General features of the dissociative recombination of polyatomic molecules

Journal Article · Thu Jan 29 00:00:00 EST 2015 · EPJ Web of Conferences

DOI:https://doi.org/10.1051/epjconf/20158404001· OSTI ID:1209111

Pratt, S. T. ^[1]; Jungen, Ch. ^[2]; Schneider, I. F.; Dulieu, O.; Robert, J.

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1. Argonne National Lab. (ANL), Argonne, IL (United States)
2. Universite de Paris-Sud, Orsay (France). 2Laboratoire Aimé Cotton du CNRS; Univ. College London (United Kingdom). Dept. of Physics and Astronomy.

We discuss some aspects of a simple expression for the low-energy dissociative recombination cross section that applies when the recombination process is dominated by the indirect mechanism. In most previous applications, this expression has been applied to capture into vibrationally excited Rydberg states with the assumption that capture is always followed by prompt dissociation. Here we consider the dissociative recombination of larger polyatomic ions and electrons. More specifically, we consider capture into electronically core-excited Rydberg states, and begin to assess its potential importance for larger systems.

• Research Organization: Argonne National Laboratory (ANL), Argonne, IL (United States)
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
• Grant/Contract Number: AC02-06CH11357
• OSTI ID: 1209111
• Journal Information: EPJ Web of Conferences, Journal Name: EPJ Web of Conferences Vol. 84; ISSN 2100-014X
• Publisher: EDP Sciences
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS