The interfacial orientation relationship of oxide nanoparticles in a hafnium-containing oxide dispersion-strengthened austenitic stainless steel

Miao, Yinbin; Mo, Kun; Cui, Bai; Chen, Wei-Ying; Miller, Michael K.; Powers, Kathy A.; McCreary, Virginia; Gross, David; Almer, Jonathan; Robertson, Ian M.; Stubbins, James F.

doi:10.1016/j.matchar.2015.01.015

Title: The interfacial orientation relationship of oxide nanoparticles in a hafnium-containing oxide dispersion-strengthened austenitic stainless steel

Journal Article · Mon Jan 26 00:00:00 EST 2015 · Materials Characterization

DOI:https://doi.org/10.1016/j.matchar.2015.01.015· OSTI ID:1185533

^[1]; Mo, Kun ^[2]; Cui, Bai ^[3]; Chen, Wei-Ying ^[1]; Miller, Michael K. ^[4]; Powers, Kathy A. ^[4]; McCreary, Virginia ^[1]; Gross, David ^[1]; Almer, Jonathan ^[2]; Robertson, Ian M. ^[5]; Stubbins, James F. ^[1]

Univ. of Illinois, Urbana-Champaign, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Nebraska, Lincoln, NE (United States); Univ. of Illinois, Urbana-Champaign, IL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Wisconsin, Madison, WI (United States); Univ. of Illinois, Urbana-Champaign, IL (United States)

We report comprehensive investigations on the orientation relationship of the oxide nanoparticles in a hafnium-containing austenitic oxide dispersion-strengthened 316 stainless steel. The phases of the oxide nanoparticles were determined by a combination of scanning transmission electron microscopy–electron dispersive X-ray spectroscopy, atom probe tomography and synchrotron X-ray diffraction to be complex Y–Ti–Hf–O compounds with similar crystal structures, including bixbyite Y₂O₃, fluorite Y₂O₃–HfO₂solid solution and pyrochlore (or fluorite) Y₂(Ti,Hf)_{2 - x}O_{7 - x}. High resolution transmission electron microscopy was used to characterize the particle–matrix interfaces. Moreover, two different coherency relationships along with one axis-parallel relation between the oxide nanoparticles and the steel matrix were found. The size of the nanoparticles significantly influences the orientation relationship. Our results provide insight into the relationship of these nanoparticles with the matrix, which has implications for interpreting material properties as well as responses to radiation.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725; FG02-07ER46453; FG02-07ER46471

OSTI ID:: 1185533

Alternate ID(s):: OSTI ID: 1359521

Journal Information:: Materials Characterization, Vol. 101, Issue C; ISSN 1044-5803

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 41 works

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