Dechlorination of small quantities of mixed waste from a DOE site

Technical Report · Sat Dec 31 04:00:00 EST 1994

OSTI ID:121047

Hoeffner, S L

Sludge from tank bottoms containing PCB`s, radioactivity and hazardous constituents are present in several tanks at one of the National Laboratories. Disposal of the material can proceed if the material is removed from TSCA regulations by decreasing the concentration of the PCB`s to {le}2 ppm. ON the bench scale, this sludge was treated by the DECHLOR/KGME{sup {trademark}} chemical dechlorination process. The levels of PCB`s were reduced to below 2 ppm, allowing the material to be managed outside the TSCA regulations. RUST believes that this is the first successful chemical dechlorination of a radioactive, RCRA listed, PCB bearing waste. A pilot scale unit is available to provide on-site treatment of the remaining waste. Because of the small amounts of waste, treatment costs are high on a per unit volume. As a result of these high costs and other concerns the client is investigating potential non-treatment options of delisting the waste of obtaining a waiver. In the event that this particular waste cannot be delisted or a waiver is not granted, then dechlorination of the waste to remove it from TSCA regulations remains a viable option to allow the material to be disposed.

• Research Organization: Arizona Univ., Tucson, AZ (United States). Coll. of Engineering and Mines; New Mexico State Univ., University Park, NM (United States); Waste-Management Education and Research Consortium (WERC), Las Cruces, NM (United States); USDOE, Washington, DC (United States)
• OSTI ID: 121047
• Report Number(s): CONF-940225--Vol.2
• Country of Publication: United States
• Language: English

Related Subjects

05 NUCLEAR FUELS
DECHLORINATION
ORGANIC WASTES
RADIOACTIVE WASTE PROCESSING
RADIOACTIVE WASTES
SLUDGES
TANKS
TESTING