Direct, single-step synthesis of hierarchical zeolites without secondary templating

Wang, Zhuopeng; Li, Chao; Cho, Hong Je; Kung, Shih-Chieh; Snyder, Mark A.; Fan, Wei

doi:10.1039/c4ta05031b

Direct, single-step synthesis of hierarchical zeolites without secondary templating

Journal Article · Tue Nov 25 00:00:00 EST 2014 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c4ta05031b· OSTI ID:1210431

Wang, Zhuopeng ^[1]; Li, Chao ^[2]; Cho, Hong Je ^[3]; Kung, Shih-Chieh ^[4]; Snyder, Mark A. ^[4]; Fan, Wei ^[1]

Univ. of Massachusetts, Amherst, MA (United States)
Univ. of Massachusetts, Amherst, MA (United States); South China Univ. of Technology (SCUT), Guangzhou (China)
Department of Chemical Engineering; University of Massachusetts Amherst; USA
Lehigh Univ., Bethlehem, PA (United States)

Here, hierarchical ZSM-5 was directly synthesized by controlling the nucleation, growth and template-free self-assembly of zeolite precursors formed in the initial stage of the zeolite crystallization process. The facile synthesis results in spherical particles primarily composed of a micro-mesoporous core of aggregated 30–50 nm MFI nanocrystals, and a thin crystalline shell. MFI nanocrystal assembly coupled with a possible dissolution–crystallization mechanism results in a template-free route to broadly distributed mesopores and, thereby, a ca. 25 nm diffusion length in a micrometer-sized particle. The materials exhibit enhanced mass transport and superior catalytic activity for bulky molecules.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI)

Sponsoring Organization:: Chinese Scholarship Council (CSC); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001004

OSTI ID:: 1210431

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 3 Vol. 3; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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