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Materials Data on Pr2O3 by Materials Project

Dataset ·
DOI:https://doi.org/10.17188/1195765· OSTI ID:1195765
Pr2O3 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Pr3+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of Pr–O bond distances ranging from 2.34–2.72 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Pr3+ atoms to form OPr4 tetrahedra that share corners with six equivalent OPr6 octahedra, corners with six equivalent OPr4 tetrahedra, edges with three equivalent OPr6 octahedra, and edges with three equivalent OPr4 tetrahedra. The corner-sharing octahedra tilt angles range from 18–56°. In the second O2- site, O2- is bonded to six equivalent Pr3+ atoms to form OPr6 octahedra that share corners with twelve equivalent OPr4 tetrahedra, edges with six equivalent OPr6 octahedra, and edges with six equivalent OPr4 tetrahedra.
Research Organization:
LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Organization:
The Materials Project; MIT; UC Berkeley; Duke; U Louvain
DOE Contract Number:
AC02-05CH11231
OSTI ID:
1195765
Report Number(s):
mp-2063
Country of Publication:
United States
Language:
English

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