Bandwidth optimization of femtosecond pure-rotational coherent anti-Stokes Raman scattering by pump/Stokes spectral focusing.

Kearney, Sean Patrick

doi:10.1364/AO.53.006579

Bandwidth optimization of femtosecond pure-rotational coherent anti-Stokes Raman scattering by pump/Stokes spectral focusing.

Journal Article · Tue Jul 01 00:00:00 EDT 2014 · Applied Optics

DOI:https://doi.org/10.1364/AO.53.006579· OSTI ID:1182983

Kearney, Sean Patrick ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Engineering Sciences Center

A simple spectral focusing scheme for bandwidth optimization of gas-phase rotational coherent anti-Stokes Raman scattering (CARS) spectra is presented. The method is useful when femtosecond pump/Stokes preparation of the Raman coherence is utilized. The approach is of practical utility when working with laser pulses that are not strictly transform limited, or when windows or other sources of pulse chirp may be present in the experiment. A delay between the femtosecond preparation pulses is introduced to shift the maximum Raman preparation away from zero frequency and toward the Stokes or anti-Stokes side of the spectrum with no loss in total preparation bandwidth. Shifts of 100 cm^-1 or more are attainable and allow for enhanced detection of high-energy (150-300 cm^-1) rotational Raman transitions at near transform-limited optimum sensitivity. A simple theoretical treatment for the case of identical pump and Stokes pulses with linear frequency chirp is presented. The approach is then demonstrated experimentally for typical levels of transform-limited laser performance obtained our laboratory with nonresonant CARS in argon and Raman-resonant spectra from a lean H₂/air flat flame.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Science (NA-113)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1182983

Report Number(s):: SAND--2014-15528J; 533705

Journal Information:: Applied Optics, Journal Name: Applied Optics Journal Issue: 28 Vol. 53; ISSN 0003-6935

Publisher:: Optical Society of America (OSA)Copyright Statement

Country of Publication:: United States

Language:: English

References (33)

