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Title: Highly active non-PGM catalysts prepared from metal organic frameworks

Abstract

Finding inexpensive alternatives to platinum group metals (PGMs) is essential for reducing the cost of proton exchange membrane fuel cells (PEMFCs). Numerous materials have been investigated as potential replacements of Pt, of which the transition metal and nitrogen-doped carbon composites (TM/N x/C) prepared from iron doped zeolitic imidazolate frameworks (ZIFs) are among the most active ones in catalyzing the oxygen reduction reaction based on recent studies. In this report, we demonstrate that the catalytic activity of ZIF-based TM/N x/C composites can be substantially improved through optimization of synthesis and post-treatment processing conditions. Ultimately, oxygen reduction reaction (ORR) electrocatalytic activity must be demonstrated in membrane-electrode assemblies (MEAs) of fuel cells. The process of preparing MEAs using ZIF-based non-PGM electrocatalysts involves many additional factors which may influence the overall catalytic activity at the fuel cell level. Evaluation of parameters such as catalyst loading and perfluorosulfonic acid ionomer to catalyst ratio were optimized. Our overall efforts to optimize both the catalyst and MEA construction process have yielded impressive ORR activity when tested in a fuel cell system.

Authors:
 [1];  [2];  [2];  [3];  [2]
  1. Argonne National Lab. (ANL), Argonne, IL (United States); Northern Illinois Univ., DeKalb, IL (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Northern Illinois Univ., DeKalb, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office
OSTI Identifier:
1208863
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Catalysts
Additional Journal Information:
Journal Volume: 5; Journal Issue: 2; Journal ID: ISSN 2073-4344
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 30 DIRECT ENERGY CONVERSION; non-PGM catalyst; proton exchange membrane fuel cell (PEMFC); oxygen reduction reaction (ORR); zeolitic imidazolate framework (ZIF)

Citation Formats

Barkholtz, Heather M., Chong, Lina, Kaiser, Zachary B., Xu, Tao, and Liu, Di -Jia. Highly active non-PGM catalysts prepared from metal organic frameworks. United States: N. p., 2015. Web. doi:10.3390/catal5020955.
Barkholtz, Heather M., Chong, Lina, Kaiser, Zachary B., Xu, Tao, & Liu, Di -Jia. Highly active non-PGM catalysts prepared from metal organic frameworks. United States. doi:10.3390/catal5020955.
Barkholtz, Heather M., Chong, Lina, Kaiser, Zachary B., Xu, Tao, and Liu, Di -Jia. Thu . "Highly active non-PGM catalysts prepared from metal organic frameworks". United States. doi:10.3390/catal5020955. https://www.osti.gov/servlets/purl/1208863.
@article{osti_1208863,
title = {Highly active non-PGM catalysts prepared from metal organic frameworks},
author = {Barkholtz, Heather M. and Chong, Lina and Kaiser, Zachary B. and Xu, Tao and Liu, Di -Jia},
abstractNote = {Finding inexpensive alternatives to platinum group metals (PGMs) is essential for reducing the cost of proton exchange membrane fuel cells (PEMFCs). Numerous materials have been investigated as potential replacements of Pt, of which the transition metal and nitrogen-doped carbon composites (TM/Nx/C) prepared from iron doped zeolitic imidazolate frameworks (ZIFs) are among the most active ones in catalyzing the oxygen reduction reaction based on recent studies. In this report, we demonstrate that the catalytic activity of ZIF-based TM/Nx/C composites can be substantially improved through optimization of synthesis and post-treatment processing conditions. Ultimately, oxygen reduction reaction (ORR) electrocatalytic activity must be demonstrated in membrane-electrode assemblies (MEAs) of fuel cells. The process of preparing MEAs using ZIF-based non-PGM electrocatalysts involves many additional factors which may influence the overall catalytic activity at the fuel cell level. Evaluation of parameters such as catalyst loading and perfluorosulfonic acid ionomer to catalyst ratio were optimized. Our overall efforts to optimize both the catalyst and MEA construction process have yielded impressive ORR activity when tested in a fuel cell system.},
doi = {10.3390/catal5020955},
journal = {Catalysts},
issn = {2073-4344},
number = 2,
volume = 5,
place = {United States},
year = {2015},
month = {6}
}

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Cited by: 16 works
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Works referenced in this record:

Carbonized Nanoscale Metal–Organic Frameworks as High Performance Electrocatalyst for Oxygen Reduction Reaction
journal, November 2014

  • Zhao, Shenlong; Yin, Huajie; Du, Lei
  • ACS Nano, Vol. 8, Issue 12
  • DOI: 10.1021/nn505582e

