Materials Data on V5Sb4 by Materials Project

Dataset · Thu Jul 16 00:00:00 EDT 2020

DOI:https://doi.org/10.17188/1204935· OSTI ID:1204935

The Materials Project

V5Sb4 is Titanium telluride structured and crystallizes in the tetragonal I4/m space group. The structure is three-dimensional. there are two inequivalent V+2.40+ sites. In the first V+2.40+ site, V+2.40+ is bonded in a square co-planar geometry to four equivalent Sb3- atoms. All V–Sb bond lengths are 2.94 Å. In the second V+2.40+ site, V+2.40+ is bonded to five equivalent Sb3- atoms to form a mixture of corner and edge-sharing VSb5 square pyramids. There are a spread of V–Sb bond distances ranging from 2.68–2.72 Å. Sb3- is bonded in a 6-coordinate geometry to six V+2.40+ atoms.

• Research Organization: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
• Sponsoring Organization: USDOE Office of Science (SC), Basic Energy Sciences (BES)
• Contributing Organization: MIT; UC Berkeley; Duke; U Louvain
• DOE Contract Number: AC02-05CH11231; EDCBEE
• OSTI ID: 1204935
• Report Number(s): mp-30536
• Resource Relation: Related Information: https://materialsproject.org/citing
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
crystal structure
V5Sb4
Sb-V