Lattice dynamics of BaFe2X3(X=S,Se) compounds

Popović, Z. V.; Šćepanović, M.; Lazarević, N.; Opačić, M.; Radonjić, M. M.; Tanasković, D.; Lei, Hechang; Petrovic, C.

doi:10.1103/PhysRevB.91.064303

Lattice dynamics of ${BaFe}_{2} X_{3} (X = S, Se)$ compounds

Journal Article · Fri Feb 27 00:00:00 EST 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.91.064303· OSTI ID:1193207

Popović, Z. V. ^[1]; Šćepanović, M. ^[1]; Lazarević, N. ^[1]; Opačić, M. ^[1]; Radonjić, M. M. ^[1]; Tanasković, D. ^[1]; Lei, Hechang ^[2]; Petrovic, C. ^[2]

Univ. of Belgrade, Belgrade (Serbia)
Brookhaven National Lab. (BNL), Upton, NY (United States)

We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe₂X₃ (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe₂S₃ (BaFe₂Se₃) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe₂S(Se)₃ is supported by the lattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe₂Se₃ below T_N=255K leaves a fingerprint both in the A_1g and B_3g phonon mode linewidth and energy.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Emergent Superconductivity (CES)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1193207

Alternate ID(s):: OSTI ID: 1210686
OSTI ID: 1180751

Report Number(s):: BNL--107988-2015-JA; KC0201050

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 6 Vol. 91; ISSN 1098-0121; ISSN PRBMDO

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (5)

Temperature-Dependent Raman Study of Nanostructured and Multifunctional Materials Šćepanović, Maja; Grujić-Brojčin, Mirjana; Lazarević, Nenad physica status solidi (a), Vol. 216, Issue 13 https://doi.org/10.1002/pssa.201800763	journal	March 2019
Spin dynamics of the block orbital-selective Mott phase Herbrych, J.; Kaushal, N.; Nocera, A. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06181-6	journal	September 2018
Exploration of high-pressure structural transition and electronic properties of BaFe ₂ S ₃ Kong, Panlong; Wang, Jingjing; Jin, Yuanyuan Journal of Physics: Condensed Matter, Vol. 31, Issue 11 https://doi.org/10.1088/1361-648x/aaf8f8	journal	January 2019
Orbital order and fluctuations in the two-leg ladder materials BaFe 2 X 3 ( X = S and Se) and CsFe 2 Se 3 Takubo, Kou; Yokoyama, Yuichi; Wadati, Hiroki Physical Review B, Vol. 96, Issue 11 https://doi.org/10.1103/physrevb.96.115157	journal	September 2017
Gradual enhancement of stripe-type antiferromagnetism in the spin-ladder material BaFe 2 S 3 under pressure Zheng, Liangliang; Frandsen, Benjamin A.; Wu, Changwei Physical Review B, Vol. 98, Issue 18 https://doi.org/10.1103/physrevb.98.180402	journal	November 2018

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