Stabilization of reactants in a weakly bound complex: OH--H{sub 2} and OH--D{sub 2}
Journal Article
·
· Journal of Chemical Physics
- Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323 (United States)
Binary complexes of OH {ital X} {sup 2}{Pi} and H{sub 2}/D{sub 2} have been stabilized in a shallow well below the activation barrier to the hydrogen abstraction reaction and identified by laser-induced fluorescence in the OH {ital A} {sup 2}{Sigma}{sup +}--X {sup 2}{Pi} 1--0 spectral region. The characteristics of the OH ({ital X} {sup 2}{Pi}, {ital A} {sup 2}{Sigma}{sup +})+H{sub 2}/D{sub 2} potentials are in accord with {ital ab} {ital initio} predictions.
- OSTI ID:
- 119408
- Journal Information:
- Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 10 Vol. 103; ISSN JCPSA6; ISSN 0021-9606
- Country of Publication:
- United States
- Language:
- English
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