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Title: Dechlorination of small quantities of mixed waste from a DOE site

Technical Report ·
OSTI ID:121047

Sludge from tank bottoms containing PCB`s, radioactivity and hazardous constituents are present in several tanks at one of the National Laboratories. Disposal of the material can proceed if the material is removed from TSCA regulations by decreasing the concentration of the PCB`s to {le}2 ppm. ON the bench scale, this sludge was treated by the DECHLOR/KGME{sup {trademark}} chemical dechlorination process. The levels of PCB`s were reduced to below 2 ppm, allowing the material to be managed outside the TSCA regulations. RUST believes that this is the first successful chemical dechlorination of a radioactive, RCRA listed, PCB bearing waste. A pilot scale unit is available to provide on-site treatment of the remaining waste. Because of the small amounts of waste, treatment costs are high on a per unit volume. As a result of these high costs and other concerns the client is investigating potential non-treatment options of delisting the waste of obtaining a waiver. In the event that this particular waste cannot be delisted or a waiver is not granted, then dechlorination of the waste to remove it from TSCA regulations remains a viable option to allow the material to be disposed.

Research Organization:
Univ. of Arizona, Tucson, AZ (United States). Coll. of Engineering and Mines; New Mexico State Univ., Las Cruces, NM (United States); Waste-Management Education and Research Consortium (WERC), Las Cruces, NM (United States); US Department of Energy (USDOE), Washington DC (United States)
OSTI ID:
121047
Report Number(s):
CONF-940225-Vol.2; TRN: 95:007146-0025
Resource Relation:
Conference: Waste management `94: working towards a cleaner environment, Tucson, AZ (United States), 27 Feb - 3 Mar 1994; Other Information: PBD: 1994; Related Information: Is Part Of Technology and programs for Radioactive Waste Management and Environmental Restoration. Volume 2; Post, R.G. [ed.] [Arizona Univ., Tucson, AZ (United States). College of Engineering and Mines]; PB: 750 p.
Country of Publication:
United States
Language:
English