Time-resolved femtosecond CARS from 10 to 50 Bar: collisional sensitivity: Time-resolved femtosecond CARS Wrzesinski, Paul J.; Stauffer, Hans U.; Kulatilaka, Waruna D. Journal of Raman Spectroscopy, Vol. 44, Issue 10 https://doi.org/10.1002/jrs.4287	journal	March 2013
Is rotational CARS an alternative to vibrational CARS for thermometry? Kr�ll, S.; Bengtsson, P. -E.; Ald�n, M. Applied Physics B Photophysics and Laser Chemistry, Vol. 51, Issue 1 https://doi.org/10.1007/BF00332320	journal	July 1990
Theoretical modeling of single-laser-shot, chirped-probe-pulse femtosecond coherent anti-Stokes Raman scattering thermometry Richardson, D. R.; Lucht, R. P.; Kulatilaka, W. D. Applied Physics B, Vol. 104, Issue 3 https://doi.org/10.1007/s00340-011-4489-0	journal	April 2011
Nitrogen and hydrogen CARS temperature measurements in a hydrogen/air flame using a near-adiabatic flat-flame burner Hancock, Robert D.; Bertagnolli, Kenneth E.; Lucht, Robert P. Combustion and Flame, Vol. 109, Issue 3 https://doi.org/10.1016/S0010-2180(96)00191-5	journal	May 1997
Rotational CARS for simultaneous measurements of temperature and concentrations of N2, O2, CO, and CO2 demonstrated in a CO/air diffusion flame Vestin, Fredrik; Bengtsson, Per-Erik Proceedings of the Combustion Institute, Vol. 32, Issue 1 https://doi.org/10.1016/j.proci.2008.06.027	journal	January 2009
Diagnostic Imaging in Flames with Instantaneous Planar Coherent Raman Spectroscopy Bohlin, A.; Kliewer, C. J. The Journal of Physical Chemistry Letters, Vol. 5, Issue 7 https://doi.org/10.1021/jz500384y	journal	March 2014
Spectral focusing: High spectral resolution spectroscopy with broad-bandwidth laser pulses Hellerer, Thomas; Enejder, Annika M. K.; Zumbusch, Andreas Applied Physics Letters, Vol. 85, Issue 1 https://doi.org/10.1063/1.1768312	journal	July 2004
Femtosecond coherent anti-Stokes Raman scattering measurement of gas temperatures from frequency-spread dephasing of the Raman coherence Lucht, Robert P.; Roy, Sukesh; Meyer, Terrence R. Applied Physics Letters, Vol. 89, Issue 25 https://doi.org/10.1063/1.2410237	journal	December 2006
Theory of femtosecond coherent anti-Stokes Raman scattering spectroscopy of gas-phase transitions Lucht, Robert P.; Kinnius, Paul J.; Roy, Sukesh The Journal of Chemical Physics, Vol. 127, Issue 4 https://doi.org/10.1063/1.2751184	journal	July 2007
Coherent anti-Stokes Raman microspectroscopy using spectral focusing with glass dispersion Rocha-Mendoza, Israel; Langbein, Wolfgang; Borri, Paola Applied Physics Letters, Vol. 93, Issue 20 https://doi.org/10.1063/1.3028346	journal	November 2008
Effects of N2–CO polarization beating on femtosecond coherent anti-Stokes Raman scattering spectroscopy of N2 Roy, Sukesh; Richardson, Daniel; Kinnius, Paul J. Applied Physics Letters, Vol. 94, Issue 14 https://doi.org/10.1063/1.3116087	journal	April 2009
Single-beam coherent anti-Stokes Raman scattering spectroscopy of N2 using a shaped 7 fs laser pulse Roy, Sukesh; Wrzesinski, Paul; Pestov, Dmitry Applied Physics Letters, Vol. 95, Issue 7 https://doi.org/10.1063/1.3207829	journal	August 2009
Tunable excitation source for coherent Raman spectroscopy based on a single fiber laser Adany, Peter; Arnett, David C.; Johnson, Carey K. Applied Physics Letters, Vol. 99, Issue 18 https://doi.org/10.1063/1.3657529	journal	October 2011
Communication: Time-domain measurement of high-pressure N2 and O2 self-broadened linewidths using hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering Miller, Joseph D.; Roy, Sukesh; Gord, James R. The Journal of Chemical Physics, Vol. 135, Issue 20 https://doi.org/10.1063/1.3665932	journal	November 2011
Communication: Hybrid femtosecond/picosecond rotational coherent anti-Stokes Raman scattering thermometry using a narrowband time-asymmetric probe pulse Stauffer, Hans U.; Miller, Joseph D.; Roy, Sukesh The Journal of Chemical Physics, Vol. 136, Issue 11 https://doi.org/10.1063/1.3693669	journal	March 2012
Communication: Simplified two-beam rotational CARS signal generation demonstrated in 1D Bohlin, Alexis; Patterson, Brian D.; Kliewer, Christopher J. The Journal of Chemical Physics, Vol. 138, Issue 8 https://doi.org/10.1063/1.4793556	journal	February 2013
Communication: Two-dimensional gas-phase coherent anti-Stokes Raman spectroscopy (2D-CARS): Simultaneous planar imaging and multiplex spectroscopy in a single laser shot Bohlin, Alexis; Kliewer, Christopher J. The Journal of Chemical Physics, Vol. 138, Issue 22 https://doi.org/10.1063/1.4810876	journal	June 2013
Ultrafast nonlinear spectroscopy with chirped optical pulses Nibbering, Erik T. J.; Wiersma, Douwe A.; Duppen, Koos Physical Review Letters, Vol. 68, Issue 4 https://doi.org/10.1103/PhysRevLett.68.514	journal	January 1992