Solvent/additive-free synthesis of porous/zeolitic metal azolate frameworks from metal oxide/hydroxide
journal, January 2011

  • Lin, Jian-Bin; Lin, Rui-Biao; Cheng, Xiao-Ning
  • Chemical Communications, Vol. 47, Issue 32
  • DOI: 10.1039/c1cc12763b

Iron imidazolate framework as precursor for electrocatalysts in polymer electrolyte membrane fuel cells
journal, January 2012

  • Zhao, Dan; Shui, Jiang-Lan; Chen, Chen
  • Chemical Science, Vol. 3, Issue 11
  • DOI: 10.1039/c2sc20657a

Electrochemistry and the Future of the Automobile
journal, June 2010

  • Wagner, Frederick T.; Lakshmanan, Balasubramanian; Mathias, Mark F.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
  • DOI: 10.1021/jz100553m

A Highly Efficient Electrocatalyst for the Oxygen Reduction Reaction: N-Doped Ketjenblack Incorporated into Fe/Fe 3 C-Functionalized Melamine Foam
journal, November 2012

  • Lee, Jang-Soo; Park, Gi Su; Kim, Sun Tai
  • Angewandte Chemie International Edition, Vol. 52, Issue 3
  • DOI: 10.1002/anie.201207193

Review and analysis of PEM fuel cell design and manufacturing
journal, February 2003


A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
journal, September 2011

  • Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie
  • Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388
  • DOI: 10.1002/chem.201101595

Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts
journal, January 2011

  • Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V.
  • Chemistry - A European Journal, Vol. 17, Issue 7
  • DOI: 10.1002/chem.201003080

Highly Efficient Non-Precious Metal Electrocatalysts Prepared from One-Pot Synthesized Zeolitic Imidazolate Frameworks
journal, December 2013

  • Zhao, Dan; Shui, Jiang-Lan; Grabstanowicz, Lauren R.
  • Advanced Materials, Vol. 26, Issue 7
  • DOI: 10.1002/adma.201304238

Well-defined carbon polyhedrons prepared from nano metal–organic frameworks for oxygen reduction
journal, January 2014

  • Xia, Wei; Zhu, Jinghan; Guo, Wenhan
  • J. Mater. Chem. A, Vol. 2, Issue 30
  • DOI: 10.1039/C4TA01656D

Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength
journal, May 2013

  • Tian, Juan; Morozan, Adina; Sougrati, Moulay Tahar
  • Angewandte Chemie International Edition, Vol. 52, Issue 27
  • DOI: 10.1002/anie.201303025

Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012


Metal Organic Framework Catalysis: Quo vadis ?
journal, December 2013

  • Gascon, Jorge; Corma, Avelino; Kapteijn, Freek
  • ACS Catalysis, Vol. 4, Issue 2, p. 361-378
  • DOI: 10.1021/cs400959k

A New Fuel Cell Cathode Catalyst
journal, March 1964

  • Jasinski, Raymond
  • Nature, Vol. 201, Issue 4925, p. 1212-1213
  • DOI: 10.1038/2011212a0

Metal-organic frameworks
journal, January 2003

  • James, Stuart L.
  • Chemical Society Reviews, Vol. 32, Issue 5
  • DOI: 10.1039/b200393g

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

  • Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1427

Metal-Free Ketjenblack Incorporated Nitrogen-Doped Carbon Sheets Derived from Gelatin as Oxygen Reduction Catalysts
journal, March 2014

  • Nam, Gyutae; Park, Joohyuk; Kim, Sun Tai
  • Nano Letters, Vol. 14, Issue 4
  • DOI: 10.1021/nl404640n

Nanoporous metal organic framework materials for smart applications
journal, April 2014


Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges
journal, April 2010

  • Gewirth, Andrew A.; Thorum, Matthew S.
  • Inorganic Chemistry, Vol. 49, Issue 8
  • DOI: 10.1021/ic9022486

Nanoscale metal–organic materials
journal, January 2011

  • Carné, Arnau; Carbonell, Carlos; Imaz, Inhar
  • Chem. Soc. Rev., Vol. 40, Issue 1
  • DOI: 10.1039/C0CS00042F

Layer-by-layer Nanoarchitectonics: Invention, Innovation, and Evolution
journal, January 2014

  • Ariga, Katsuhiko; Yamauchi, Yusuke; Rydzek, Gaulthier
  • Chemistry Letters, Vol. 43, Issue 1
  • DOI: 10.1246/cl.130987

Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction
journal, July 2009

  • Jaouen, Frédéric; Herranz, Juan; Lefèvre, Michel
  • ACS Applied Materials & Interfaces, Vol. 1, Issue 8, p. 1623-1639
  • DOI: 10.1021/am900219g