The crystalline sponge method: MOF terminal ligand effects

Ramadhar, Timothy R.; Zheng, Shao-Liang; Chen, Yu-Sheng; Clardy, Jon

doi:10.1039/c5cc03840e

Title: The crystalline sponge method: MOF terminal ligand effects

Journal Article · Tue Jun 02 00:00:00 EDT 2015 · ChemComm

DOI:https://doi.org/10.1039/c5cc03840e· OSTI ID:1203759

Ramadhar, Timothy R. ^[1]; Zheng, Shao-Liang ^[2]; Chen, Yu-Sheng ^[3]; Clardy, Jon ^[1]

Harvard Medical School, Boston, MA (United States)
Harvard Univ., Cambridge, MA (United States)
Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Bromide and chloride analogs of the commonly used zinc iodide-based metal organic framework for the crystalline sponge method were synthesized and evaluated. Inclusion of (1R)-(–)-menthyl acetate into these MOFs was analysed using third-generation synchrotron radiation, and the effects and potential benefits of varying the MOF terminal ligand are discussed.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC)

Grant/Contract Number:: U19-AI109673; F32-GM108415; NSF/CHE-1346572; AC02-06CH11357

OSTI ID:: 1203759

Journal Information:: ChemComm, Vol. 51, Issue 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 56 works

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Title: The crystalline sponge method: MOF terminal ligand effects

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