Experimental comparison of single-shot broadband vibrational and dual-broadband pure rotational coherent anti-Stokes Raman scattering in hot air Seeger, Thomas; Leipertz, Alfred Applied Optics, Vol. 35, Issue 15 https://doi.org/10.1364/AO.35.002665	journal	January 1996
Simultaneous and time-resolved temperature and relative CO_2–N_2 and O_2–CO_2–N_2 concentration measurements with pure rotational coherent anti-Stokes Raman scattering for pressures as great as 5 MPa Schenk, Martin; Seeger, Thomas; Leipertz, Alfred Applied Optics, Vol. 44, Issue 26 https://doi.org/10.1364/AO.44.005582	journal	January 2005
Femtosecond laser electronic excitation tagging for quantitative velocity imaging in air Michael, James B.; Edwards, Matthew R.; Dogariu, Arthur Applied Optics, Vol. 50, Issue 26 https://doi.org/10.1364/AO.50.005158	journal	January 2011
Probe-pulse optimization for nonresonant suppression in hybrid fs/ps coherent anti-Stokes Raman scattering at high temperature Miller, Joseph D.; Slipchenko, Mikhail N.; Meyer, Terrence R. Optics Express, Vol. 19, Issue 14 https://doi.org/10.1364/OE.19.013326	journal	January 2011
Single-shot gas-phase thermometry using pure-rotational hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering Miller, Joseph D.; Roy, Sukesh; Slipchenko, Mikhail N. Optics Express, Vol. 19, Issue 16 https://doi.org/10.1364/OE.19.015627	journal	January 2011
Interference-free gas-phase thermometry at elevated pressure using hybrid femtosecond/picosecond rotational coherent anti-Stokes Raman scattering Miller, Joseph D.; Dedic, Chloe E.; Roy, Sukesh Optics Express, Vol. 20, Issue 5 https://doi.org/10.1364/OE.20.005003	journal	January 2012
Polarization suppression of the nonresonant background in femtosecond coherent anti-Stokes Raman scattering for flame thermometry at 5 kHz Richardson, Daniel R.; Bangar, Devashish; Lucht, Robert P. Optics Express, Vol. 20, Issue 19 https://doi.org/10.1364/OE.20.021495	journal	January 2012
Interference-free coherence dynamics of gas-phase molecules using spectral focusing Wrzesinski, Paul J.; Roy, Sukesh; Gord, James R. Optics Express, Vol. 20, Issue 21 https://doi.org/10.1364/OE.20.023390	journal	January 2012
Hybrid femtosecond/picosecond rotational coherent anti-Stokes Raman scattering temperature and concentration measurements using two different picosecond-duration probes Kearney, Sean P.; Scoglietti, Daniel J.; Kliewer, Christopher J. Optics Express, Vol. 21, Issue 10 https://doi.org/10.1364/OE.21.012327	journal	January 2013
Simplified setup for high-resolution spectroscopy that uses ultrashort pulses Gershgoren, E.; Bartels, R. A.; Fourkas, J. T. Optics Letters, Vol. 28, Issue 5 https://doi.org/10.1364/OL.28.000361	journal	January 2003
Hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering for high-speed gas-phase thermometry Miller, Joseph D.; Slipchenko, Mikhail N.; Meyer, Terrence R. Optics Letters, Vol. 35, Issue 14 https://doi.org/10.1364/OL.35.002430	journal	January 2010
One-dimensional single-shot thermometry in flames using femtosecond-CARS line imaging Kulatilaka, W. D.; Stauffer, H. U.; Gord, J. R. Optics Letters, Vol. 36, Issue 21 https://doi.org/10.1364/OL.36.004182	journal	January 2011
Photolytic-interference-free, femtosecond two-photon fluorescence imaging of atomic hydrogen Kulatilaka, Waruna D.; Gord, James R.; Katta, Viswanath R. Optics Letters, Vol. 37, Issue 15 https://doi.org/10.1364/OL.37.003051	journal	January 2012
Hybrid femtosecond/picosecond rotational coherent anti-Stokes Raman scattering at flame temperatures using a second-harmonic bandwidth-compressed probe Kearney, Sean P.; Scoglietti, Daniel J. Optics Letters, Vol. 38, Issue 6 https://doi.org/10.1364/OL.38.000833	journal	January 2013
Split-probe hybrid femtosecond/picosecond rotational CARS for time-domain measurement of S-branch Raman linewidths within a single laser shot Patterson, Brian D.; Gao, Yi; Seeger, Thomas Optics Letters, Vol. 38, Issue 22 https://doi.org/10.1364/OL.38.004566	journal	January 2013

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Impact of moderate pump–Stokes chirp on femtosecond coherent anti‐Stokes Raman scattering spectra Gu, Mingming; Satija, Aman; Lucht, Robert P. Journal of Raman Spectroscopy, Vol. 51, Issue 1 https://doi.org/10.1002/jrs.5754	journal	October 2019
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Interplay of pulse bandwidth and spectral resolution in spectral-focusing CARS microscopy Cole, R. A.; Slepkov, A. D. Journal of the Optical Society of America B, Vol. 35, Issue 4 https://doi.org/10.1364/josab.35.000842	journal	January 2018
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