation during inorganic calcite formation: I. Sr incorporation journal August 2008
Evaluation of kinetic effects on clumped isotope fractionation (Δ47) during inorganic calcite precipitation journal June 2014
A unified approach to model uptake kinetics of trace elements in complex aqueous – solid solution systems journal February 2014
Speleothem calcite farmed in situ: Modern calibration of δ18O and δ13C paleoclimate proxies in a continuously-monitored natural cave system journal September 2011
The effect of carbonic anhydrase on the kinetics and equilibrium of the oxygen isotope exchange in the CO2–H2O system: Implications for δ18O vital effects in biogenic carbonates journal October 2012
The thermodynamic properties of isotopic substances journal January 1947
Oxygen isotope exchange between carbonic acid, bicarbonate, carbonate, and water: A re-examination of the data of McCrea (1950) and an expression for the overall partitioning of oxygen isotopes between the carbonate species and water journal August 1993
Oxygen isotope fractionation between aragonite and seawater: Developing a novel kinetic oxygen isotope fractionation model journal September 2013
The influence of kinetics on the oxygen isotope composition of calcium carbonate journal August 2013
A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals 1 1Associate editor: R.H. Byrne journal April 2004
The surface chemistry of divalent metal carbonate minerals; a critical assessment of surface charge and potential data using the charge distribution multi-site ion complexation model journal October 2008
Calcite growth kinetics: Modeling the effect of solution stoichiometry journal January 2012
Variations in calcite growth kinetics with surface topography: molecular dynamics simulations and process-based growth kinetics modelling journal January 2013
Trends, Rhythms, and Aberrations in Global Climate 65 Ma to Present journal April 2001
An explanation of the effect of seawater carbonate concentration on foraminiferal oxygen isotopes journal July 1999
Reply to the comment by P. Deines on “An explanation of the effect of seawater carbonate concentration on foraminiferal oxygen isotopes,” by R. E. Zeebe (1999) journal February 2005
An expression for the overall oxygen isotope fractionation between the sum of dissolved inorganic carbon and water: OXYGEN ISOTOPES journal September 2007
On the molecular diffusion coefficients of dissolved , and and their dependence on isotopic mass journal May 2011
3. Paleoelevation Reconstruction using Pedogenic Carbonates book December 2007

Cited By (15)

Are aragonite stalagmites reliable paleoclimate proxies? Tests for oxygen isotope time-series replication and equilibrium journal April 2015
The origin of carbon isotope vital effects in coccolith calcite journal March 2017
Seasonal temperatures from δ 18 O in recent Spanish tufa stromatolites: Equilibrium redux! journal February 2018
Assessing kinetic fractionation in brachiopod calcite using clumped isotopes journal January 2018
Assessment of Factors Controlling Clumped Isotopes and δ 18 O Values of Hydrothermal Vent Calcites journal June 2018
Equatorial heat accumulation as a long-term trigger of permanent Antarctic ice sheets during the Cenozoic journal October 2016
Geochronology and Stable Isotope Analysis of Fracture-Fill and Karst Mineralization Reveal Sub-Surface Paleo-Fluid Flow and Microbial Activity of the COSC-1 Borehole, Scandinavian Caledonides journal February 2020
Vanishing coccolith vital effects with alleviated carbon limitation journal January 2016
Most Earth-surface calcites precipitate out of isotopic equilibrium journal January 2019
Control of ambient pH on growth and stable isotopes in phytoplanktonic calcifying algae: COCCOLITHOPHORE VITAL EFFECT AND PH journal August 2015
Reconstruction of sea-surface temperatures in the Canary Islands during Marine Isotope Stage 11 journal November 2019
Enzymatically catalyzed CO 2 ‐H 2 O equilibration for oxygen isotope analyses of aqueous samples journal June 2019
A Kinetic Difference Between 12 C- and 13 C-Bound Oxygen Exchange Rates Results in Decoupled δ 18 O and Δ 47 Values of Equilibrating DIC Solutions journal August 2018
Stable isotopic and elemental characteristics of recent tufa from a karstic Krka River (south-east Slovenia): useful environmental proxies? journal December 2016
Biological and environmental signals recorded in shells of Argonauta argo (Cephalopoda, Octobrachia) from the Sea of Japan journal October 2015

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