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Method to produce water-soluble sugars from biomass using solvents containing lactones

Patent ·
OSTI ID:1183449
A process to produce an aqueous solution of carbohydrates that contains C6-sugar-containing oligomers, C6 sugar monomers, C5-sugar-containing oligomers, C5 sugar monomers, or any combination thereof is presented. The process includes the steps of reacting biomass or a biomass-derived reactant with a solvent system including a lactone and water, and an acid catalyst. The reaction yields a product mixture containing water-soluble C6-sugar-containing oligomers, C6-sugar monomers, C5-sugar-containing oligomers, C5-sugar monomers, or any combination thereof. A solute is added to the product mixture to cause partitioning of the product mixture into an aqueous layer containing the carbohydrates and a substantially immiscible organic layer containing the lactone.
Research Organization:
Wisconsin Alumni Research Foundation, Madison, WI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FC02-07ER64494
Assignee:
Wisconsin Alumni Research Foundation (Madison, WI)
Patent Number(s):
9,045,804
Application Number:
13/736,550
OSTI ID:
1183449
Country of Publication:
United States
Language:
English

References (21)

Ionic liquid pretreatment of cellulosic biomass: Enzymatic hydrolysis and ionic liquid recycle journal December 2010
Hydrothermal degradation of polymers derived from plants journal January 1994
The Path Forward for Biofuels and Biomaterials journal January 2006
The Effect of Flow Rate of Very Dilute Sulfuric Acid on Xylan, Lignin, and Total Mass Removal from Corn Stover journal May 2004
Production of 5-Hydroxymethylfurfural from Glucose Using a Combination of Lewis and Brønsted Acid Catalysts in Water in a Biphasic Reactor with an Alkylphenol Solvent journal April 2012
A techno-economical comparison of three processes for the production of ethanol from pine journal January 1995
Fermentable sugars by chemical hydrolysis of biomass journal March 2010
Cellulases and biofuels journal June 2009
Conversion of Hemicellulose into Furfural Using Solid Acid Catalysts in γ-Valerolactone journal December 2012
Lignocellulose: A chewy problem journal June 2011
How biotech can transform biofuels journal February 2008
Furfural-A Promising Platform for Lignocellulosic Biofuels journal December 2011
Soluble and insoluble solids contributions to high-solids enzymatic hydrolysis of lignocellulose journal December 2008
Production of levulinic acid and gamma-valerolactone (GVL) from cellulose using GVL as a solvent in biphasic systems journal January 2012
Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates journal June 2007
Gamma-valerolactone-based solvents journal January 2010
Integrated conversion of hemicellulose and cellulose from lignocellulosic biomass journal January 2013
The Billion-Ton Biofuels Vision journal June 2006
Reactive Extraction of Levulinate Esters and Conversion to γ-Valerolactone for Production of Liquid Fuels journal January 2011
Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose journal June 2006
Producing concentrated solutions of monosaccharides using biphasic CO2–H2O mixtures journal January 2012